二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用

引用本文: 杨佳艺, 郝建秀, 周华从, 刘全生. 二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用[J]. 大学化学, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105 shu

Citation: Jiayi Yang, Jianxiu Hao, Huacong Zhou, Quansheng Liu. “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles[J]. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105 shu

二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用

1.
内蒙古工业大学化工学院, 呼和浩特 010051;
2.
内蒙古自治区绿色化工重点实验室, 呼和浩特 010051;
3.
二氧化碳资源化利用自治区高等学校重点实验室, 呼和浩特 010051

通讯作者: 郝建秀,E-mail:hjx2020@imut.edu.cn

基金项目:
国家自然科学基金(22468036, 22468035, 22368038)；内蒙古工业大学研究生教育教学改革项目(YJG2024007)；内蒙古自治区自然科学基金杰出青年项目(2022JQ04)；内蒙古自治区自然科学基金青年项目(2024QN02018)；内蒙古自治区科技重大专项(2021ZD0020)；内蒙古工业大学科研启动金项目(BS2021018)

摘要: 二氧化碳(CO₂)的大量排放引发了一系列环境问题，但同时CO₂也是一种重要的碳资源。因此，捕获CO₂并将其转化为高附加值化学品，已成为科学与工业领域的热点课题。从化学角度而言，CO₂被视作一种稳定、安全且储量丰富的C1资源。将CO₂转化为高值化学品，不仅能有效解决CO₂排放问题，同时实现了CO₂的资源化利用。把CO₂催化环化加成到环氧化物中，制备高附加值的环状碳酸酯，是一种反应过程简单且前景可观的CO₂利用策略，该反应无副产物产生，原子经济性100%，反应条件温和。本文综述了CO₂化学利用途径，着重介绍了CO₂环加成反应高效催化剂，并对不同类型催化剂的性能进行了比较，最后对CO₂环加成反应研究进展进行了总结与展望。

关键词:

English

“Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles

1.
College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;
2.
Inner Mongolia Key Laboratory of Green Chemical Engineering, Hohhot 010051, China;
3.
Key Laboratory of CO₂ Resource Utilization at Universities of Inner Mongolia Autonomous Region, Hohhot 010051, China

Corresponding author: Jianxiu Hao, hjx2020@imut.edu.cn

Received Date: 20 February 2025
Revised Date: 10 March 2025
Available Online: 14 March 2025

Abstract: The massive emission of carbon dioxide (CO₂) has led to a series of environmental challenges; however, CO₂ is also a valuable carbon resource. As a result, capturing CO₂ and converting it into high-value chemicals has become an urgent area of research in both science and industry. Chemically, CO₂ is considered a stable, safe, and abundant C1 resource. Converting CO₂ into high-value chemicals not only addresses the issue of CO₂ emissions but also facilitates its resource utilization. Among the various methods, the catalytic addition of CO₂ to epoxides for the preparation of high-value cyclic carbonates is a promising strategy for CO₂ utilization. This process is atomically efficient (100%), generates no by-products, and operates under mild reaction conditions. This review discusses the chemical utilization pathways of CO₂, emphasizes efficient catalysts for the CO₂ cycloaddition reaction, compares the catalytic activities of different types of catalysts, and concludes with a summary and outlook on the progress in CO₂ cycloaddition research.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用

通讯作者: 郝建秀,E-mail:hjx2020@imut.edu.cn

English

“Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles

Corresponding author: Jianxiu Hao, hjx2020@imut.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用

通讯作者: 郝建秀,E-mail:hjx2020@imut.edu.cn

English

“Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles

Corresponding author: Jianxiu Hao, hjx2020@imut.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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