Home

Citation: Shikun Jia, Hui Jiang, Yuanyuan Chang, Linlin Shi, Erqing Li, Kai Li, Xinqi Hao, Guangjian Mei. 大学有机化学“芳香性”教学拓展——以芳香全氮化合物为例[J]. University Chemistry, ;2026, 41(10): 127-131. doi: 10.12461/PKU.DXHX202511012 shu

大学有机化学“芳香性”教学拓展——以芳香全氮化合物为例

College of Chemistry, Zhengzhou University, Zhengzhou 450001, Henan Province, China

Corresponding author: Xinqi Hao, Guangjian Mei,
Received Date: 3 November 2025
Accepted Date: 22 December 2025

芳香性作为大学有机化学教学中最重要的概念之一，一直受到化学家的关注。最近，在高能密度材料研究中，化学家发现或者预测了多种芳香全氮化合物。本文介绍了三种芳香全氮化合物，包括芳香五唑阴离子(cyclo-N₅^-)、芳香六嗪阴离子([N₆]^4-)以及芳香5/6并环多氮阴离子(cyclo-N₉^-)。笔者认为，这些芳香全氮化合物可以做为大学有机化学中经典芳香化合物的教学补充，不仅可以加深学生对芳香化合物判定标准的理解，而且有助于有机化学科学思维的养成。
- Organic chemistry,
- Aromaticity,
- Polynitrogen compounds,
- Pentazole anion,
- Hexazine anion
1. [1]
2. [2]
  M. Faraday, Philos. Trans. R. Soc. London 1825, 115, 440.
3. [3]
  E.Z. Hückel, Phys. 1931, 70(3), 204.
4. [4]
5. [5]
  M.T. Nguyen, Coord. Chem. Rev. 2003, 244(1), 93.
6. [6]
  C. Zhang, C. Sun, B. Hu, C. Yu, M. Lu, Science 2017, 355(6323), 374.
7. [7]
  Y. Xu, Q. Wang, C. Shen, Q. Lin, P. Wang, M. Lu, Nature 2017, 549, 78.
8. [8]
  D. Laniel, F. Trybel, Y. Yin, T. Fedotenko, S. Khandarkhaeva, A. Aslandukov, G. Aprilis, A.I. Abrikosov, T.B. Masood, C. Giacobbe, et al., Nat. Chem. 2023, 15, 641.
9. [9]
10. [10]
  X. Yuan, Z. Xu, H. Gu, T. Zhang, Y. Xu, M. Lu, Adv. Sci. 2025, 12, 2414394.
1. [1]
  Benhua Wang , Chaoyi Yao , Yiming Li , Qing Liu , Minhuan Lan , Guipeng Yu , Yiming Luo , Xiangzhi Song . 一种基于香豆素氟离子荧光探针的合成、表征及性能测试——“科研反哺教学”在有机化学综合实验教学中的探索与实践. University Chemistry, 2025, 40(6): 201-209. doi: 10.12461/PKU.DXHX202408070
2. [2]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
3. [3]
  Dawei Zhang , Yuqian Zhao , Mingyu Jiao , Yan Wang . Cultivation of Students’ Critical Thinking in the Practice of Ideological and Political in Organic Chemistry Courses: Taking the Discrimination and Analysis of Chemical Rumors as Examples. University Chemistry, 2025, 40(4): 181-188. doi: 10.12461/PKU.DXHX202405211
4. [4]
  Linjie Wang , Zhao Wei , Ming Gao , Xiaohui Zheng , Xinghai Hao . Item Development in the Context of Academic Exploration: Materials, Key Considerations, and Suggestions: A Case Study on the Research and Development of Polynitrogen Compounds. University Chemistry, 2026, 41(2): 411-419. doi: 10.12461/PKU.DXHX202503033
5. [5]
  Guojiao Wu , Yuzhou Wu , Weiming Yuan , Fangrui Zhong . Bridging chemistry and biology: innovative practices in organic chemistry teaching. University Chemistry, 2026, 41(6): 72-78. doi: 10.12461/PKU.DXHX202508064
6. [6]
  Fuxian Wan , Ying Li , Yuanhong Zhang , Shuhua Zhu , Jing Xu , Yanfang Wang , Lili Zhang . Exploration and Practice of Teaching in Agricultural Characteristic Organic Chemistry Course. University Chemistry, 2024, 39(2): 298-306. doi: 10.3866/PKU.DXHX202308041
7. [7]
  Zhichang Xiao , Xiaohui Li , Ling Zhang , Huimin Liu . Exploration of Ideological and Political Construction in University Foundation Course of Organic Chemistry. University Chemistry, 2024, 39(2): 314-320. doi: 10.3866/PKU.DXHX202308058
8. [8]
  Shuixing Dai , Jilei Jiang , Yuxiao Wang , Jinqi Hu , Minghua Huang . Application of Knoevenagel Reaction in Organic Chemistry Teaching. University Chemistry, 2025, 40(5): 334-341. doi: 10.12461/PKU.DXHX202405208
9. [9]
  Zhenxing Liu , Jiaen Hu , Zishi Cheng , Xinqi Hao . 基础有机化学教学中烯烃的氧化反应. University Chemistry, 2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107
10. [10]
  Linlin Wang , Yanqin Chen , Feng Li , Ruikang Tan . Practical Exploration of Graded Teaching in the Public Organic Chemistry Course for Agricultural Science Students. University Chemistry, 2025, 40(7): 48-54. doi: 10.12461/PKU.DXHX202409054
11. [11]
  Qi Lin , Jianhua Liu , Liyun Yao , Xiuyan Yang , Weina He , Ruolin Yang . Exploring the Application of Superstar AI Teaching Assistant in Medical Organic Chemistry Courses. University Chemistry, 2025, 40(9): 142-147. doi: 10.12461/PKU.DXHX202502035
12. [12]
  Di Xu , Li Dai , Wenzhi Yao , Li Wang , Fang Zhang , Xin Gao . Exploration and Application of Smart Teaching in Organic Chemistry. University Chemistry, 2025, 40(9): 189-195. doi: 10.12461/PKU.DXHX202412072
13. [13]
  Yuwei Song , Wan He , Kaiyue Jiang , Mengzhao Xi , Xinyue Wang , Jie Li , Yan Zhang . Learning and Memorizing Common Named Reactions in College Organic Chemistry. University Chemistry, 2026, 41(2): 400-410. doi: 10.12461/PKU.DXHX202501004
14. [14]
  Hanni Zhou , Juanjuan Lu , Xinrui Zhao , Huilin Li , Junlong Zhao . Oil-Splashed Chili: A Symphony of Traditional Cuisine and Organic Chemistry. University Chemistry, 2026, 41(3): 357-362. doi: 10.12461/PKU.DXHX202504010
15. [15]
  Zi Wang , Zhihua Peng , Longli Zhang , Linhua Song , Da Yang , Cuiyu Jiang . Exploration and Practice of Ideological and Political Education in Organic Chemistry Curriculum Integrated with Petroleum Industry Characteristics. University Chemistry, 2026, 41(4): 104-111. doi: 10.12461/PKU.DXHX202502086
16. [16]
  Cuiyuan Liang , Xinyu Zhang , Mei Zhang , Dianpeng Qi . 有机化学教学数字化智能化改造. University Chemistry, 2026, 41(8): 40-46. doi: 10.12461/PKU.DXHX202507053
17. [17]
  Yuhui Jin , Qiao Chen , Hexiang Jia , Yin Wang . Curriculum ideological and political education of organic chemistry for radiochemistry major: exploration and practice. University Chemistry, 2026, 41(6): 297-309. doi: 10.12461/PKU.DXHX202504065
18. [18]
  Fei Xie , Shichong Yu , Ting Wang , Yongsheng Jin , Dazhi Zhang , Yumeng Hao . Practice and Exploration of O-PIRTAS Flipped Classroom in Organic Chemistry Course. University Chemistry, 2024, 39(4): 238-243. doi: 10.3866/PKU.DXHX202310055
19. [19]
  Hui Liu , Shupeng Zhang , Yuntian Zhang , Wei Dong , Yuji Liu , Bingxin Deng , Dongping Chen , Yongxing Tang . Research on the Application of Virtual Reality (VR) Technology in the Teaching of Organic Chemistry. University Chemistry, 2024, 39(8): 64-71. doi: 10.3866/PKU.DXHX202312028
20. [20]
  Jian He , Dinglin Zhang , Liping Wu , Ying Bao , Xiaochao Yang . 知识网络构建策略在有机化学教学中的应用及效果分析. University Chemistry, 2025, 40(8): 66-71. doi: 10.12461/PKU.DXHX202410092

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(145)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return