Citation: Linjie Wang, Zhao Wei, Ming Gao, Xiaohui Zheng, Xinghai Hao. Item Development in the Context of Academic Exploration: Materials, Key Considerations, and Suggestions: A Case Study on the Research and Development of Polynitrogen Compounds[J]. University Chemistry, ;2026, 41(2): 411-419. doi: 10.12461/PKU.DXHX202503033 shu

Item Development in the Context of Academic Exploration: Materials, Key Considerations, and Suggestions: A Case Study on the Research and Development of Polynitrogen Compounds

1.
NO. 1 Middle School affiliated to Central China Normal University, Wuhan 430223, China;
2.
Hubei Provincial Education Science Research Institute, Wuhan 430079, China

Corresponding author: Zhao Wei, 51397192@qq.com
Received Date: 10 March 2025
Revised Date: 25 March 2025

In the 2017 national college entrance examination, a test question was designed based on the pentazole anion (cyclo-N₅^-) salt reported by Chinese scholars. Since then, the number of test questions related to polynitrogen compounds has gradually increased. By reviewing the research and development history of polynitrogen compounds and analyzing test questions derived from these materials, scientific inaccuracies were identified in some cases. Therefore, when developing test items in the context of academic exploration, particular attention should be given to ensuring accuracy, relevance, and the backwash effect.
- Test item development,
- Academic exploration context,
- Polynitrogen compound,
- Pentazole anion
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
  Wang, P. C.; Xu, Y. G.; Lin, Q. H.; Lu, M. Chem. Soc. Rev. 2018, 47 (20), 7522.
6. [6]
7. [7]
  Cacace, F.; De petris, G.; Troiani, A. Science 2002, 295 (5554), 480.
8. [8]
  Oleg, V. M.; Denis, V. C. Chem. Phys. Lett. 2020, 753, 137594.
9. [9]
  Lang, Q.; Xu, Y. G.; Jiang, S. J.; Lu, M. New J. Chem. 2022, 46 (29), 14170.
10. [10]
  Th. Curtius. Ber. Dtsch. Chem. Ges 1890, 23 (2), 3023.
11. [11]
  Christe, K. O.; Wilson, W. W.; Sheehy, J. A.; Boatz J. A. Angew. Chem. Int. Ed. 1999, 38 (13), 2004.
12. [12]
  Xia, H. L.; Zhang, W. Q.; Cao, Y. T.; Zhang, Q. H. CrystEngComm 2021, 23 (33), 5551.
13. [13]
  Mikhail, I. E.; Alexander G. G.; Ivan A. T.; Dzivenko, D. A.; Boehler, R. Nat. Mater. 2004, 3 (8), 558.
14. [14]
  Klapotke, T. M. Chemistry of High-Energy Materials. De Gruyter, Berlin, 2012.
15. [15]
16. [16]
  Greenwood, N. N.; Earnshaw, E. Chemistry of the Elements 1984, (2), 835.
17. [17]
  Minh Tho Nguyen. Coord. Chem. Rev. 2003, 244 (1), 93.
18. [18]
  Vij, A.; Wilson, W. W.; Vij, V.; Tham, F. S.; Sheehy, J. A.; Christe, K. O. J. Am. Chem. Soc. 2001, 123 (26), 6308.
19. [19]
  Seminario, J. M.; Politzer, P. Chem. Phys. Lett. 1989, 159 (1), 27.
20. [20]
  Francl, M. M.; Chesick, J. P. J. Phys. Chem. 1990, 94, 526.
21. [21]
  Bittererová, M.; Östmark, H.; Brinck, T. Chem. Phys. Lett. 2001, 347, 220.
22. [22]
23. [23]
  Tan, B. S.; Huang, M.; Long, X. P.; Li, J. S.; Yuan, X. D.; Xu, R. J. Int. J. Quantum Chem 2015, 115 (2), 84.
24. [24]
  Hao Liu, Yong Zhang, Ruying London Li, Abou-Rachid, H.; Lussier L. S.; Sun, X. Int. J. Energ. Mater. Ch. 2010, 9, 55.
25. [25]
26. [26]
  Bräse, S.; Gil, C.; Knepper, K.; Zimmermann, V. Angew. Chem. Int. Ed. 2005, 44 (33), 5188.
27. [27]
  Tashrifi, Z.; Khanaposhtani, M. M.; Larijani, B.; Mahdavi, M. ChemistrySelect 2021, 6 (47), 13419.
28. [28]
  Wilson, W. W.; Vij, A.; Boatz, J. A.; Christe, K. O. J. Fluor. Chem. 2022, 263, 110042.
29. [29]
  Dixon, D. A.; Feller, D.; Christe, K. O.; Wilson, W. W.; Vij, A.; Vij, V.; Jenkins, H. D. B.; Olson, R. M.; Gordon, M. S. J. Am. Chem. Soc. 2004, 126 (3), 834.
30. [30]
  Bazanov, B.; Geiger, U.; Carmieli, R.; Grinstein, D.; Welner, S.; Haas, Y. Angew. Chem. Int. Ed. 2016, 55 (42), 13233.
31. [31]
  Zhang, C.; Sun, C. G.; Hu, B. C.; Yu, C. M.; Lu, M. Science 2017, 355 (6323), 374.
32. [32]
  Zhang, C.; Yang, C.; Hu, B. C.; Yu, C. M.; Zheng, Z. S.; Sun, C. G. Angew. Chem. Int. Ed. 2017, 56 (16), 4512.
33. [33]
  Sun, C. G.; Zhang, C.; Jiang, C.; Yang, C.; Du, Y.; Zhao, Y.; Hu, B. C.; Zheng, Z. S.; Christe, K. O. Nat. Commun. 2018, 9 (1), 1269.
34. [34]
  Chen, L.; Yang, C. Hu, H. R.; Shi, L.; Zhang, C.; Sun, C. G.; Gao, C.; Du, Y.; Hu, B. C. CrystEngComm 2022, 24 (46), 8152.
35. [35]
36. [36]
37. [37]
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