Citation:
Gang Ma, Siyu Jin, Bo Zheng, Lingyan Gao. Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials[J]. University Chemistry,
;2026, 41(4): 275-279.
doi:
10.12461/PKU.DXHX202504088
-
Bound water plays a pivotal role in maintaining biomacromolecular structures and facilitating their specific functions through mechanisms such as hydrogen-bond anchoring and hydrophobic association. Inspired by these natural phenomena, researchers have incorporated bound water as a functional structural unit into polymer networks through biomimetic design and molecular engineering. This innovative approach overcomes the conventional limitation of “water-induced softening” and instead utilizes water molecules to regulate material mechanical properties, enabling the fabrication of polymer materials with high toughness, environmental adaptability, and energy dissipation capabilities. This review systematically summarizes recent advances in polymer performance modulation through the introduction of bound water into polymer networks and the manipulation of interactions between bound water and polymeric structural elements.
-
Keywords:
- Bound water,
- Hydrogen bonding,
- Polymers,
- Mechanical property
-
-
-
[1]
P. Ball, Chem. Rev. 2008, 108 (1), 74.
-
[2]
-
[3]
-
[4]
M. Hishida, A. Kaneko, Y. Yamamura, K. Saito, J. Phys. Chem. B 2023, 127, 6296.
-
[5]
-
[6]
M.W. Trim, M.F. Horstemeyer, H. Rhee, H.E. Kadiri, L.N. Williams, J. Liao, K.B. Walters, J. McKittrick, S. Park, J. Acta. Biomater. 2011, 7 (3), 1228.
-
[7]
M.S. Jhon, J.D. Andrade, J. Biomed. Mater. Res. 1973, 7 (6), 509.
-
[8]
H. Arazoe, D. Miyajima, A. Kouki, F. Araoka, E. Sato, T. Hikima, M. Kawamoto, T. Aida, Nat. Mater. 2016, 15 (10), 1084.
-
[9]
M. Ma, L. Guo, D. G. Anderson, R. Langer, Science 2013, 339 (6116), 186.
-
[10]
X. Ming, L. Yao, H. Zhu, Q. Zhang, S. Zhu, Adv. Funct. Mater. 2022, 32, 2109850.
-
[11]
S. Dong, J. Leng, Y. Feng, M. Liu, C.J. Stackhouse, A. Schönhal, L. Chiappisi, L. Gao, W. Chen, J. Shang, et al., Sci. Adv. 2017, 3 (11), eaao0900.
-
[12]
Q. Zhang, T. Li, A. Duan, S. Dong, W. Zhao, P.J. Stang, J. Am. Chem. Soc. 2019, 141, 8058.
-
[13]
T. Li, Q. Zhang, D. Li, S. Dong, W. Zhao, P. Stang, J. ACS Appl. Mater. Interfaces. 2020, 12, 38700.
-
[14]
C. Cai, S. Wu, Y. Zhang, F. Li, Z. Tan, S. Dong, Nat. Commun. 2024, 15, 3929.
-
[15]
C. Cai, Y. Pan, Y. Zhang, F. Li, Z. Tan, S. Dong, CCS Chem. 2025, 7, 2520.
-
[16]
K. Gong, L. Hou, P. Wu, Adv. Mater. 2022, 34, 2201065.
-
[17]
J. Xu, B. Wu, L. Hou, P. Wu, Small 2024, 20 (36), 2401164.
-
[18]
X. Zhang, S. Dong, X. Yang, L. Wang, G. Li, T.W. Wong, T. Li, W. Yang, Z. Luo, Science 2025, 387 (6737), 967.
-
[1]
-
-
-
[1]
Ke Liu , Qi Gao , Haifeng Li , Lipeng Diao , Xuegang Chen , Daohao Li , Guanglei Wu . Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance. Acta Physico-Chimica Sinica, 2026, 42(8): 100315-0. doi: 10.1016/j.actphy.2026.100315
-
[2]
Xinmeng Huang , Haoran Zhang , Mengxin Liu , Ying Miao , Zhenxi Yu , Qi Wu , Lei Pan . A densified conductive network of carbon nanotube-bridged vertical ZnO arrays for enhanced electromagnetic interference shielding, mechanical, and thermal properties of carbon fiber/polymer composites. Acta Physico-Chimica Sinica, 2026, 42(10): 100293-. doi: 10.1016/j.actphy.2026.100293
-
[3]
Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
-
[4]
Xiaoyi Sun , Duohang Bi , Hankun Qiao , Yijing Liu , Jintao Zhu . Painless Injection: Microneedles Revolutionizing Beauty and Health Brought. University Chemistry, 2025, 40(10): 166-174. doi: 10.12461/PKU.DXHX202411006
-
[5]
Zhen FAN , Jiayan WANG , Wenhao ZHU , Xiuchun ZHANG , Yang WANG , Hao LI , Zeyuan WANG , Songzhi ZHENG , Weihai SUN . Fabrication of CsPbBr3 perovskite solar cells using buried polyvinylidene fluorideinterface modification method. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2464-2478. doi: 10.11862/CJIC.20250191
-
[6]
Wenjun Zhu , Chenbin Ai , Kaiqiang Xu , Yatai Zhou , Xidong Zhang , Yong Zhang . WO3@TP inorganic@organic S-scheme photocatalyst for boosting H2O2 production. Acta Physico-Chimica Sinica, 2026, 42(3): 100184-0. doi: 10.1016/j.actphy.2025.100184
-
[7]
Cong Liu , Yuling Huang , Peng Zhen , Hualiu Li , Bingjia Xu , Suilian Luo , Guang Shi . A Comprehensive Design Experiment: Preparation and Property Characterization of Polymer Room-Temperature Phosphorescence Materials. University Chemistry, 2026, 41(4): 409-416. doi: 10.12461/PKU.DXHX202503092
-
[8]
Xinyi MA , Yuhang XIAO , Qian LI , Zihuan YAN , Chengyan LIU , Xiguang GAO , Hongju YIN , Feixiang CHENG . Thienyl metal coordination polymers: Preparation and photocatalytic degradation performance of phenol. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 969-979. doi: 10.11862/CJIC.20250317
-
[9]
Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO2-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
-
[10]
Heng Zhang , Ying Ma , Shiling Yuan . Machine Learning-based Prediction of Antifouling Performance in Polymer Materials: An Integrated Molecular Simulation Experiment. University Chemistry, 2026, 41(1): 346-353. doi: 10.12461/PKU.DXHX202506015
-
[11]
Jinyang SUI , Zhonghao NIU , Hao XU , Jingli XIE . Zinc(Ⅱ) coordination polymers from mixed triazole and carboxylate ligands: Synthesis and properties for CO2 cycloaddition and photocatalytic dye degradation. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1603-1612. doi: 10.11862/CJIC.20260089
-
[12]
Wenhao Zhang , Haisheng Fang , Lijuan Liu , Huaihao Tang , Chengyi Xiao , Weiwei Li . Spacer isomerization engineering in double-cable conjugated polymers for optimized molecular packing and enhanced photovoltaic performance. Acta Physico-Chimica Sinica, 2026, 42(10): 100229-. doi: 10.1016/j.actphy.2025.100229
-
[13]
Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
-
[14]
Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
-
[15]
Hongbo Hou , Qian Yang , Yi Gao , Yang Ou , Zhuang Wang , Shun Yi , Jingfeng He , Li Ma , Fanbin Meng . Progress in supercritical CO2 foamed polymer composites for electromagnetic protection: from rational structural design to absorption-dominated performance. Acta Physico-Chimica Sinica, 2026, 42(10): 100300-. doi: 10.1016/j.actphy.2026.100300
-
[16]
Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
-
[17]
Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
-
[18]
Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
-
[19]
Zhao Gao , Jianxiang Sun , Bin Mu , Yi Yan , Wei Tian . Exploration of Supramolecular Polymer “Chameleons” in Innovative Chemistry Experiments. University Chemistry, 2026, 41(4): 349-355. doi: 10.12461/PKU.DXHX202504044
-
[20]
Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(454)
- HTML views(89)
Login In
DownLoad: