Citation: Jing-Jing CHEN, Yu-Ying ZHENG. Quasi-3-D Gadolinium Iodate Constructed from Infinite Polyiodate: Structure, Green-emission and UV Light-driven Degradation on Organic Dye[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1323-1330. doi: 10.14102/j.cnki.0254–5861.2011–2581 shu

Quasi-3-D Gadolinium Iodate Constructed from Infinite Polyiodate: Structure, Green-emission and UV Light-driven Degradation on Organic Dye

Jing-Jing CHEN ,
Yu-Ying ZHENG ^,

College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: Yu-Ying ZHENG, yyzheng@fzu.edu.cn
Received Date: 24 August 2019
Accepted Date: 27 September 2019

Figures(8)

A new gadolinium iodate has been synthesized via hydrothermal method, and its structure was determined as [Gd(H₂O)(IO₃)₂(IO₃H₂O)]_n (1) by X-ray single-crystal diffraction. The 2-D layer is built from the linkage of Gd₂O₁₆I₄ dimer via μ₂/μ₃-bridged iodates, and the quasi-3-D network is generated via weak I···O bonds and hydrogen bonds. FTIR, powder X-ray diffraction (PXRD) and UV-Vis spectra were conducted to characterize the as-synthesized sample. Interestingly, 1 exhibits green emission, which might be assigned to electronic transfer within iodate groups. The UV adsorption of 1 hints its UV light-driven photocatalytic property, and as expected, it exhibits photocatalytic activity for the degradation of rhodamine B. Theoretical calculation was conducted to give structure/property correlation.
- rare earth iodate,
- hydrothermal synthesis,
- luminescence,
- DFT calculation
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