引用本文:
于卫峰, 卓峻峭. 金刚烷及四氮杂金刚烷立体异构分析[J]. 大学化学,
2026, 41(6): 434-440.
doi:
10.12461/PKU.DXHX202503125
Citation: Weifeng Yu, Junqiao Zhuo. Stereoisomeric Analysis of Adamantane and Hexamethylenetetramine[J]. University Chemistry, 2026, 41(6): 434-440. doi: 10.12461/PKU.DXHX202503125
Citation: Weifeng Yu, Junqiao Zhuo. Stereoisomeric Analysis of Adamantane and Hexamethylenetetramine[J]. University Chemistry, 2026, 41(6): 434-440. doi: 10.12461/PKU.DXHX202503125
金刚烷及四氮杂金刚烷立体异构分析
English
Stereoisomeric Analysis of Adamantane and Hexamethylenetetramine
Abstract:
Through structural investigation of hexamethylenetetramine (C6H12N4), we developed a “tetrahedral” model for analyzing adamantane molecular structures using chemical spatial thinking. This study proposes a novel approach for examining stereoisomerism (particularly enantiomerism) in disubstituted adamantane and hexamethylenetetramine derivatives, characterized by three distinct substitution patterns: same-ring same-carbon, same-ring different-carbon, and different-ring different-carbon. Systematic analysis of disubstituted hexamethylenetetramine (C6H12N4) and adamantane (C10H16) stereostructures was conducted using this tetrahedral model. Notably, the three-dimensional tetrahedral model can be dimensionally reduced to a two-dimensional planar triangle configuration, thereby establishing an innovative methodology for stereostructural analysis of these disubstituted compounds. This approach may offer new perspectives for investigating analogous stereochemical systems.
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Key words:
- Adamantane
- / Tetrahedral
- / Model
- / Spatial thinking
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[1]
李梦雪, 吴俊明. 化学教学, 2020, No. 4, 15.
-
[2]
卓峻峭. 化学教学, 2023, No. 6, 93.
-
[3]
刘志华, 张玉琪, 刘必富, 刘俊华. 化学教育(中英文), 2023, 44(5), 79.
-
[4]
于卫峰. 化学教育(中英文), 2025, 46(9), 111.
-
[5]
谷方致, 王建基. 高等学校化学学报, 1991, No. 5, 677.
-
[6]
H. Stetter, Angew. Chem.Int. Ed. 1962, 1(6), 286.H. Stetter, Angew. Chem.Int. Ed. 1962, 1(6), 286.
-
[7]
R.C. Fort, P.R. Schleyer, Chem. Rev. 1964, 64(3), 277.R.C. Fort, P.R. Schleyer, Chem. Rev. 1964, 64(3), 277.
-
[8]
曾昭琼. 有机化学(上册). 第4版. 北京: 高等教育出版社, 2004.
-
[9]
刘元国. 化学教学, 1998, No. 6, 46.
-
[10]
陈益. 化学教学, 1999, No. 5, 44.
-
[11]
严业安. 化学教育, 2004, No. 11, 56.
-
[12]
中华人民共和国教育部. 普通高中化学课程标准(2017年版2020年修订). 北京: 人民教育出版社, 2020.
-
[13]
董顺. 化学教学, 2016, No. 8, 65.
-
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