Citation: Wen-Qian WANG, Jun CHEN, Shuai-Hua WANG, Shao-Fan WU. Synthesis, Crystal Structure and Fluorescence Property of a Zinc(II) Coordination Polymer with a Theoretical Calculatio[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 79-84. doi: 10.14102/j.cnki.0254–5861.2011–2769 shu

Synthesis, Crystal Structure and Fluorescence Property of a Zinc(II) Coordination Polymer with a Theoretical Calculatio

Wen-Qian WANG ^{a, b} ,
Jun CHEN ^c ,
Shuai-Hua WANG ^b ,
Shao-Fan WU ^b,,

a.
College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350117, China
b.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
School of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118, China

Corresponding author: Shao-Fan WU, sfwu@fjirsm.ac.cn
Received Date: 19 February 2020
Accepted Date: 12 May 2020

Fund Project: the National Key Research Project 2017YFB1104504the Financial Support of Fujian Province 2017J05017the Financial Support of Fujian Province 2017H0043the National Natural Science Foundation of China 51872287

Figures(5)

We have designed and synthesized a new luminescent coordination polymer [Zn₂(NO₃)(NCP)₃(H₂O)₃]_n·2nH₂O (1, HNCP = 2-(2-carboxyphenyl) imidazo-[4, 5-f]-1, 10-phenanthroline) under hydrothermal conditions, which has been structurally characterized by single-crystal X-ray diffraction analyses. 1 crystallizes in monoclinic, space group P2₁/n, with a = 13.7748(3), b = 19.2651(4), c = 19.9543(4) Å, β = 95.339(2)º, V = 5272.35(19) Å³, C₆₀H_39.73N₁₃O_13.33Zn₂, M_r = 1286.80, D_c = 1.621 g/cm³, Z = 4, μ(MoKa) = 2.118, F(000) = 2629, the final R = 0.0598 and wR = 0.1483. In 1, the organic ligand NCP^– displays two different bridging modes to connect adjacent Zn(II) ions into a 1D chain along the c-direction. Photoluminescent analyses reveal that 1 exhibits a strong green emission with a fluorescent lifetime of 5.57 ns. The first-principle calculation results show that the luminescence mainly originates from ligand-centered charge transition.
- hydrothermal method,
- crystal structure,
- luminescence,
- theoretical calculation
1. [1]
  Kitagawa, S.; Kitaura, R.; Noro, S. Functional porous coordination polymers. Angew. Chem. Int. Edit. 2004, 43, 2334–2375. doi: 10.1002/anie.200300610
2. [2]
  Carraro, F.; Chapman, K.; Chen, Z. J.; Dincă, M.; Easun, T.; Eddaoudi, M.; Farha, O.; Forgan, R.; Gagliardi, L.; Haase, F.; Harris, D.; Kitagawa, S.; Knichal, J.; Lamberti, C.; Lee, J. M.; Leus, K.; Li, J.; Lin, W. B.; Lloyd, G.; Long, J. R.; Lu, C.; Ma, S. Q.; McHugh, L.; Perez, J. P. H.; Ranocchiari, M.; Rosi, N.; Rosseinsky, M.; Ryder, M. R.; Ting, V.; van der Veen, M.; Van Der Voort, P.; Volkmer, D.; Walsh, A.; Woods, D.; Yaghi, O. M. Catalysis in MOFs: general discussion. Faraday Discuss. 2017, 201, 369–394. doi: 10.1039/C7FD90046E
3. [3]
  Miao, C. L. Design and construction of a 2D Pb-II coordination polymer as a multi-response luminescent sensor for Fe³⁺, Cr₂O₇^2-, and TNP. J. Mol. Struct. 2019, 1193, 286–293. doi: 10.1016/j.molstruc.2019.05.031
4. [4]
  Zhu, Z. Q.; Tao, Y. F.; Jiang, Y. S.; Zhang, L. Y.; Xu, J. N.; Wang, L.; Fan, Y. Two scandium coordination polymers: rapid synthesis and catalytic properties. CrystEngcomm. 2019, 21, 5261–5268. doi: 10.1039/C9CE00969H
5. [5]
  Lu, J. F.; Zhao, J.; Zhao, C. B.; Yu, X. H.; Soumendra, K. R.; Yue, S. Y.; Li, L.; Zhou, K.; Jin, Li. X.; Ge, H. G. A Chinese lantern-like 2D Cu(II) coordination polymer constructed by bis-imidazole and dicarboxylate Co-ligands: synthesis, crystal structure and photocatalytic activity. Chin. J. Struct. Chem. 2020, 39, 321–328.
6. [6]
  Li, J. R.; Kuppler, R. J.; Zhou, H. C. Selective gas adsorption and separation in metal-organic frameworks. ChemInform. 2009, 38, 1477–1504.
7. [7]
  Salunkhe, R. R.; Kamachi, Y.; Torad, N. L.; Hwang, S. M.; Sun, Z. Q.; Dou, S. X.; Kim, J. H.; Yamauchi, Y. Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. J. Mater. Chem. A 2014, 2, 19848–19854. doi: 10.1039/C4TA04277H
8. [8]
  Liu, G. N.; Zhao, R. Y.; Xu, R. D.; Zhang, X.; Tang, X. N.; Dan, Q. J.; Wei, Y. W.; Tu, Y. Y.; Bo, Q. B.; Li, C. C. A novel tetranuclear copper(I) iodide metal-organic cluster Cu₄I₄(Ligand)(5) with highly selective luminescence detection of antibiotic. Cryst. Growth Des. 2018, 18, 5441–5448. doi: 10.1021/acs.cgd.8b00819
9. [9]
  Liu, G. N.; Xu, R. D.; Zhao, R. Y.; Zhao, R. Y.; Sun, Y. Q.; Bo, Q. B.; Duan, Z. Y.; Li, Y. H.; Wang, Y. Y.; Wu, Q.; Li, C. C. Hybrid copper iodide cluster-based pellet sensor for highly selective optical detection of o-nitrophenol and tetracycline hydrochloride in aqueous solution. ACS Sustain. Chem. Eng. 2019, 7, 18863–18873. doi: 10.1021/acssuschemeng.9b03963
10. [10]
  Li, L.; Zou, J. Y.; You, S. Y.; Liu, Y. W.; Cui, H. M.; Zhang, S. W. A dual luminescent chemosensor derived from a europium(III) metal-organic framework for quantitative detection of phosphate anions and acetylacetone in aqueous solution. Dyes. Pigments 2020, 173, 108004. doi: 10.1016/j.dyepig.2019.108004
11. [11]
  Bradshaw, D.; El-Hankari, S.; Lupica-Spagnolo, L. Supramolecular templating of hierarchically porous metal–organic frameworks. Chem. Soc. Rev. 2014, 43, 5431–5443. doi: 10.1039/C4CS00127C
12. [12]
  Cui, Y. J.; Yue, Y. F.; Qian, G. D.; Chen, B. L. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126–1162. doi: 10.1021/cr200101d
13. [13]
  Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330–1352. doi: 10.1039/b802352m
14. [14]
  Wang, K. C.; Lin, Z. E.; Huang, S.; Sun, J.; Zhang, Q. H. Microporous Metal-organic frameworks based on zinc clusters and their fluorescence enhancements towards acetone and chloroform. Eur. J. Inorg. Chem. 2016, 21, 3411–3416.
15. [15]
  Park, K. S.; Ni, Z.; Cote, A. P.; Choi, J. Y.; Huang, R. D.; Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. P. Natl. Acad. Sci. USA 2006, 103, 10186–10191. doi: 10.1073/pnas.0602439103
16. [16]
  Lan, Y. Q.; Li, S. L.; Fu, Y. M.; Du, D. Y.; Zang, H. Y.; Shao, K. Z.; Su, Z. M.; Fu, Q. Syntheses, structures, and luminescent properties of zinc(II) and cadmium(II) coordination complexes based on different (pyridyl)imidazole derivatives and 1, 4-benzenedicarboxylate. Cryst. Growth. Des. 2009, 9, 1353–1360. doi: 10.1021/cg8005234
17. [17]
  Song, J.; Duan, B. F.; Lu, J. F.; Wu, R.; Du, Q. C. Hydrothermal synthesis of three zinc(II) coordination polymers from 0D to 2D: synthesis, structure, luminescence properties and effect of auxiliary ligand on their structural architectures. J. Mol. Struct. 2019, 1195, 252–258. doi: 10.1016/j.molstruc.2019.05.030
18. [18]
  Yam, V. W. W.; Lo, K. K. W. Luminescent polynuclear d¹⁰ metal complexes. Chem. Soc. Rev. 1999, 28, 323–334. doi: 10.1039/a804249g
19. [19]
  Wang, K. Y.; Ding, D.; Sun, M.; Cheng, L.; Wang, C. Effective and rapid adsorption of Sr²⁺ ions by a hydrated pentasodium cluster templated zinc thiostannate. Inorg. Chem. 2019, 58, 10184–10193 doi: 10.1021/acs.inorgchem.9b01302
20. [20]
  Wang, K. Y.; Feng, M. L.; Huang, X. Y.; Li, J. Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III). Coord. Chem. Rev. 2016, 322, 41–68. doi: 10.1016/j.ccr.2016.04.021
21. [21]
  Jin, F.; Pan, C. Y.; Zhang, W. X.; Sun, L.; Hu, X. Y.; Liao, R. B.; Tao, D. L. Enhanced two-photon excited fluorescence of mercury complexes with a conjugated ligand: effect of the central metal ion. J. Lumin. 2016, 172, 264–269. doi: 10.1016/j.jlumin.2015.12.037
22. [22]
  Yin, H. Q.; Yin, X. B. Metal-organic frameworks with multiple luminescence emissions: designs and applications. Acc. Chem. Res. 2020, 53, 485–495. doi: 10.1021/acs.accounts.9b00575
23. [23]
  Liu, J. Q.; Wu, J.; Li, F. M.; Liu, W. C.; Li, B. H.; Wang, J.; Li, Q. L.; Yadave, R.; Kumar, A. Luminescent sensing from a new Zn(II) metal-organic framework. Rsc Advances 2016, 6, 31161–31166. doi: 10.1039/C6RA01709F
24. [24]
  Chen, X. L.; Cui, H. L.; Yang, H.; Liu, L.; Wang, X.; Ren, Y. X.; Wang, J. J.; Han, B. A zinc(II) coordination polymer based on a polycarboxylate ligand: synthesis, crystal structure, photoluminescence and photocatalysis. Chin. J. Struct. Chem. 2019, 38, 2148–2154.
25. [25]
  Li, J. D.; Bai, C.; Hu, H. M.; Yang, Z. H.; Xue, G. L. Solvothermal syntheses, crystal structures and luminescence properties of Zn(II) coordination compounds based on imidazophenanthroline carboxylate derivative ligand. J. Solid State Chem. 2019, 277, 1–8. doi: 10.1016/j.jssc.2019.05.039
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
3. [3]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
4. [4]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
5. [5]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
6. [6]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
7. [7]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
8. [8]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
9. [9]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
10. [10]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
11. [11]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
12. [12]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
15. [15]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
16. [16]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
17. [17]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
18. [18]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
19. [19]
  Yang Li , Yihan Chen , Jiaxin Luo , Qihuan Li , Yiwu Quan , Yixiang Cheng . Enhanced circularly polarized luminescence emission promoted by achiral dichroic oligomers of F8BT in cholesteric liquid crystal. Chinese Chemical Letters, 2024, 35(11): 109864-. doi: 10.1016/j.cclet.2024.109864
20. [20]
  Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(375)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142