Citation: Chang-Le FU, Yi WANG, Jun-Heng HUANG. Hybrid of Quaternary Layered Double Hydroxides and Carbon Nanotubes for Oxygen Evolution Reaction[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1807-1816. doi: 10.14102/j.cnki.0254–5861.2011–2729 shu

Hybrid of Quaternary Layered Double Hydroxides and Carbon Nanotubes for Oxygen Evolution Reaction

Chang-Le FU ^{a, b} ,
Yi WANG ^a,, ,
Jun-Heng HUANG ^b,,

a.
Fujian Normal University, Fuzhou 350007, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nano-structures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yi WANG, ywang@fjnu.edu.cn Jun-Heng HUANG, huangjunheng@fjirsm.ac.cn
Received Date: 7 January 2020
Accepted Date: 30 March 2020

Fund Project: National Postdoctoral Program for Innovative Talents of China BX201600164the National Natural Science Foundation of China 21701175

Figures(6)

Highly active electrocatalysts based on Layered Double Hydroxides (LDH) towards oxygen evolution reactions (OER) are required for the applications of renewable energy-conversion technology. The improvement of conductivity and electron-transporting capability for LDH materials remains an enormous challenge yet. Here, we synthesized carbon nanotube supported quaternary FeCoNiW-LDH ultrathin nanosheets with 1 nm thickness via one-pot hydrothermal methods, which exhibit enhanced OER activity due to the synergistic effect of modified CNTs and doped W⁶⁺ onto LDH nanosheets catalysts. The loaded carbon nanotubes can directly result in the improved conductivity. In addition, W⁶⁺ doping in LDH can modify the electronic structure and further enhance the conductivity of electrocatalysts. FeCoNiW-LDH/CNT exhibits a small overpotential (258 mV) at a current density of 10 mA·cm^–2 and low Tafel slope (41 mV decade^–1) towards OER in alkaline solutions, outperforming the noble metal RuO₂ catalysts.
- FeCoNiW layered double hydroxide,
- electrocatalyst,
- reduced carbon nanotube,
- tungsten doping,
- oxygen evolution reaction
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沈阳化工大学材料科学与工程学院沈阳 110142