Citation: Cong Liu, Yuling Huang, Peng Zhen, Hualiu Li, Bingjia Xu, Suilian Luo, Guang Shi. A Comprehensive Design Experiment: Preparation and Property Characterization of Polymer Room-Temperature Phosphorescence Materials[J]. University Chemistry, ;2026, 41(4): 409-416. doi: 10.12461/PKU.DXHX202503092 shu

A Comprehensive Design Experiment: Preparation and Property Characterization of Polymer Room-Temperature Phosphorescence Materials

Cong Liu ¹ ,
Yuling Huang ¹ ,
Peng Zhen ¹ ,
Hualiu Li ² ,
Bingjia Xu ³ ,
Suilian Luo ¹ ,
Guang Shi ^1,,

1.
School of Chemistry, South China Normal University, Guangzhou 510006, Guangdong Province, China;
2.
School of Physics, South China Normal University, Guangzhou 510006, Guangdong Province, China;
3.
School of Environmental and Chemical Engineering, Wuyi University, Jiangmen 529020, Guangdong Province, China

Corresponding author: Guang Shi, shiguang@scnu.edu.cn
Received Date: 21 March 2025
Accepted Date: 21 May 2025

Addressing the limitations in comprehensiveness and innovation within undergraduate material chemistry experiments, this comprehensive experiment was developed by incorporating the cutting-edge research area of “polymer room-temperature phosphorescence materials.” The experiment integrates polymer material preparation, characterization, and the evaluation of room-temperature phosphorescence properties along with their applications. Through this experimental design, students not only deepen their understanding of the relationship between polymer synthesis, structure, and properties, but also expand their knowledge of advanced optoelectronic functional materials, particularly polymer room-temperature phosphorescence materials. This approach effectively enhances students' innovative and practical capabilities, fosters a collaborative learning environment among peers, and cultivates a scientific research ethos characterized by continuous exploration and the pursuit of excellence.
- Melamine-formaldehyde resin,
- Room temperature phosphorescence,
- Anti-counterfeiting,
- Comprehensive design experiment
1. [1]
  L.Q. Li, J.Y. Zhou, J.Y. Han, D.P. Liu, M. Qi, J.F. Xu, G.Q. Yin, T. Chen, Nat. Commun. 2024, 15, 3846.
2. [2]
  J.Q. Gu, W.T. Yuan, K. Chang, C. Zhong, Y.F. Yuan, J.H. Li, Y.F. Zhang, T. Deng, Y.Y. Fan, L.K. Yuan, et al. Angew. Chem. Int. Ed. 2025, 64(3), e202415637.
3. [3]
  X. Peng, P. Zou, J. Zeng, X. Wu, D. Xie, Y. Fu, D. Yang, D. Ma, B.Z. Tang, Z. Zhao, Angew. Chem. Int. Ed. 2024, 63 (29), e202405418.
4. [4]
  Y. Li, Z.Z. Huang, A.X. Shao, Z.Q. Wu, Z.Y. He, H. Tian, X. Ma, Chem. Sci. 2025, 16 (15), 6290.
5. [5]
  Q.K. Li, X. Huang, H. Hou, F.L. Guo, X.J. Wang, M.Y. He, Y.K. Wang, Y.S. Zhang, L.J. Qu, K.T. Wang, et al. ACS Appl. Mater. Interfaces 2024, 16 (50), 69891.
6. [6]
  H.Y. Yang, Y.F. Wang, X.K. Yao, H.L. Ma, J.M. Yu, X. Li, X. Wang, X.Y. Liang, Q.M. Peng, S.Z. Cai, et al. J. Am. Chem. Soc. 2025, 147 (2), 1474.
7. [7]
  L. Zhan, Y. Xu, T. Chen, Y. Tang, C. Zhong, Q. Lin, C. Yang, S. Gong, Aggregate 2024, 5 (3), e485.
8. [8]
  M. Sing, K. Shen, W. Ye, Y.H. Gao, A.Q. Lv, K. Liu, H.L. Ma, Z.G. Meng, H.F. Shi, Z. F. An, Angew. Chem. Int. Ed. 2024, 63 (14), e202319694.
9. [9]
  K. Chen, Y. Xiong, D.L. Wang, Y.W. Pan, Z. Zhao, D. Wang, B.Z. Tang, Adv. Funct. Mater. 2024, 34 (12), 2312883.
10. [10]
  X. Yang, G.I.N. Waterhouse, S. Lu, J.H. Yu, Chem. Soc. Rev. 2023, 52 (22), 8005.
11. [11]
  X. Chen, G. Wang, X. Piao, K.K. Zhang, Chem. - Eur. J. 2024, 30 (18), e202303834.
12. [12]
  Q. Feng, S. Zhu, B. Wang, F. Yu, H. Li, M.N. Yu, L.H. Xie, Adv. Funct. Mater. 2024, 34 (14), e2312622.
13. [13]
  Y.H. Liang, P.T. Hu, H.Q. Zhang, C. Liu, Y.H. Wang, S.L. Luo, G. Shi, Z.G. Chi, B.J. Xu, Angew. Chem. Int. Ed. 2024, 63 (10), e202318516.
14. [14]
  Y.H. Liang, Y.T. Gao, S. Chang, J. Lv, B.B. Chen, D.W. Li, J. Mater. Chem. C. 2024, 12 (6), 1945.
15. [15]
  Y.H. Liang, Y.T. Zheng, J.A. Li, S.L. Luo, C. Liu, G. Shi, F.Q. Sun, Z.G. Chi, B.J. Xu, Angew. Chem. Int. Ed. 2022, 61 (23), e202201820.
16. [16]
  W. Zhao, Z. He, B.Z. Tang, Nat. Rev. Mater. 2020, 5 (12), 869.
17. [17]
18. [18]
1. [1]
  Yuecheng ZHANG , Fan YANG , Shiyu ZHANG , Chengjun MA , Rui TIAN , Xuehua SUN , Haoyu LI , Lingbo SUN , Hongyan MA . B-doped carbon quantum dots with long-afterglow room-temperature phosphorescence: Applications in information encryption and humidity sensing. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1361-1370. doi: 10.11862/CJIC.20240415
2. [2]
  Chunyuan Kang , Xiaoyu Li , Fan Yang , Bai Yang . Ionic-bond crosslinked carbonized polymer dots for tunable and enhanced room temperature phosphorescence. Acta Physico-Chimica Sinica, 2026, 42(1): 100156-0. doi: 10.1016/j.actphy.2025.100156
3. [3]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
4. [4]
  Wenwei Zeng , Qingyu Sun , Mengxiang Liang , Lirong Lin , Laiying Zhang . Unveiling Anti-Counterfeiting Secrets: Excitation-Dependent Luminescence in Sb³⁺-Doped Perovskite Materials. University Chemistry, 2026, 41(2): 375-384. doi: 10.12461/PKU.DXHX202503036
5. [5]
  Wanchun Zhu , Bing Zhou , Tengfeng Xie , Jingqi Guan , Xu Zhao . 物理化学综合设计实验教学思考与体会. University Chemistry, 2025, 40(8): 33-37. doi: 10.12461/PKU.DXHX202409139
6. [6]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
7. [7]
  Yuanchun Pan , Xinyun Lin , Leyi Yang , Wenya Hu , Dekui Song , Nan Liu . Artificial Intelligence Science Practice: Preparation of Electronic Skin by Chemical Vapor Deposition of Graphene. University Chemistry, 2025, 40(11): 272-280. doi: 10.12461/PKU.DXHX202412052
8. [8]
  Guanghui Wang , Chen Qian , Zhiyong Ma . Preparation and Characterization of 7H-Benzo[C]Carbazole Based Ultra-Long Organic Room Temperature Phosphorescence Material. University Chemistry, 2025, 40(11): 289-299. doi: 10.12461/PKU.DXHX202412062
9. [9]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
10. [10]
  Wenli FENG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress on ultralong room temperature phosphorescent carbon dots. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 833-846. doi: 10.11862/CJIC.20240308
11. [11]
  Tiantian Zheng , Huiyi Wang , Huimin Li , Xuanhe Liu , Hong Shang . Anti-Counterfeiting National Salvation Chronicle of 006. University Chemistry, 2024, 39(9): 254-258. doi: 10.3866/PKU.DXHX202307032
12. [12]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
13. [13]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
14. [14]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
15. [15]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
16. [16]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
17. [17]
  Xianggui Kong , Wenying Shi . Comprehensive Chemical Experimental Design of Optically Encrypted Materials. University Chemistry, 2025, 40(3): 355-362. doi: 10.12461/PKU.DXHX202406067
18. [18]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
19. [19]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
20. [20]
  Wenxu Liu , Feng Han , Boxuan Wang , Huayi Liu , Xiaobin Gu , Xin Zhang , Yao Liu . Comprehensive Chemical Experiment: Design, Synthesis, and Photoelectronic Properties Study of Fully Non-Fused Ring Electron Acceptors. University Chemistry, 2025, 40(10): 263-275. doi: 10.12461/PKU.DXHX202412021

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(180)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142