Citation: Nan ZHANG, Yu-Hua GUO, You-Zhu YU, Zhen WANG, Yong-Sheng NIU, Xian-Li WU. Solvothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Silver(I) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2009-2015. doi: 10.14102/j.cnki.0254–5861.2011–2750 shu

Solvothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Silver(I) Coordination Polymer

a.
Henan Joint International Research Laboratory of Nanocomposite Sensing Materials, School of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Yong-Sheng NIU, 119yyz@163.com
Received Date: 1 February 2020
Accepted Date: 31 March 2020

Fund Project: the National Natural Science Foundation of China 21702005the Foundation of Anyang Institute of Technology YPY2019003

Figures(6)

An unprecedented one-dimensional coordination polymer [Ag₂(PhPO₃H)₂(DPPP)]_n (1) based on phenylphosphonic acid (PhPO₃H₂) and 1, 3-bis(diphenyphosphino)propane (DPPP) has been synthesized and characterized by IR, elemental analyses, thermogravimetric analyses and X-ray diffraction technique. Single-crystal X-ray diffraction analyses revealed that the complex crystallizes in triclinic system, space group P1. The coordination geometry of each Ag(I) ion is planar trigonal. Two kinds of rings were found in 1, such as the four-membered ring with Ag₂O₂ and the eight-membered ring with Ag₂O₄P₂ constructed by PhPO₃H^– ligands, which were then connected by DPPP ligands forming a zigzag type chain. Moreover, the light absorption and luminescent property of 1 were also investigated.
- silver complex,
- crystal structure,
- coordination polymer,
- photoluminescent property
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