Citation: Liyuan Huang, Shaodan Wang, Lili Wen, Hong Yuan. S型异质结富硫空位Sv-ZnIn₂S₄/TpPa-1的构筑及其光催化制氢研究——推荐一个创新化学实验[J]. University Chemistry, ;2026, 41(8): 339-349. doi: 10.12461/PKU.DXHX202508010 shu

S型异质结富硫空位Sv-ZnIn₂S₄/TpPa-1的构筑及其光催化制氢研究——推荐一个创新化学实验

Liyuan Huang ^1,2 ,
Shaodan Wang ^1,2 ,
Lili Wen ^1,2,, ,
Hong Yuan ^1,2

1.
College of Chemistry, Central China Normal University, Wuhan 430079, Hubei Province, China;
2.
National Demonstration Center for Experimental Chemistry Education (Central China Normal University), Wuhan 430079, Hubei Province, China

Corresponding author: Lili Wen, wenlili@ccnu.edu.cn
Received Date: 5 August 2025
Accepted Date: 15 September 2025

介绍了一个创新化学实验——S型异质结富硫空位Sv-ZnIn₂S₄/TpPa-1的构筑及其光催化制氢研究。本实验基于微波-水热法合成Sv-ZnIn₂S₄/TpPa-1，利用离心操作对产物进行分离提纯，运用气相色谱仪在线检测H₂的产量并计算制氢速率，利用X射线光电子能谱仪分析S型异质结光生电荷的转移机制。本实验综合了无机化学、物理化学和分析化学的基础知识，以及实验技能和大型仪器的学习操作，同时也体现了光催化分解水制氢这一科研热点。本实验使学生既巩固了所学基础知识和实验技能，也激发了科研热情，并帮助学生初步建立科学的思维方式与研究能力，达到创新实验教学的目的。此外，在课程教学过程中，通过引入科研反哺教学、课程思政元素、价值引领成长的教学路径，系统性地培养服务国家现代化建设的复合型科技人才，引导学生树立科技报国、绿色发展和协作创新等核心价值观。
1. [1]
2. [2]
3. [3]
4. [4]
  Y. Song, X. Zheng, Y. Yang, Y. Liu, J. Li, D. Wu, W. Liu, Y. Shen, X. Tian, Adv. Mater. 2024, 36, 2305835.
5. [5]
  P.J. Waller, F. Gándara, O.M. Yaghi, Acc. Chem. Res. 2015, 48, 305.
6. [6]
  M. Zhang, M. Lu, Z.L. Lang, J. Liu, M. Liu, J.N. Chang, L.Y. Li, L.J. Shang, M. Wang, S. Li, et al., Angew. Chem. Int. Ed. 2020, 59, 6500.
7. [7]
  P. Dong, A. Zhang, T. Cheng, J. Pan, J. Song, L. Zhang, R. Guan, X. Xi, J. Zhang, Chin. J. Catal. 2022, 43, 2592.
8. [8]
  L. Sun, W. Wang, T. Kong, H. Jiang, H. Tang, Q.J. Liu, J. Mater. Chem. A 2022, 10, 22531.
9. [9]
  W.L. Jia, X. Wu, Y. Liu, J.Y. Zhao, Y. Zhang, P.F. Liu, Q. Cheng, H.G. Yang, J. Mater. Chem. A 2022, 10, 25586.
10. [10]
  S. Wang, L. Huang, L. Xue, Q. Kang, L. Wen, K. Lv, Appl. Catal. B: Environ. 2024, 358, 124366.
11. [11]
  S. Bao, Q. Tan, S. Wang, J. Guo, K. Lv, S.A.C. Carabineiro, L. Wen, Appl. Catal. B: Environ. 2023, 330, 122624.
12. [12]
  C.G. Pope, J. Chem. Educ. 1997, 74(1), 129.
13. [13]
14. [14]
  C. Yang, S. Zhang, Y. Huang, K. Lv, K. Fang, X. Wu, Q. Li, J. Fan, Appl. Surf. Sci. 2020, 505, 144654.
15. [15]
  Q. Xu, L. Zhang, B. Cheng, J. Fan, J. Yu, Chem 2020, 6, 1543.
16. [16]
1. [1]
  Xinwan Zhao , Yue Cao , Minjun Lei , Zhiliang Jin , Tsubaki Noritatsu . Constructing S-scheme heterojunctions by integrating covalent organic frameworks with transition metal sulfides for efficient noble-metal-free photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(12): 100152-0. doi: 10.1016/j.actphy.2025.100152
2. [2]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
3. [3]
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4. [4]
  Yihong Shao , Rongchen Shen , Song Wang , Shijie Li , Peng Zhang , Xin Li . Composition engineering in covalent organic frameworks for tailored photocatalysis. Acta Physico-Chimica Sinica, 2025, 41(12): 100176-0. doi: 10.1016/j.actphy.2025.100176
5. [5]
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6. [6]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
  Yujin Deng , Yishuang Chen , Lijie Zhang , Huile Jin , Yun Yang , Quanlong Xu , Shun Wang . Plasmonic Au nanobipyramid assembly covalent organic framework for boosting photocatalytic hydrogen evolution through strong local electric field. Acta Physico-Chimica Sinica, 2026, 42(6): 100193-0. doi: 10.1016/j.actphy.2025.100193
13. [13]
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14. [14]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
15. [15]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
16. [16]
  Biaolin Yin , Yuanfu Deng , Dongen Lin . Exploration and Practice of Integrating Ideological and Political Education and Innovative Thinking into “Organic Chemistry” Teaching. University Chemistry, 2024, 39(2): 286-291. doi: 10.3866/PKU.DXHX202308026
17. [17]
  Deyun Ma , Fenglan Liang , Qingquan Xue , Yanping Liu , Chunqiang Zhuang , Shijie Li . Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Physico-Chimica Sinica, 2025, 41(12): 100190-0. doi: 10.1016/j.actphy.2025.100190
18. [18]
  Wenjun Zhu , Chenbin Ai , Kaiqiang Xu , Yatai Zhou , Xidong Zhang , Yong Zhang . WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production. Acta Physico-Chimica Sinica, 2026, 42(3): 100184-0. doi: 10.1016/j.actphy.2025.100184
19. [19]
  Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-0. doi: 10.1016/j.actphy.2025.100149
20. [20]
  Kaiqiang Xu , Jia Yu , Wei Xia , Jianjun Zhang , Sheng Han . Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity. Acta Physico-Chimica Sinica, 2026, 42(7): 100211-. doi: 10.1016/j.actphy.2025.100211

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

S型异质结富硫空位Sv-ZnIn2S4/TpPa-1的构筑及其光催化制氢研究——推荐一个创新化学实验

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通讯作者: 陈斌, bchen63@163.com

S型异质结富硫空位Sv-ZnIn₂S₄/TpPa-1的构筑及其光催化制氢研究——推荐一个创新化学实验