Citation: Huan XUE, Tao LI, Qi YIN, Ge HUANG, Tian-Fu LIU. A Sulfonate-based Metal-organic Framework for the Transformation of CO₂ and Epoxides into Cyclic Carbonates[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2027-2032. doi: 10.14102/j.cnki.0254–5861.2011–2741 shu

A Sulfonate-based Metal-organic Framework for the Transformation of CO₂ and Epoxides into Cyclic Carbonates

Huan XUE ^{a, b, §} ,
Tao LI ^{a, b, §} ,
Qi YIN ^{b, §} ,
Ge HUANG ^{b, §} ,
Tian-Fu LIU ^{b, §,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Tian-Fu LIU, tfliu@fjirsm.ac.cn
Received Date: 18 January 2020
Accepted Date: 22 March 2020

Fund Project: the National Natural Science Foundation of China 21871267

Figures(4)

An interesting metal-organic framework (MOF) PFC-31 was synthesized by a simple solvothermal reaction. X-ray crystallography reveals that PFC-31 crystallizes in monoclinic system, space group P2₁/c with a = 6.8410(17), b = 20.123(5), c = 7.689(2) Å, β = 104.239(7)°, V = 1026.0(5) Å³, Z = 2, C₁₆H₂₂CuN₄O₈S₂, M_r = 526.03, μ = 1.322 mm^–1, D_c = 1.703 g/cm³, F(000) = 542, GOOF = 1.214, R = 0.0975 and wR = 0.2324. According to X-ray analysis, PFC-31 shows one-dimensional chain constructed by Cu(II) centers coordinating with two pyridine groups, two sulfonate groups and two DMF molecules. Owing to the orderly functionalized sulfonate group and Lewis metal sites, PFC-31 exhibits good catalytic capability for CO₂ cycloaddition of epoxide under normal pressure and temperature.
- metal-organic frameworks,
- sulfonate group,
- Lewis metal sites,
- cycloaddition
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A Sulfonate-based Metal-organic Framework for the Transformation of CO2 and Epoxides into Cyclic Carbonates

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通讯作者: 陈斌, bchen63@163.com

A Sulfonate-based Metal-organic Framework for the Transformation of CO₂ and Epoxides into Cyclic Carbonates