Citation: Hai-Peng WANG, Hong-Liang WANG, Bao-Long LI. Synthesis, Structure, Luminescence and Thermal Stability Properties of a New (3, 4)-Connected 2D Zn Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1835-1840. doi: 10.14102/j.cnki.0254–5861.2011–2708 shu

Synthesis, Structure, Luminescence and Thermal Stability Properties of a New (3, 4)-Connected 2D Zn Coordination Polymer

a.
School of Chemistry and Environmental Engineering, Shanxi Datong University, Datong, Shanxi 037009, China
b.
Institute of Materials Science & Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China
c.
State and Local Joint Engineering Laboratory for Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Bao-Long LI, libaolong@suda.edu.cn
Received Date: 18 December 2019
Accepted Date: 4 March 2020

Fund Project: the Natural Science Foundation of Jiangsu Province BK20161212the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the project of Scientific and Technological Infrastructure of Suzhou SZS201905

Figures(5)

A new zinc coordination polymer {[Zn₂(ttmb)₂(dca)₄(H₂O)]·H₂O}_n (1·H₂O) was synthesized by the reaction of 1, 3, 5-tris(1, 2, 4-triazol-1-ylmethyl)benzene (ttmb), Zn(II) salt and sodium dicyanamide (Na(dca)). The structure of the title compound was determined by single-crystal X-ray diffraction, elemental analyses and IR spectra. 1 exhibits a (3, 4)-connected 2D double-layer network with the point symbol of {6³}{(6⁶}. The solid-state luminescence shows a strong emission band at 485 nm upon excitation at 384 nm. The thermal stability properties were also studied.
- coordination polymer,
- structure,
- (3, 4)-connected,
- luminescence,
- thermal stability properties
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沈阳化工大学材料科学与工程学院沈阳 110142