Citation: Xiao-Ling WU, Zi-Jian LI, Fang-Dong TANG, Nan QIAN, Xin-Xin CHU, Wei LIU. A Novel Fluorinated Metal-organic Framework for Xenon/Krypton Separation[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 85-90. doi: 10.14102/j.cnki.0254–5861.2011–2776 shu

A Novel Fluorinated Metal-organic Framework for Xenon/Krypton Separation

Xiao-Ling WU ^a ,
Zi-Jian LI ^a ,
Fang-Dong TANG ^b ,
Nan QIAN ^a ,
Xin-Xin CHU ^a,, ,
Wei LIU ^a,,

a.
Shanghai Institute of Applied Physics, Chinese Academy of Science, Shanghai 201800, China
b.
Shanghai Institute of Measurement and Testing Technology, Shanghai 201203, China

Corresponding author: Xin-Xin CHU, Chuxinxin@sinap.ac.cn Wei LIU, Liuwei@sinap.ac.cn
Received Date: 24 February 2020
Accepted Date: 27 April 2020

Fund Project: the National Natural Science Foundation of China 51606210Young Potential Program of Shanghai Institute of Applied Physics, Chinese Academy of Science YX2019007Science and Technology Project of Shanghai Municipal Bureau of Quality and Technology Supervision 2017-01

Figures(5)

A porous metal-organic framework [C₂₁H₂₀CoF₆O₇] was synthesized with Co(CH₃COO)₂·4H₂O and CPHFP (2, 2'-bis(4-carboxyphenyl)hexafluoro-propane) under hydrothermal conditions. This FMOF-Co has been characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, single-crystal and powder X-ray diffraction. The crystal is of monoclinic space group P2₁/n with a = 7.8911(2), b = 29.9053(8), c = 10.5811(3) Å, β = 90.193(10)°, V = 2499.70(12) Å³, Z = 4, M_r= 557.3, D_c= 1.481 g·cm^–3, F(000)= 1132, μ = 0.768 mm^–1, GOOF = 1.035, the final R = 0.0722 and wR = 0.2326 for 6347 observed reflections with I > 2σ(I). The structure of FMOF-Co is constructed form the linkage of Co(II) through CPHFP, forming a 3D net framework. The Kr and Xe uptake values are 0.225 and 0.484 mmol·g^–1 at 303 K (100 KPa) with their mol selectivity to be 0.46; while the Kr and Xe uptake values are 0.486 and 0.077 mmol·g^–1 at 233 K (100 KPa), with their mol separation being 6.29 at this condition.
- fluorinated MOFs,
- crystal structure,
- gas adsorption
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