Citation: Zhen ZHANG, Qi-Hui FANG, Zan-Yong ZHUNAG, Yang HAN, Ling-Yun LI, Yan YU. Europium Activated Aluminum Organic Frameworks for Highly Selective and Sensitive Detection of Fe³⁺ and Cr(Ⅵ) in Aqueous Solution[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 1958-1964. doi: 10.14102/j.cnki.0254–5861.2011–2742 shu

Europium Activated Aluminum Organic Frameworks for Highly Selective and Sensitive Detection of Fe³⁺ and Cr(Ⅵ) in Aqueous Solution

Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: Ling-Yun LI, lilingyun@fzu.edu.cn Yan YU, yuyan@fzu.edu.cn
Received Date: 18 January 2020
Accepted Date: 17 August 2020

Fund Project: the Natural Science Foundation of Fujian Province 2017J01746National Natural Science Foundation of China 51972061

Figures(6)

The aluminum based MOFs compound, MIL-96(Al), has been studied as a luminescence sensor by incorporating of Eu³⁺ ions, which renders the compound strong red-light emission. The as-synthesized MIL-96(Al): Eu³⁺ nanocrystals exhibit water dispersibility and environmental stability, which are general requirement for an ideal sensing material. The MIL-96(Al): Eu³⁺ nanocrystals show excellent selective detection ability on Fe³⁺ ions in aqueous solution with value of low detection limit 20 μM. Meanwhile, it also exhibits excellent selective detection ability on CrO₄^2- and Cr₂O₇^2- in aqueous solution with value of low detection limit 10 and 22 μM, respectively. The results of this study show that MIL-96(Al): Eu³⁺ nanocrystals could be used as a multi-responsive luminescent senor for Fe³⁺ and Cr(VI) species in aqueous solution. The possible luminescence quenching mechanism has also been discussed.
- luminescent sensor,
- selective detection,
- quenching mechanism
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Europium Activated Aluminum Organic Frameworks for Highly Selective and Sensitive Detection of Fe3+ and Cr(Ⅵ) in Aqueous Solution

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通讯作者: 陈斌, bchen63@163.com

Europium Activated Aluminum Organic Frameworks for Highly Selective and Sensitive Detection of Fe³⁺ and Cr(Ⅵ) in Aqueous Solution