Citation: Ying LIU, Ying-Ying WU, Ya-Jie SHI, Ya-Min LI, Hui-Shuang ZHANG. One POM-based Coordination Polymer with 2,6-Bis(1-imidazoly) Pyridine as the Ligand: Synthesis, Structure and Characterizations[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1350-1356. doi: 10.14102/j.cnki.0254–5861.2011–2599 shu

One POM-based Coordination Polymer with 2,6-Bis(1-imidazoly) Pyridine as the Ligand: Synthesis, Structure and Characterizations

Ying LIU ^{a, b} ,
Ying-Ying WU ^{a, b} ,
Ya-Jie SHI ^{a, b} ,
Ya-Min LI ^{a, b,,} ,
Hui-Shuang ZHANG ^{a, b,,}

a.
Henan Key Laboratory of Polyoxometalate, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
b.
School of Marine Resources and Environment, Jiangsu Ocean University, Lianyungang, Jiangsu 222005, China

Corresponding author: Ya-Min LI, liyamin@henu.edu.cn Hui-Shuang ZHANG, liyamin@henu.edu.cn
Received Date: 11 September 2019
Accepted Date: 19 November 2019

Fund Project: the National Natural Science Foundation of China U1504209the National Natural Science Foundation of China 21403053Young Backbone Teacher Project of Henan Colleges and Universities 2016GGJS-023Foundation of Henan University 0000A40478

Figures(7)

One new polyoxometalate-based coordination polymer with 2,6-bis(1-imidazoly) pyridine (L) as the ligand, [Ni(L)(HL)(H₂O)(H₂W₁₂O₄₀)_0.5·H₂O]_n, has been synthesized under hydrothermal method and characterized by IR spectra, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analyses and thermogravimetric analyses (TGA). It crystallizes in orthorhombic, space group Pnma with a = 20.169(7), b = 23.924(8), c = 15.333(5) Å, V = 7398(4) Å³, Z = 8, F(000) = 6992, D_c = 3.488 Mg/m³, M_r = 1942.32, µ = 19.177 mm⁻¹ and the final R = 0.0299, wR = 0.0551. In the title compound, each Ni(Ⅱ) atom is bridged by two ligands L to form Ni₂L₂, which are further connected into a one-dimensional chain structure by coordination with [H₂W₁₂O₄₀]^6– polyoxoanions, and thus the ultimate 3D framework is constructed via different hydrogen bonding interactions. In addition, the cyclic voltammograms, magnetism, luminescence and photocatalytic activity towards RhB are investigated. The title compound exhibits antiferromagnetic behaviors, luminescent behaviors at solid state and photocatalytic activity to RhB.
- 2,6-bis(1-imidazoly) pyridine,
- polyoxometalate,
- antiferromagnetic behavior
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