基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO<sub>2</sub>催化转化

引用本文: 于莹莹, 徐航. 基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化[J]. 大学化学, 2026, 41(10): 132-142. doi: 10.12461/PKU.DXHX202511033 shu

Citation: Yingying Yu, Hang Xu. 基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化[J]. University Chemistry, 2026, 41(10): 132-142. doi: 10.12461/PKU.DXHX202511033 shu

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

于莹莹 ,
徐航 ^,

南开大学化学学院, 天津 300071

通讯作者: 徐航,E-mail:xuhang@nankai.edu.cn

基金项目:
国家自然科学基金(22271159)

摘要: 为响应国家科技兴邦与可持续战略，本研究将前沿成果融入教学，旨在增强学生社会责任感，拓展专业与学术视野，培养科学思维、创新能力与实践能力，激发科研热情。诺贝尔奖前沿材料金属有机框架(MOFs)，尤其是簇基MOFs，因结构可调、稳定性高且活性位点丰富，在CO₂催化转化中展现出广阔前景，已成国内外研究热点。但簇基MOFs合成仍面临“黑箱反应”带来的不可预测性与结构精确调控的挑战。本文以X-射线单晶衍射解析金属团簇结构为起点，系统介绍了从零维金属团簇“自下而上”构筑簇基MOFs的研究进展，并从金属团簇中心、有机配体及孔道客体分子三方面深入探讨调控其CO₂催化性能的策略。通过精选的典型案例，有助于本科生直观理解X-射线单晶衍射、簇基MOFs及CO₂催化转化等前沿动态，拓展其相关领域认知。

关键词:

English

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

Yingying Yu ,
Hang Xu ^,

College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Hang Xu, xuhang@nankai.edu.cn

Received Date: 05 November 2025
Accepted Date: 02 December 2025
Available Online: 15 December 2025

Abstract: 为响应国家科技兴邦与可持续战略，本研究将前沿成果融入教学，旨在增强学生社会责任感，拓展专业与学术视野，培养科学思维、创新能力与实践能力，激发科研热情。诺贝尔奖前沿材料金属有机框架(MOFs)，尤其是簇基MOFs，因结构可调、稳定性高且活性位点丰富，在CO₂催化转化中展现出广阔前景，已成国内外研究热点。但簇基MOFs合成仍面临“黑箱反应”带来的不可预测性与结构精确调控的挑战。本文以X-射线单晶衍射解析金属团簇结构为起点，系统介绍了从零维金属团簇“自下而上”构筑簇基MOFs的研究进展，并从金属团簇中心、有机配体及孔道客体分子三方面深入探讨调控其CO₂催化性能的策略。通过精选的典型案例，有助于本科生直观理解X-射线单晶衍射、簇基MOFs及CO₂催化转化等前沿动态，拓展其相关领域认知。

Key words:

1. [1]
  M. Ding, R.W. Flaig, H.-L. Jiang, O.M. Yaghi, Chem. Soc. Rev. 2019, 48(10), 2783.M. Ding, R.W. Flaig, H.-L. Jiang, O.M. Yaghi, Chem. Soc. Rev. 2019, 48(10), 2783.
2. [2]
  J. Shi, Y. Jiang, Z. Jiang, X. Wang, X. Wang, S. Zhang, P. Han, C. Yang, Chem. Soc. Rev. 2015, 44(17), 5981.J. Shi, Y. Jiang, Z. Jiang, X. Wang, X. Wang, S. Zhang, P. Han, C. Yang, Chem. Soc. Rev. 2015, 44(17), 5981.
3. [3]
  M. Lu, M. Zhang, J. Liu, Y. Chen, J. Liao, M. Yang, Y. Cai, S. Li, Y. Lan, Angew. Chem. Int. Ed. 2022, 61(15), e202200003.M. Lu, M. Zhang, J. Liu, Y. Chen, J. Liao, M. Yang, Y. Cai, S. Li, Y. Lan, Angew. Chem. Int. Ed. 2022, 61(15), e202200003.
4. [4]
  S. Gulati, S.Vijayan, Mansi, S. Kumar, B. Harikumar, M. Trivedi, R.S. Varma, Coord. Chem. Rev. 2023, 474, 214853.S. Gulati, S.Vijayan, Mansi, S. Kumar, B. Harikumar, M. Trivedi, R.S. Varma, Coord. Chem. Rev. 2023, 474, 214853.
5. [5]
  C. Zhang, Z. Lin, L. Jiao, H. Jiang, Angew. Chem. Int. Ed. 2024, 63(50), e202414506.C. Zhang, Z. Lin, L. Jiao, H. Jiang, Angew. Chem. Int. Ed. 2024, 63(50), e202414506.
6. [6]
  F.-Y. Ren, B. Zhao, Acc. Chem. Res. 2025, 58(19), 3033.F.-Y. Ren, B. Zhao, Acc. Chem. Res. 2025, 58(19), 3033.
7. [7]
  Z.-H. Pan, Z.-Z. Weng, X.-J. Kong, L.-S. Long, L.-S. Zheng, Coord. Chem. Rev. 2022, 457, 214419.Z.-H. Pan, Z.-Z. Weng, X.-J. Kong, L.-S. Long, L.-S. Zheng, Coord. Chem. Rev. 2022, 457, 214419.
8. [8]
  T. Song, X. Liu, H. Wang, Q. Yuan, X. Cai, W. Ding, Y. Zhu, Coord. Chem. Rev. 2025, 543, 216922.T. Song, X. Liu, H. Wang, Q. Yuan, X. Cai, W. Ding, Y. Zhu, Coord. Chem. Rev. 2025, 543, 216922.
9. [9]
  L. Dong, L. Zhang, J. Liu, Q. Huang, M. Lu, W. Ji, Y. Lan, Angew. Chem. Int. Ed. 2020, 59(7), 2659.L. Dong, L. Zhang, J. Liu, Q. Huang, M. Lu, W. Ji, Y. Lan, Angew. Chem. Int. Ed. 2020, 59(7), 2659.
10. [10]
  I. Abánades Lázaro, X. Chen, M. Ding, A. Eskandari, D. Fairen-Jimenez, M. Giménez-Marqués, R. Gref, W. Lin, T. Luo, R.S. Forgan, Nat. Rev. Method. Prime. 2024, 4(1), 42.I. Abánades Lázaro, X. Chen, M. Ding, A. Eskandari, D. Fairen-Jimenez, M. Giménez-Marqués, R. Gref, W. Lin, T. Luo, R.S. Forgan, Nat. Rev. Method. Prime. 2024, 4(1), 42.
11. [11]
  H.-G. Jin, P.-C. Zhao, Y. Qian, J.-D. Xiao, Z.-S. Chao, H.-L. Jiang, Chem. Soc. Rev. 2024, 53(18), 9378.H.-G. Jin, P.-C. Zhao, Y. Qian, J.-D. Xiao, Z.-S. Chao, H.-L. Jiang, Chem. Soc. Rev. 2024, 53(18), 9378.
12. [12]
  Y. Xu, Q. Li, H. Xue, H. Pang, Coord. Chem. Rev. 2018, 376, 292.Y. Xu, Q. Li, H. Xue, H. Pang, Coord. Chem. Rev. 2018, 376, 292.
13. [13]
  Y.-L. Bai, J. Tao, R.-B. Huang, L.-S. Zheng, Angew. Chem. Int. Ed. 2008, 47(29), 5344.Y.-L. Bai, J. Tao, R.-B. Huang, L.-S. Zheng, Angew. Chem. Int. Ed. 2008, 47(29), 5344.
14. [14]
  X.-L. Wang, C. Qin, S.-X. Wu, K.-Z. Shao, Y.-Q. Lan, S. Wang, D.-X. Zhu, Z.-M. Su, E.-B. Wang, Angew, Chem. Int. Ed. 2009, 48(29), 5291.X.-L. Wang, C. Qin, S.-X. Wu, K.-Z. Shao, Y.-Q. Lan, S. Wang, D.-X. Zhu, Z.-M. Su, E.-B. Wang, Angew, Chem. Int. Ed. 2009, 48(29), 5291.
15. [15]
  Z. Niu, S. Fang, X. Liu, J.-G. Ma, S. Ma, P. Cheng, J. Am. Chem. Soc. 2015, 137(47), 14873.Z. Niu, S. Fang, X. Liu, J.-G. Ma, S. Ma, P. Cheng, J. Am. Chem. Soc. 2015, 137(47), 14873.
16. [16]
  Z.-L. Liang, Z.-H. Zhang, Y.-E. Jiao, H. Xu, H.-S. Hu, B. Zhao, J. Am. Chem. Soc. 2024, 146(15), 10776.Z.-L. Liang, Z.-H. Zhang, Y.-E. Jiao, H. Xu, H.-S. Hu, B. Zhao, J. Am. Chem. Soc. 2024, 146(15), 10776.
17. [17]
  Y.-S. Xia, L. Zhang, J.-N. Lu, X.-H. Zhao, L.-Z. Dong, J. Liu, Y.-Q. Lan, Nat. Synth. 2024, 3(3), 406.Y.-S. Xia, L. Zhang, J.-N. Lu, X.-H. Zhao, L.-Z. Dong, J. Liu, Y.-Q. Lan, Nat. Synth. 2024, 3(3), 406.
18. [18]
  H. Xue, Z.-H. Zhao, P.-Q. Liao, X.-M. Chen, J. Am. Chem. Soc. 2023, 145(31), 16978.H. Xue, Z.-H. Zhao, P.-Q. Liao, X.-M. Chen, J. Am. Chem. Soc. 2023, 145(31), 16978.
19. [19]
  L.-L. Ling, X. Guan, X. Liu, X.-M. Lei, Z. Lin, H.-L. Jiang, Natl. Sci. Rev. 2024, 11(6), nwae114.L.-L. Ling, X. Guan, X. Liu, X.-M. Lei, Z. Lin, H.-L. Jiang, Natl. Sci. Rev. 2024, 11(6), nwae114.
20. [20]
  H. Liu, H. Wang, Q. Song, K. Küster, U. Starke, P.A. Aken, E. Klemm, Angew. Chem. Int. Ed. 2022, 61(9), e202117058.H. Liu, H. Wang, Q. Song, K. Küster, U. Starke, P.A. Aken, E. Klemm, Angew. Chem. Int. Ed. 2022, 61(9), e202117058.
21. [21]
  Y.-F. Lu, L.-Z. Dong, J. Liu, R.-X. Yang, J.-J. Liu, Y. Zhang, L. Zhang, Y.-R. Wang, S.-L. Li, Y.-Q. Lan, Angew. Chem. Int. Ed. 2021, 60(50), 26210.Y.-F. Lu, L.-Z. Dong, J. Liu, R.-X. Yang, J.-J. Liu, Y. Zhang, L. Zhang, Y.-R. Wang, S.-L. Li, Y.-Q. Lan, Angew. Chem. Int. Ed. 2021, 60(50), 26210.
22. [22]
  X. Zhang, Y. Jiang, H. Fei, Chem. Commun. 2019, 55(79), 11928.X. Zhang, Y. Jiang, H. Fei, Chem. Commun. 2019, 55(79), 11928.
23. [23]
  X.-R. Tian, X.-L. Jiang, S.-L. Hou, Z.-H. Jiao, J. Han, B. Zhao, Angew. Chem. Int. Ed. 2022, 61(18), e202200123.X.-R. Tian, X.-L. Jiang, S.-L. Hou, Z.-H. Jiao, J. Han, B. Zhao, Angew. Chem. Int. Ed. 2022, 61(18), e202200123.
24. [24]
  Y. Yin, S. Feng, X. Xu, Y. Liu, Y. Li, L. Gao, X. Zhou, J. Dong, Y. Wu, J. Su, et al., J. J. Am. Chem. Soc. 2025, 147(19), 16481.Y. Yin, S. Feng, X. Xu, Y. Liu, Y. Li, L. Gao, X. Zhou, J. Dong, Y. Wu, J. Su, et al., J. J. Am. Chem. Soc. 2025, 147(19), 16481.
25. [25]
  Z. Zhang, Q. Xu, W. Li, Y. Zhu, J.-S. Qin, Y. Yang, H. Rao, L. Chen, J. Am. Chem. Soc. 2025, 147(37), 33330.Z. Zhang, Q. Xu, W. Li, Y. Zhu, J.-S. Qin, Y. Yang, H. Rao, L. Chen, J. Am. Chem. Soc. 2025, 147(37), 33330.
26. [26]
  K. Ma, J. Li, J. Liu, C. Li, Z. Shi, S. Feng, Nano Res. 2024, 17(5), 3653.K. Ma, J. Li, J. Liu, C. Li, Z. Shi, S. Feng, Nano Res. 2024, 17(5), 3653.
27. [27]
  L.-Y. Li, X.-Y. Zhao, M.-H. Tang, Z.-W. Yang, F.-Y. Ren, Z.-L. Liang, P.-F. Guo, H. Xu, X.-Y. Zhang, J. Zhao, et al., Angew. Chem. Int. Ed. 2025, 64(37), e202512100.L.-Y. Li, X.-Y. Zhao, M.-H. Tang, Z.-W. Yang, F.-Y. Ren, Z.-L. Liang, P.-F. Guo, H. Xu, X.-Y. Zhang, J. Zhao, et al., Angew. Chem. Int. Ed. 2025, 64(37), e202512100.
28. [28]
  Z. Niu, W.D.C. Bhagya Gunatilleke, Q. Sun, P.C. Lan, J. Perman, J.-G. Ma, Y. Cheng, B. Aguila, S. Ma, Chem 2018, 4(11), 2587.Z. Niu, W.D.C. Bhagya Gunatilleke, Q. Sun, P.C. Lan, J. Perman, J.-G. Ma, Y. Cheng, B. Aguila, S. Ma, Chem 2018, 4(11), 2587.
29. [29]
  A.-L. Gu, Y.-X. Zhang, Z.-L. Wu, H.-Y. Cui, T.-D. Hu, B. Zhao, Angew. Chem. Int. Ed. 2022, 61(19), e202114817.A.-L. Gu, Y.-X. Zhang, Z.-L. Wu, H.-Y. Cui, T.-D. Hu, B. Zhao, Angew. Chem. Int. Ed. 2022, 61(19), e202114817.
30. [30]
  C.-H. Zhang, T.-D. Hu, Y.-T. Zhai, Y.-X. Zhang, Z.-L. Wu, Green Chem. 2023, 25(5), 1938.C.-H. Zhang, T.-D. Hu, Y.-T. Zhai, Y.-X. Zhang, Z.-L. Wu, Green Chem. 2023, 25(5), 1938.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 99
HTML全文浏览量: 6

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

通讯作者: 徐航,E-mail:xuhang@nankai.edu.cn

English

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

Corresponding author: Hang Xu, xuhang@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化

通讯作者: 徐航,E-mail:xuhang@nankai.edu.cn

English

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO2催化转化

Corresponding author: Hang Xu, xuhang@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

基于X-射线单晶衍射精准构筑簇基金属有机框架及其CO₂催化转化

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs