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Citation: Ruming Yuan, Laiying Zhang, Xiaoming Xu, Pingping Wu, Gang Fu, Bin Ren. 从微观结构到宏观极性：实验与计算协同解析偶极矩[J]. University Chemistry, ;2026, 41(9): 293-300. doi: 10.12461/PKU.DXHX202508054 shu

从微观结构到宏观极性：实验与计算协同解析偶极矩

National Demonstration Center for Experimental Chemistry Education (Xiamen University), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China

Corresponding author: Ruming Yuan, yuanrm@xmu.edu.cn
Received Date: 15 August 2025
Revised Date: 13 October 2025

针对传统偶极矩实验中“重操作、轻机理”的局限性，本文依托化学“101计划”化学测量学实验，提出“实验测定-计算模拟”深度融合的教学模式。以溶液法偶极矩测定实验为基础，引入Gaussian/GaussView量化计算工具，引导学生结合静电势和自然键轨道电荷解析偶极本质、溶剂效应及构象调控。通过“基础-进阶-创新”三层次模块构建“结构-性质-功能”的贯通认知，提升学生从实验技能到分子设计的综合能力，为培养兼具实践与创新能力的复合型化学人才提供教学范式。
- Chemistry “101 Plan”,
- Dipole moment,
- Computational simulation,
- Molecular design
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