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Citation: Jiamin Li, Wenyue Zhong, Kin Shing Chan. “烯”君入瓮又入学——据元素周期表与酸碱理论谈烯烃教学[J]. University Chemistry, ;2025, 40(6): 177-182. doi: 10.12461/PKU.DXHX202408040 shu

“烯”君入瓮又入学——据元素周期表与酸碱理论谈烯烃教学

School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Received Date: 10 August 2024
Revised Date: 26 September 2024

以对话形式展现K教授和学生小C之间的交流，围绕烯烃化学中几种重要反应展开讨论，引入元素周期表和酸碱理论的概念，对烯烃反应进行系统和全面的解释。全文从烯烃的基本性质入手，衍生至烯烃的多种典型反应，包括氢卤酸加成、硼氢化反应等亲电加成反应，再发展至对设计反应和催化剂本质的思考。小C在K教授的引导下，逐步深入理解这些反应的机理和原理，借助元素周期表和酸碱理论，进一步深化对有机化学的认识和思考。
- Alkene chemistry,
- Electrophilic addition,
- Halogenation,
- Acid-base theory,
- Hydroboration reaction,
- Periodic table
1. [1]
  Bruice, P. Y. Organic Chemistry, 4th ed.; Prentice Hall: New Jersey, NJ, USA, 2004; pp. 629–638.
2. [2]
  pK_a Values Compilation. [2024-9-20]. https://organicchemistrydata.org/hansreich/resources/pka/pka_data/evans_pKa_table.pdf
3. [3]
4. [4]
  Thomas, E. M.; Kai, C. H.; Miguel, Y.; Francisco, F.; Mizuki, T. Chem. Rev. 2008, 108, 3795.
5. [5]
  Masaru, U.; John, F. H. J. Am. Chem. Soc. 2003, 125, 14287.
6. [6]
  Shigehisa, H.; Koseki, N.; Shimizu, N.; Fujisawa, M.; Niitsu, M.; Hiroya, K. J. Am. Chem. Soc. 2014, 136, 13534.
7. [7]
  Green, S. A.; Huffman, T. R.; McCourt, R. O.; van der Puyl, V.; Shenvi, R. A. J. Am. Chem. Soc. 2019, 141, 7709.
8. [8]
  Geunes, E. P.; Meinhardt, J. M.; Wu, E. J.; Knowles, R. R. J. Am. Chem. Soc. 2023, 145, 21738.
9. [9]
  Qilei, Z.; Daniel, G. N. J. Am. Chem. Soc. 2020, 142, 17913.
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