Citation: Hongshen Lin, Yuxiao Hu, Wenju Chang, Jie Shen. P(III)/P(V)催化循环在Wittig反应中的应用研究进展[J]. University Chemistry, ;2026, 41(10): 118-126. doi: 10.12461/PKU.DXHX202510003 shu

P(III)/P(V)催化循环在Wittig反应中的应用研究进展

College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian Province, China

Corresponding author: Wenju Chang, Jie Shen,
Received Date: 9 October 2025
Accepted Date: 26 November 2025

传统Wittig反应需使用化学计量的膦试剂，并不可避免地产生等当量的膦氧化物副产物，难以符合绿色化学理念。近年来，研究人员致力于发展P(III)/P(V)循环催化策略，利用催化量膦试剂实现高效转化，显著提高原子经济性。本文综述了催化型Wittig反应及其机理，旨在加深学生对绿色化学与反应机制的理解，促进科研成果与教学实践的融合。
- Wittig reaction,
- P(III)/P(V) redox catalysis,
- Organic phosphorus compounds,
- Green chemistry,
- Atom economy
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