Citation: Nan Wu,  Hang Zhang,  Lingling Wei,  Quan Gu,  Haoquan Zheng,  Weiqiang Zhang,  Rui Cao. Cyanide: Poison or Treasure?[J]. University Chemistry, ;2025, 40(7): 177-188. doi: 10.12461/PKU.DXHX202409072 shu

Cyanide: Poison or Treasure?

  • Corresponding author: Hang Zhang,  Haoquan Zheng, 
  • Received Date: 19 September 2024
    Revised Date: 6 November 2024

  • Cyanides are widely present in nature and are highly toxic, often evoking significant concern. The development of human civilization and scientific technology has led to a gradual deepening of the exploration of cyanides, with continuous advancements in understanding and comprehension. However, they are also essential components of the Earth’s primordial atmosphere and play a crucial role as reactive intermediates in the synthesis of key biomolecules, such as amino acids. Hydrocyanic acid and its salts are of critical importance in various industrial processes, including electroplating, dyeing, washing, painting, rubber manufacturing, textiles, and gold mining. Moreover, cyanides are important research subjects in modern medicine and energy fields. This paper explores the dual nature of cyanides, highlighting their role as both a remnant of early Earth’s atmosphere and a catalyst for technological progress. By examining their industrial applications and potential research directions, the paper aims to shed light on the complex role of cyanides in the advancement of human civilization and their ongoing potential for future exploration.
  • 加载中
    1. [1]

    2. [2]

    3. [3]

    4. [4]

      Schulz, A.; Surkau, J. Rev. Inorg. Chem. 2023, 43(1), 49.

    5. [5]

      Wang, L.; Shao, Y.; Cheng, J. Org. Biomol. Chem. 2021, 19(40), 8646.

    6. [6]

      Birckenbach, L.; Huttner, K. Ber. Dtsch. Chem. Ges. 1929, 62(1), 153.

    7. [7]

      Birckenbach, L.; Kellermann, K. Ber. Dtsch. Chem. Ges. 1925, 58(10), 2377.

    8. [8]

      Birckenbach, L.; Kellermann, K. Ber. Dtsch. Chem. Ges. 1925, 58(4), 786.

    9. [9]

      Black, J. H.; Dishoeck, E. F. V. Astrophys. J. 1991, 369 (1), L9.

    10. [10]

      Arulsamy, N.; Bohle, D. S.; Doletski, B. G. Inorg. Chem. 1999, 38(11), 2709.

    11. [11]

      Brand, H.; Mayer, P.; Schulz, A.; Weigand J. J. Angew. Chem. Int. Ed. 2005, 44(25), 3929.

    12. [12]

      Grundmann, C.; Fulton, M. B. Chem. Ber. 1964, 97(2), 566.

    13. [13]

      Hocking, W. H.; Gerry, M. C. L. J. Mol. Spectrosc. 1976, 59(3), 338.

    14. [14]

      Corain, B. Coord. Chem. Rev. 1984, 53, 296.

    15. [15]

      Geier, J.; Willner, H. Z. Anorg. Allg. Chem. 2008, 634, 1863.

    16. [16]

      Stetter, H. Angew. Chem. Int. Ed. 1969, 81(7), 267.

    17. [17]

      Mayer, E. Angew. Chem. Int. Ed. 1969, 81(16), 627.

    18. [18]

    19. [19]

      Roesky, H. W. Angew. Chem. Int. Ed. 1987, 99(6), 607.

    20. [20]

      Kraft, A. Bull. Hist. Chem. 2011, 36(1), 3.

    21. [21]

      Buser, H. J.; Schwarzenbach, D.; Petter, W.; Ludi, A. Inorg. Chem. 1977, 16(11), 2704.

    22. [22]

      Neff, V. D. J. Electrochem. Soc. 1978, 125(6), 886.

    23. [23]

      Hall, A. H.; Rumack, B. H. Ann. Emerg. Med. 1986, 15(9), 1067.

    24. [24]

      Baskin, S. I.; Horowitz, A. M.; Nealley, E. W. J. Clin. Pharmacol. 1992, 32(4), 368.

    25. [25]

    26. [26]

    27. [27]

    28. [28]

    29. [29]

    30. [30]

    31. [31]

      Satpathy, B.; Jena, S.; Das, S.; Das, K. Surf. Coat. Technol. 2021, 424, 127680.

    32. [32]

    33. [33]

    34. [34]

    35. [35]

    36. [36]

    37. [37]

      Abelson, P. H. Proc. Natl. Acad. Sci. U. S. A. 1966, 55(6), 1365.

    38. [38]

      Loew, G. H. J. Theor. Biol. 1971, 33(1), 121.

    39. [39]

      Moffat, J. B.; Tang, K. F. J. Theor. Biol. 1976, 58(1), 83.

    40. [40]

    41. [41]

    42. [42]

      Yadav, M.; Pulletikurti, S.; Yerabolu, J. R.; Krishnamurthy, R. Nat. Chem. 2022, 14(2), 170.

    43. [43]

      Islam, S. Nat. Chem. 2022, 14(2), 123.

    44. [44]

    45. [45]

    46. [46]

    47. [47]

    48. [48]

      Kong, B.; Selomulya, C.; Zheng, G.; Zhao, D. Chem. Soc. Rev. 2015, 44(22), 7997.

    49. [49]

      Jia, X.; Cai, X.; Chen, Y.; Wang, S.; Xu, H.; Zhang, K.; Ma, M.; Wu, H.; Shi, J.; Chen, H. ACS Appl. Mater. Interfaces 2015, 7(8), 4579.

    50. [50]

      Shu, X.; Chen, Y.; Yan, P.; Xiang, Y.; Shi, Q.; Yin, T.; Wang, P.; Liu, L.; Shuai, X. J. Control. Release 2022, 347, 270.

    51. [51]

    52. [52]

    53. [53]

    54. [54]

    55. [55]

    56. [56]

    57. [57]

    58. [58]

    59. [59]

  • 加载中
    1. [1]

      Yuxia Gao Li Zhang Chenhui Zhang Fengpei Du . Chemical Empowerment for Green Development of Pesticides: From Molecular Design to Field Application. University Chemistry, 2025, 40(12): 78-86. doi: 10.12461/PKU.DXHX202509052

    2. [2]

      Qiuping Liu Yongxian Fan Wenxian Chen Mengdi Wang Mei Mei Genrong Qiang . Design of Ideological and Political Education for the Preparation Experiment of Ferrous Sulfate. University Chemistry, 2024, 39(2): 116-120. doi: 10.3866/PKU.DXHX202309083

    3. [3]

      Sibei Mai Guo-Bin Xiao Xijiao Mu Jing Cao . “一融双高”背景下课程思政与化学研究生科研教育的融合路径. University Chemistry, 2026, 41(9): 70-81. doi: 10.12461/PKU.DXHX202509027

    4. [4]

      Mingbao Liu Tian Zhang Heng Liu Baoyue Cao Chengfang Qiaods区元素电子结构赋予的特殊物理化学性质及生理作用. University Chemistry, 2026, 41(8): 176-193. doi: 10.12461/PKU.DXHX202507120

    5. [5]

      Yu SUXinlian FANYao YINLin WANG . From synthesis to application: Development and prospects of InP quantum dots. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2105-2123. doi: 10.11862/CJIC.20240126

    6. [6]

      Dan LUOXingcheng LIUDong LITong CHANG . Metal-support interaction effects on CO activation over Con/SiO2 catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2337-2344. doi: 10.11862/CJIC.20250003

    7. [7]

      Xiang Wu Chengfeng Zhu Fang Li Bing Li Yanming Fu Lanjun Cheng Yougui Li . Cultivating the Innovative Practical Abilities of College Students Based on the OBE Concept: Taking the Applied Chemistry Major of Hefei University of Technology as an Example. University Chemistry, 2024, 39(2): 280-285. doi: 10.3866/PKU.DXHX202308040

    8. [8]

      Yue-Zhou ZhuKun WangShi-Sheng ZhengHong-Jia WangJin-Chao DongJian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040

    9. [9]

      Shuyong Zhang Yanguang Wang Yi Yang Hualong Xu Yuqiang Ding Wenqing Zhang Gang Ni Qiue Cao Jianping Li Chunyan Sun Xijiang Han . The Leading Role of University Chemistry in the Reform and Development of the Applied Chemistry Major. University Chemistry, 2025, 40(12): 41-48. doi: 10.12461/PKU.DXHX202508013

    10. [10]

      Lingqi Zhang Hairong Huang Jialin Li Li Ji Yufan Pan Meiling Ye Cuixue Chen Shunü Peng . 桂花碳量子点的绿色制备及科普应用方案. University Chemistry, 2025, 40(8): 298-306. doi: 10.12461/PKU.DXHX202409138

    11. [11]

      Yuxin CHENYanni LINGYuqing YAOKeyi WANGLinna LIXin ZHANGQin WANGHongdao LIWenmin WANG . Construction, structures, and interaction with DNA of two Sm4 complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

    12. [12]

      Xiaomei Ai Muran Lin Jinlan Zeng Jiwei Ren . 可见光催化绿色合成二肽化合物. University Chemistry, 2026, 41(5): 358-367. doi: 10.12461/PKU.DXHX202510007

    13. [13]

      Huiying Xu Minghui Liang Zhi Zhou Hui Gao Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011

    14. [14]

      Yifan Liu Haonan Peng . AI-Assisted New Era in Chemistry: A Review of the Application and Development of Artificial Intelligence in Chemistry. University Chemistry, 2025, 40(7): 189-199. doi: 10.12461/PKU.DXHX202405182

    15. [15]

      Zitong Chen Zipei Su Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054

    16. [16]

      Jiaxin SuJiaqi ZhangShuming ChaiYankun WangSibo WangYuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012

    17. [17]

      Changqing MIAOFengjiao CHENWenyu LIShujie WEIYuqing YAOKeyi WANGNi WANGXiaoyan XINMing FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    18. [18]

      Jiaxun Wu Mingde Li Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098

    19. [19]

      Yuying JIANGJia LUOZhan GAO . Development status and prospects of solid oxide cell high entropy electrode catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1719-1730. doi: 10.11862/CJIC.20250124

    20. [20]

      Jia JITengqi YAOWenqian DENGWenjing SHIXuan LÜLin TIANXiaoyan XINYinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141

Metrics
  • PDF Downloads(2)
  • Abstract views(1565)
  • HTML views(130)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return