Citation: Ling Li, Chunying Peng, Wenhu Wang, Xueling Li, Jie Liu. Fehling试剂中Cu²⁺-酒石酸钾钠盐螯合物的结构[J]. University Chemistry, ;2026, 41(10): 143-148. doi: 10.12461/PKU.DXHX202511054 shu

Fehling试剂中Cu²⁺-酒石酸钾钠盐螯合物的结构

College of Tea and Coffee, Puer University, Puer 665000, Yunnan Province, China

Corresponding author: Chunying Peng, pengchunyin@peu.edu.cn
Received Date: 10 November 2025
Accepted Date: 30 December 2025

Fehling试剂用于鉴定脂肪醛类化合物和还原糖类化合物，也用于还原糖类化合物的定量测定。目前国内外有机化学教材中均未提及Fehling试剂中Cu²⁺与酒石酸盐螯合物的结构。本文介绍了国内外对于Fehling试剂中Cu²⁺螯合物结构研究的最新成果，旨在对教材中Fehling试剂及其反应的知识进行补充，弥补教材知识点的局限性。
- Fehling reagent,
- Potassium sodium tartrate,
- Chelate,
- Aliphatic aldehyde,
- Reducing carbohydrate
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
  T.W.G. Solomons, C.B. Fryhle, Organic Chemistry, 10th ed.; John Wiley & Sons: Hoboken, NJ, USA, 2011; p. 1016.
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
  K. Blomqvist, E.R. Still, Inorg. Chem. 1984, 23(23), 3730.
26. [26]
27. [27]
  M. Bubtelsky, J. Jordan, J. Am. Chem. Soc. 1945, 67(10), 1824.
28. [28]
29. [29]
30. [30]
  J. Selbin, Chem. Rev. 1965, 65(2), 153.
31. [31]
  M. Biver, Inorg. Chem. 2021, 60(23), 18360.
32. [32]
  N.D. Chasteen, R.L. Belford, I.C. Paul, Inorg. Chem. 1969, 8(3), 408.
33. [33]
  L.I. Katzin, E. Gulyas, J. Phys. Chem. 1960, 64(10), 1347.
34. [34]
  J.G. Lanese, B. Jaselskis, Anal. Chem. 1963, 35(12), 1878.
35. [35]
  G.L. Robbins, R.E. Tapscott, Inorg. Chem. 1976, 15(1), 154.
36. [36]
  N.D. Chasteen, R.L. Belford, Inorg. Chem. 1970, 9(1), 169.
37. [37]
  J. Piispanen, L.H.J. Lajunen, Acta Chem. Scand. 1995, 49, 241.
38. [38]
39. [39]
  T.G. Hörner, P. Klüfers, Eur. J. Inorg. Chem. 2016, 1798.
40. [40]
  S. Albrecht, P. Klüfers, Z. Anorg. Allg. Chem. 2013, 639(2), 280.
41. [41]
42. [42]
1. [1]
  Lanjun Cheng , Xinyuan Wang , Jie An , Xiang Wu , Chengfeng Zhu , Yanming Fu , Yougui Li . Improvement of the Resolution Experiment of Racemic Tartaric Acid. University Chemistry, 2025, 40(7): 277-285. doi: 10.12461/PKU.DXHX202408010
2. [2]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
3. [3]
  Tianjiao Hu , Jie Zhang , Juan Xie , Jin Li , Mianjue Wang . 葡萄酒中有“钻石”？！——关于酒石酸家族的科普实验. University Chemistry, 2026, 41(5): 340-349. doi: 10.12461/PKU.DXHX202511013
4. [4]
  Sihan Wang , Chenxi Yu , Shuzhang Ran , Jiawei Chen , Shoutong Rao , Xinyi Liang , Ruiqi Dong , Guixiang Zeng , Guoqiang Wang , Jing Ma . 铁配合物合成与性质探究的数智化改进——大学化学实验中“磺基水杨酸合铁配合物的组成与稳定常数的测定”的创新设计. University Chemistry, 2026, 41(5): 36-49. doi: 10.12461/PKU.DXHX202511137
5. [5]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
6. [6]
  Huilin ZHENG , Tao WANG , Ruilin GAO , Mengke ZHOU , Xinyue LI , Hui WANG , Xiaoxia GU . Antitumor and antibacterial activities of transition metal complexes incorporating pyridyl salicylaldehyde Schiff base. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 897-905. doi: 10.11862/CJIC.20250358
7. [7]
  Shengwen XU , Longlong YANG , Houji CAO , Deshuang TU , Xing WEI , Changsheng LU , Hong YAN . Research progress on light-induced functionalization of polyhedral carborane clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2187-2200. doi: 10.11862/CJIC.20250192
8. [8]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
9. [9]
  Yuai Duan , Xuanyu Gan , Yao Fu , Yingjie Cao , Hongliang Han , Zhanfang Ma . Application and Innovative Design of Digital Technology in the Preparation Experiment of Cis(Trans)-Diglycine Copper Complexes. University Chemistry, 2026, 41(1): 373-381. doi: 10.12461/PKU.DXHX202504048
10. [10]
  Hao YAN , Meng WANG , Chenyi HU , Ming LI , Chuanjun YUAN . Synthesis of europium complex bonded NaYF₄∶Yb, Er micron-materials and their applications in dual-mode fluorescent development of latent fingerprints. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 991-1002. doi: 10.11862/CJIC.20250302
11. [11]
  Jiang Liu , Can Hu , Shunli Li . Design and practical exploration of teaching cases for metal-oxygen clusters: an introduction to the inorganic chemistry teaching case under the Chemistry “101 Plan”. University Chemistry, 2026, 41(6): 30-34. doi: 10.12461/PKU.DXHX202510023
12. [12]
  Pengli GUAN , Renhu BAI , Xiuling SUN , Bin LIU . Trianiline-derived aggregation-induced emission luminogen probe for lipase detection and cell imaging. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1817-1826. doi: 10.11862/CJIC.20250058
13. [13]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
14. [14]
  Chi Zhou , Zeyu Yuan , Zhibin Hu , Yaqun Wu , Liping Duan , Yichen Du , Xiaosi Zhou . Energy storage mechanisms and optimization strategies of polymer cathodes for potassium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(11): 100363-0. doi: 10.1016/j.actphy.2026.100363
15. [15]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
16. [16]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
17. [17]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
18. [18]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
19. [19]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
20. [20]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(149)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fehling试剂中Cu2+-酒石酸钾钠盐螯合物的结构

Metrics

通讯作者: 陈斌, bchen63@163.com

Fehling试剂中Cu²⁺-酒石酸钾钠盐螯合物的结构