Citation: Shuai Yuan, Yaofeng Yuan. Academician Chengye Yuan and Organic Phosphorus Chemistry[J]. University Chemistry, ;2025, 40(7): 393-400. doi: 10.12461/PKU.DXHX202409123 shu

Academician Chengye Yuan and Organic Phosphorus Chemistry

Shuai Yuan ,
Yaofeng Yuan

College of Chemistry, Fuzhou University, Fuzhou 350108, China

Received Date: 27 September 2024
Revised Date: 16 January 2025

Yuan Chengye is the pioneer in the field of extractant chemistry in China. In response to national defense needs such as the “Two Bombs, One Satellite” program, he successfully developed key extractants, including P204 (bis(2-ethylhexyl)phosphoric acid ester) and P350 (methylphosphonic acid dimethylheptyl ester). He also developed various phosphorus extractants, such as P507 (2-ethylheptylphosphonic acid-2-ethylheptyl ester), based on the comprehensive utilization of non-ferrous metals. Mr. Yuan Chengye’s team conducted extensive research on the structure and performance of extractants, based on a large amount of experimental data. Through in-depth analysis using quantum chemistry, molecular mechanics, thermodynamics, and other testing methods, they enhanced the chemical properties of organic phosphorus extractants to a new level. These studies provide a solid theoretical foundation for the design and optimization of extractants and have also advanced industrial applications.
- Organic phosphorus chemistry,
- Extractant,
- Scientist spirit,
- Nuclear fuel
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
  Yuan, C. Y. Some Problems in Chemical Structures and Properties of Organic Extractants. Proceedings of the International Solvent Extraction Conference, Liege, Belgium, Sept 6–12, 1980; Assoc. des Ingénieurs Sortis de l'Univ.: Liège, Belgium, 1980.
8. [8]
  Li, D. J. Rare Earths 2019, 37 (5), 468.
9. [9]
10. [10]
  Li, J. J. Michaelis–Arbuzov phosphonate synthesis. In Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications; Li, J. J. Ed.; Springer: Berlin and Heidelberg, Germany, 2009; pp. 357–358.
11. [11]
12. [12]
13. [13]
  Yuan, C. Y.; Ding, Y. Y. Acta Chim. Sin. 1987, 5 (1), 73.
14. [14]
  Ma, E. X.; Yan, J. Y.; Wang, S. Y.; Long, H. Y.; Yuan, C. Y. Sci. China Math. 1981, 29 (9), 1237.
15. [15]
  Ma, E. X.; Yan, J. Y.; Wang, G. L.; Yuan, C. Y. Chin. Sci. Bull. 1980, 25 (11), 911.
16. [16]
17. [17]
18. [18]
  Yuan, C. Y.; Yan, J. Y.; Feng, H. Z.; Long, H. Y.; Wu, F. B.; Jin, P. L. Sci. China Ser. B 1987, No. 7, 681.
19. [19]
  Li, S. S.; Cheng, Z. Y.; Yuan, C. Y. Sci. China Ser. B 1989, No. 10, 1172.
20. [20]
21. [21]
1. [1]
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