Citation: Bo XU, Xiao-Dong YANG, Ling-Xue KONG. Structure and Thermochromic Property of a Silver(Ⅰ) Complex Based on Dicyanamide and Phosphine Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1301-1306. doi: 10.14102/j.cnki.0254–5861.2011–2566 shu

Structure and Thermochromic Property of a Silver(Ⅰ) Complex Based on Dicyanamide and Phosphine Ligands

School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China

Corresponding author: Bo XU, chm_xub@ujn.edu.cn
Received Date: 8 August 2019
Accepted Date: 22 November 2019

Fund Project: the China Postdoctoral Science Foundation 2017M612174the Science and Technology Project of University of Jinan XKY1826

Figures(6)

A new silver(Ⅰ) complex {Ag₂(dppm)₂[N(CN)₂]}₂[μ-N(CN)₂]₂ (1) with chelate ligand bis(diphenyl-phosphino)methane (dppm) and bridging ligand dicyanamide (N(CN)₂) was carefully synthesized and fully characterized by single-crystal X-ray crystallography, IR spectrometry, high-resolution mass spectrometry, thermal analysis and ¹H NMR. According to the crystal structure analysis, this complex could be considered as two binucleate moieties {Ag₂(dppm)₂[N(CN)₂]}⁺ linked by two bridging anionic ligands N(CN)₂⁻. It exhibits thermochromic property in solid state. The dependence of color or emission of substance on temperature is known as thermochromism. Various temperature luminescences of complex 1 are tested. Along with the reduction of temperature from 298 K to 77 K, a noticeable emission enhancement as well as lifetime extension is observed.
- silver complex,
- crystal structure,
- dicyanamide,
- bis(diphenylphosphino)methane,
- thermochromic property
1. [1]
  Seeboth, A.; Lӧtzsch, D.; Ruhmann R.; Muehling, O. Thermochromic polymers-function by design. Chem. Rev. 2014, 114, 3037–3068. doi: 10.1021/cr400462e
2. [2]
  Vu, T. D.; Chen, Z.; Zeng, X.; Jiang, M.; Liu, S.; Gao, Y.; Long, Y. Physical vapor deposition of vanadium dioxide for thermochromic smart window applications. J. Mater. Chem. C 2019, 7, 2121–2145. doi: 10.1039/C8TC05014G
3. [3]
  Zhang, Q.; Geng, A.; Zhang, H.; Hu, F.; Lu, Z.; Sun, D.; Wei, X.; Ma, C. An independent 1D single-walled metal-organic nanotube transformed from a 2D layer exhibits highly selective and reversible sensing of nitroaromatic compounds. Chem. Eur. J. 2014, 20, 4885–4890. doi: 10.1002/chem.201304784
4. [4]
  Luo, X.; Li, J.; Li, C.; Heng, L.; Dong, Y. Q.; Liu, Z.; Bo, Z.; Tang, B. Z. Reversible switching of the emission of diphenyldibenzofulvenes by thermal and mechanical stimuli. Adv. Mater. 2011, 23, 3261–3265. doi: 10.1002/adma.201101059
5. [5]
  Wang, X.; Wolfbeis, O. S.; Meier, R. J. Luminescent probes and sensors for temperature. Chem. Soc. Rev. 2013, 42, 7834–7869. doi: 10.1039/c3cs60102a
6. [6]
  Zhang, Q.; Lei, M.; Kong, F.; Yang, Y. A water-stable homochiral luminescent MOF constructed from an achiral acylamide-containing dicarboxylate ligand for enantioselective sensing of penicillamine. Chem. Commun. 2018, 54, 10901–10904. doi: 10.1039/C8CC06274A
7. [7]
  Yoshida, M.; Kato, M. Regulation of metal-etal interactions and chromic phenomena of multi-decker platinum complexes having p-systems. Coord. Chem. Rev. 2018, 355, 101–115. doi: 10.1016/j.ccr.2017.07.016
8. [8]
  Chan, K. H. Y.; Chow, H. S.; Wong, K. M. C.; Yeung, M. C. L.; Yam, V. W. W. Towards thermochromic and thermoresponsive near-infrared (NIR) luminescent molecular materials through the modulation of inter- and/or intramolecular Pt…Pt and π-π interactions. Chem. Sci. 2010, 1, 477–482. doi: 10.1039/c0sc00208a
9. [9]
  Ogawa, T.; Sameera, W. M. C.; Yoshida, M.; Kobayashi, A.; Kato, M. Luminescent ionic liquids based on cyclometalated platinum(Ⅱ) complexes exhibiting thermochromic behaviour in different colour regions. Dalton Trans. 2018, 47, 5589–5594. doi: 10.1039/C8DT00651B
10. [10]
  Veselska, O.; Okhrimenko, L.; Guillou, N.; Podbevšek, D.; Ledoux, G.; Dujardin, C.; Monge, M.; Chevrier, D. M.; Yang, R.; Zhang, P.; Fateeva, A.; Demessence, A. Intrinsic dual-emitting gold thiolate coordination polymer, (Au(+Ⅰ)(p-SPhCO₂H)]_n, for ratiometric temperature sensing. J. Mater. Chem. C 2017, 5, 9843–9848. doi: 10.1039/C7TC03605A
11. [11]
  Ghimire, M. M.; Nesterov, V. N.; Omary, M. A. Remarkable aurophilicity and photoluminescence thermochromism in a homoleptic cyclic trinuclear gold(Ⅰ) imidazolate complex. Inorg. Chem. 2017, 56, 12086–12089. doi: 10.1021/acs.inorgchem.7b01679
12. [12]
  Devadas, M. S.; Thanthirige, V. D.; Bairu, S.; Sinn, E.; Ramakrishna, G. Temperature-dependent absorption and ultrafast luminescence dynamics of bi-icosahedral Au₂₅ clusters. J. Phys. Chem. C 2013, 117, 23155–23161. doi: 10.1021/jp408333h
13. [13]
  Luo, G. G.; Su, H. F.; Xiao, A.; Wang, Z.; Zhao, Y.; Wu, Q. Y.; Wu, J. H.; Sun, D.; Zheng, L. S. Silver-sulfur hybrid supertetrahedral clusters: the hitherto missing members in the metal-chalcogenide tetrahedral clusters. Chem. Eur. J. 2017, 23, 14420–14424. doi: 10.1002/chem.201703468
14. [14]
  Xu, Q. Q.; Dong, X. Y.; Huang, R. W.; Li, B.; Zang, S. Q.; Mak, T. C. W. A thermochromic silver nanocluster exhibiting dual emission character. Nanoscale 2015, 7, 1650–1654. doi: 10.1039/C4NR05122J
15. [15]
  Kitagawa, H.; Ozawa, Y.; Toriumi, K. Flexibility of cubane-like Cu₄I₄ framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu₄I₄(PPh₃)₄] in two polymorphic crystalline states. Chem. Commun. 2010, 46, 6302–6304. doi: 10.1039/c0cc01434f
16. [16]
  Yang, K.; Li, S. L.; Zhang, F. Q.; Zhang, X. M. Simultaneous luminescent thermochromism, vapochromism, solvatochromism, and mechanochromism in a C₃-symmetric cubane [Cu₄I₄P₄] cluster without Cu–Cu interaction. Inorg. Chem. 2016, 55, 7323–7325. doi: 10.1021/acs.inorgchem.6b00922
17. [17]
  Zhan, S.; Wang, H.; Wang, D. X.; Lu, H. F.; Feng, S. Y.; Sun, D. Reactant ratio-modulated six new copper(ⅰ)-iodide coordination complexes based on diverse [Cu_mI_m] aggregates and biimidazole linkers: syntheses, structures and temperature-dependent luminescence properties. CrystEngComm. 2013, 15, 7792–7802. doi: 10.1039/c3ce41021h
18. [18]
  Roppolo, I.; Celasco, E.; Fargues, A.; Garcia, A.; Revaux, A.; Dantelle, G.; Maroun, F.; Gacoin, T.; Boilot, J. P.; Sangermanoa, M.; Perruchas, S. Luminescence thermochromism of acrylic materials incorporating copper iodide clusters. J. Mater. Chem. 2011, 21, 19106–19113. doi: 10.1039/c1jm13600c
19. [19]
  Sun, D.; Yuan, S.; Wang, H.; Lu, H. F.; Feng, S. Y.; Sun, D. F. Luminescence thermochromism of two entangled copper-iodide networks with a large temperature-dependent emission shift. Chem. Commun. 2013, 49, 6152–6154. doi: 10.1039/c3cc42741b
20. [20]
  Shan, X.; Jiang, F.; Yuan, D.; Zhang, H.; Wu, M.; Chen, L.; Wei, J.; Zhang, S. Q.; Pan, J.; Hong, M. C. A multi-metal-cluster MOF with Cu₄I₄ and Cu₆S₆ as functional groups exhibiting dual emission with both thermochromic and near-IR character. Chem. Sci. 2013, 4, 1484–1489. doi: 10.1039/c3sc21995j
21. [21]
  Zhao, S.; Wang, L.; Liu, Y.; Chen, L.; Xie, Z. Stereochemically dependent synthesis of two Cu(ⅰ) cluster-based coordination polymers with thermochromic luminescence. Inorg. Chem. 2017, 56, 13975–13981. doi: 10.1021/acs.inorgchem.7b02123
22. [22]
  Zhang, H.; Lin, C.; Sheng, T.; Hu, S.; Zhuo, C.; Fu, R.; Wen, Y.; Li, H.; Su, S.; Wu, X. A luminescent metal-rganic framework thermometer with intrinsic dual emission from organic lumophores. Chem. Eur. J. 2016, 22, 4460–4468. doi: 10.1002/chem.201504432
23. [23]
  Chen, L.; Ye, J. W.; Wang, H. P.; Pan, M.; Yin, S. Y.; Wei, Z. W.; Zhang, L. Y.; Wu, K.; Fan, Y. N.; Su, C. Y. Ultrafast water sensing and thermal imaging by a metal-organic framework with switchable luminescence. Nat. Commun. 2017, 8, 15985. doi: 10.1038/ncomms15985
24. [24]
  Zhu, Q.; Sheng, T.; Tan, C.; Hu, S.; Fu, R.; Wu, X. Formation of Zn(Ⅱ) and Cd(Ⅱ) coordination polymers assembled by triazine-based polycarboxylate and in-situ-generated pyridine-4-thiolate or dipyridylsulfide ligands: observation of an unusual luminescence thermochromism. Inorg. Chem. 2011, 50, 7618–7624. doi: 10.1021/ic200640g
25. [25]
  Wu, Y.; Zhang, X.; Zhang, Y. Q.; Yang, M.; Chen, Z. N. Achievement of ligand-field induced thermochromic luminescence via two-step single-crystal to single-crystal transformations. Chem. Commun. 2018, 54, 13961–13964. doi: 10.1039/C8CC08665F
26. [26]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. C Struct. Chem. 2015, 71, 3–8. doi: 10.1107/S2053229614024218
27. [27]
  Bondi, A. Van der Waals volumes and radii. J. Phys. Chem. 1964, 68, 441–451. doi: 10.1021/j100785a001
28. [28]
  Yam, V. W. W.; Au, V. K. M.; Leung, S. Y. L. Light-emitting self-assembled materials based on d⁸ and d¹⁰ transition metal complexes. Chem. Rev. 2015, 115, 7589–7728. doi: 10.1021/acs.chemrev.5b00074
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