Citation: Fu-Xiang WANG, Guo-Jian REN, Rui-Jing TIAN, Li-Juan FENG, Yong-Hang YANG, Yong-Yan DENG, Qin-He PAN. Pillared-layer MOF Based on Template-directed Method: Synthesis, Structure and Proton Conduction Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1337-1342. doi: 10.14102/j.cnki.0254–5861.2011–2609 shu

Pillared-layer MOF Based on Template-directed Method: Synthesis, Structure and Proton Conduction Properties

a.
Key Laboratory of Advanced Materials of Tropical Island Resources, Ministry of Education, School of Science, Hainan University, Haikou 570228, China
b.
School of Information Engineering, Changchun Sci-Tech University, Changchun 130600, China

Corresponding author: Guo-Jian REN, rgj860508@163.com Yong-Yan DENG, laodeng0224@163.com Qin-He PAN, panqinhe@163.com
Received Date: 20 September 2019
Accepted Date: 9 December 2019

Figures(6)

By using Co(NH₃)₆³⁺ as the template, a new complex HNU-38 was synthesized under hydrothermal reaction through the adoption of H₃BTC and Cl^- as the ligands (H₃BTC = 1,3,5-benzenetricarboxylic acid). HNU-38 crystallized in the monoclinic system, P2₁/c space group with a = 9.9696(3), b = 17.0580(6), c = 16.5263(6) Å, β = 100.400(2)º, Z = 4, V = 2764.31(16) Å³, M_r = 883.63, D_c = 2.123 g/cm³, F(000) = 1736, S = 0.920, R = 0.0358 and wR = 0.0838 (I > 2σ(I)). In HNU-38, the Cd²⁺ and BTC^3- were linked together to form layers with Cl^- serving as the pillar. It should be noted that (H₂O)_n chains were found in the channels and play a co-templating role along with the Co(NH₃)₆³⁺ cations in HNU-38, and the proton conduction properties were investigated.
- template,
- synthesis,
- metal-organic framework,
- pillared-layer,
- proton conduction
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