Citation: Jing-Jing CHEN, Yu-Ying ZHENG. Quasi-3-D Gadolinium Iodate Constructed from Infinite Polyiodate: Structure, Green-emission and UV Light-driven Degradation on Organic Dye[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1323-1330. doi: 10.14102/j.cnki.0254–5861.2011–2581 shu

Quasi-3-D Gadolinium Iodate Constructed from Infinite Polyiodate: Structure, Green-emission and UV Light-driven Degradation on Organic Dye

Jing-Jing CHEN ,
Yu-Ying ZHENG ^,

College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: Yu-Ying ZHENG, yyzheng@fzu.edu.cn
Received Date: 24 August 2019
Accepted Date: 27 September 2019

Figures(8)

A new gadolinium iodate has been synthesized via hydrothermal method, and its structure was determined as [Gd(H₂O)(IO₃)₂(IO₃H₂O)]_n (1) by X-ray single-crystal diffraction. The 2-D layer is built from the linkage of Gd₂O₁₆I₄ dimer via μ₂/μ₃-bridged iodates, and the quasi-3-D network is generated via weak I···O bonds and hydrogen bonds. FTIR, powder X-ray diffraction (PXRD) and UV-Vis spectra were conducted to characterize the as-synthesized sample. Interestingly, 1 exhibits green emission, which might be assigned to electronic transfer within iodate groups. The UV adsorption of 1 hints its UV light-driven photocatalytic property, and as expected, it exhibits photocatalytic activity for the degradation of rhodamine B. Theoretical calculation was conducted to give structure/property correlation.
- rare earth iodate,
- hydrothermal synthesis,
- luminescence,
- DFT calculation
1. [1]
  Eliseeva, S. V.; Bünzli, J. C. G. Lanthanide luminescence for functional materials and bio-sciences. Chem. Soc. Rev. 2010, 39, 189–227. doi: 10.1039/B905604C
2. [2]
  Hu, C. L.; Mao, J. G. Recent advances on second-order NLO materials based on metal iodates. Coord. Chem. Rev. 2015, 288, 1–17. doi: 10.1016/j.ccr.2015.01.005
3. [3]
  Chen, J.; Hu, C. L.; Mao, F. F.; Yang, B. P.; Zhang, X. H.; Mao, J. G. REI₅O₁₄ (RE = Y and Gd): promising SHG materials featuring the semicircle-shaped I₅O₁₄^3- polyiodate anion. Angew. Chem. Int. Ed. 2019, 58, 11666–11669. doi: 10.1002/anie.201904383
4. [4]
  Sykora, R. E.; Khalifah, P.; Assefa, Z.; Albrecht-Schmitt, T. E.; Haire, R. G. Magnetism and Raman spectroscopy of the dimeric lanthanide iodates Ln(IO₃)₃ (Ln = Gd, Er) and magnetism of Yb(IO₃)₃. J. Solid State Chem. 2008, 181, 1867–1875. doi: 10.1016/j.jssc.2008.04.019
5. [5]
  Huang, C.; Hu, C. L.; Xu, X.; Yang, B. P.; Mao, J. G. Explorations of a series of second order nonlinear optical materials based on monovalent metal gold(Ⅲ) iodates. Inorg. Chem. 2013, 52, 11551–11562. doi: 10.1021/ic401891f
6. [6]
  Sun, C. F.; Hu, C. L.; Xu, X.; Yang, B. P.; Mao, J. G. Explorations of new second-order nonlinear optical materials in the potassium vanadyl iodate system. J. Am. Chem. Soc. 2011, 133, 5561–5572. doi: 10.1021/ja200257a
7. [7]
  Phanon, D.; Mosset, A.; Gautier-Luneau, I. New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO₃)₃ (M = Y, Dy) and β-M(IO₃)₃ (M = Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln³⁺ cationic radius. Solid State Sci. 2007, 9, 496–505. doi: 10.1016/j.solidstatesciences.2007.04.004
8. [8]
  Assefa, Z.; Ling, J.; Haire, R. G.; Albrecht-Schmittc, T. E.; Sykora, R. E. Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO₃)₃ and Ln(IO₃)₃(H₂O) (Ln: Yb, Lu). J. Solid State Chem. 2006, 179, 3653–3663. doi: 10.1016/j.jssc.2006.07.042
9. [9]
  Pan, C. Y.; Mai, H. D.; Chen, W. Z.; Zhao, F. H.; Yang, H. M. Synthesis, structure, and properties of a new Er^Ⅲ iodate. Aust. J. Chem. 2014, 67, 763–767. doi: 10.1071/CH13570
10. [10]
  Sykora, R. E.; Assefa, Z.; Haire, R. G. Synthesis, structure, and spectroscopic properties of Am(IO₃)₃ and the photoluminescence behavior of Cm(IO₃)₃. Inorg. Chem. 2005, 44, 5667–5676. doi: 10.1021/ic050386k
11. [11]
  Chai, W.; Lin, J.; Song, L.; Shu, K.; Qin, L.; Shi, H.; Guo, J. A two-dimensional topological structure and a series of corresponding plate-like Ln(IO₃)₃(H₂O)·H₂O (Ln = Nd, Eu, Gd, Tb, Dy) nanomaterials: syntheses, structures and properties. Solid State Sci. 2010, 12, 2100−2105. doi: 10.1016/j.solidstatesciences.2010.09.006
12. [12]
  Regny, S.; Riporto, J.; Mugnier, Y.; Dantec, R. L.; Kodjikian, S.; Pairis, S.; Gautier-Luneau, I.; Dantell, G. Microwave synthesis and up-conversion properties of SHG-active α-(La, Er)(IO₃)₃ nanocrystals. Inorg. Chem. 2019, 58, 1647−1656. doi: 10.1021/acs.inorgchem.8b03208
13. [13]
  Li, C.; Wang, F.; Zhu, J.; Yu, J. C. NaYF₄: Yb, Tm/CdS composite as a novel near-infrared-driven photocatalyst. Appl. Catal. B 2010, 100, 433−439. doi: 10.1016/j.apcatb.2010.08.017
14. [14]
  Qin, W.; Zhang, D.; Zhao, D.; Wang, L.; Zheng, K. Near-infrared photocatalysis based on YF₃: Yb³⁺, Tm³⁺/TiO₂ core/shell nanoparticles. Chem. Commun. 2010, 46, 2304−2306. doi: 10.1039/b924052g
15. [15]
  Wang, W.; Cheng, H.; Huang, B.; Li, X.; Qin, X.; Zhang, X.; Dai, Y. Ln(IO₃)₃ (Ln = Ce, Nd, Eu, Gd, Er, Yb) polycrystals as novel photocatalysts for efficient decontamination under ultraviolet light irradiation. Inorg. Chem. 2014, 53, 4989−4993. doi: 10.1021/ic500027f
16. [16]
  Perew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phy. Rev. Lett. 1996, 77, 3865–3868. doi: 10.1103/PhysRevLett.77.3865
17. [17]
  Segall, M.; Probert, M.; Pickard, C.; Hasnip, P.; Clark, S.; Refson, K.; Payne, M. First principles methods using CASTEP. Z. Krystallogr. 2005, 220, 567–570.
18. [18]
  Sheldrick, G. M. SHELXS-97: Program for the Solution of Crystal Structures. University of Gottingen, Germany 1997.
19. [19]
  Sheldrick, G. M. SHELXL-97: Program for the Refinement of Crystal Structures. University of Gottingen, Germany 1997.
20. [20]
  Douglas, P.; Hector, A. L.; Levason, W.; Light, M. E.; Matthews, M. L.; Webster, M. Hydrothermal synthesis of rare earth iodates from the corresponding periodates: Ⅱ. synthesis and structures of Ln(IO₃)₃ (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO₃)₃·2H₂O (Ln = Eu, Gd, Dy, Er, Tm, Yb). Z. Anorg. Allg. Chem. 2004, 630, 479−483. doi: 10.1002/zaac.200300377
21. [21]
  Kubelka, P.; Munk, F. Z. An article on optics of paint layers. Z. Technol. Phys. 1931, 12, 593−601.
22. [22]
  Lin, J.; Liu, Q.; Yue, Z.; Diefenbach, K.; Cheng, L.; Lin, Y.; Wang, J. Q. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties. Dalton Trans. 2019, 48, 4823–4829. doi: 10.1039/C8DT05120H
23. [23]
  Dong, H.; Sun, L.; Yan, C. Energy transfer in lanthanide upconversion studies for extended optical applications. Chem. Soc. Rev. 2015, 44, 1608−1634. doi: 10.1039/C4CS00188E
24. [24]
  Huang, H. W.; Tu, S. C.; Zeng, C.; Zhang, T. R.; Reshak, A. H.; Zhang, Y. H. Macroscopic polarization enhancement promoting photo- and piezoelectric-induced charge separation and molecular oxygen activation. Angew. Chem. Int. Ed. 2017, 56, 11860–11864 doi: 10.1002/anie.201706549
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