Citation: Jianlin Ren, Bing Li, Yan Guo, Xiangyu Liu. 氖的特殊化学物种：研究进展与成键机制[J]. University Chemistry, ;2026, 41(9): 182-201. doi: 10.12461/PKU.DXHX202508055 shu

氖的特殊化学物种：研究进展与成键机制

National Key Laboratory of Coal Efficient Utilization and Green Chemical Technology, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, Ningxia Hui Autonomous Region, China

Corresponding author: Jianlin Ren, rjl@nxu.edu.cn
Received Date: 19 August 2025
Revised Date: 17 October 2025

氖是价电子层为2s2²p⁶的闭壳层八隅体，属轻稀有气体，因而在常规条件下表现出极强的化学惰性。近年来，借助高精度计算化学对势能面的系统预测，以及极端条件下原位实验技术(低温基质隔离、高压金刚石对顶砧、同步辐射原位光谱等)的同步发展，研究者已能在实验室尺度诱导氖与特定宿主发生弱相互作用，生成若干“非经典”化学物种。本文在梳理现有文献的基础上，将这些发现归纳为三类：包合物(含内嵌富勒烯化合物)、高压下与碱金属/碱土金属形成的离子型化合物、低温基质中与含硅自由基的范德华复合物(含与四氯化碳的电荷转移复合物)，其成键机制与已报道的氦化合物具有高度相似。
- Noble gas,
- Neon,
- Clathrate,
- Compound,
- Complex
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