Citation: Rui-Ting Gao, Xiaotian Guo, Lei Wang. BiVO₄基光阳极用于太阳能水分解性能的研究进展[J]. University Chemistry, ;2026, 41(8): 162-175. doi: 10.12461/PKU.DXHX202507100 shu

BiVO₄基光阳极用于太阳能水分解性能的研究进展

College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, Inner Mongolia Autonomous Region, China

Corresponding author: Lei Wang, wanglei@imu.edu.cn
Received Date: 21 July 2025
Accepted Date: 16 September 2025

光电化学(PEC)水分解是将太阳能转化成氢能的关键技术之一。在众多半导体光阳极材料中，BiVO₄因其适中的带隙(2.4-2.5 eV)、良好的化学稳定性、环境友好以及易于合成等优点，被视为是一种极具潜力的候选材料。然而，其PEC效率受到载流子迁移速率以及严重的体相与表面复合的限制。近期研究表明，通过针对性的改性策略可以有效克服这些瓶颈，显著提升BiVO₄的光电化学性能。本文系统综述了关键的优化策略，包括纳米结构调控、掺杂(本征/外源)、异质结构筑、表面钝化以及助催化剂负载，并分析了这些策略对电荷分离与传输动力学的影响。最后，对BiVO₄基光电化学系统未来的研究方向进行了展望。
- Photoelectrochemistry,
- BiVO₄-based photoanodes,
- Water splitting,
- Charge carrier
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BiVO₄基光阳极用于太阳能水分解性能的研究进展