Citation: Cen Zhou, Biqiong Hong, Yiting Chen. Application of Electrochemical Techniques in Supramolecular Chemistry[J]. University Chemistry, ;2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086 shu

Application of Electrochemical Techniques in Supramolecular Chemistry

College of Materials and Chemical Engineering, Minjiang University, Fuzhou 350108, China

Corresponding author: Cen Zhou, zhoucen@mju.edu.cn
Received Date: 24 June 2024
Revised Date: 14 September 2024

The most frequently used scaffolds in supramolecular chemistry are typically redox active and susceptible to electron transfer. As a basic tool, electrochemical techniques assist in the generation of active species, which leads to altered interactions between molecules. Meanwhile, more information on energy and kinetics that is not available with other characterization techniques can be provided. In this review, the typically examples on applying electrochemical techniques in supramolecular chemistry are briefly summarized.
- Supramolecular chemistry,
- Electrochemistry,
- Noncovalent interaction,
- Redox control,
- Cyclic voltammetry
1. [1]
  Lehn, J.-M. Science 1993, 260, 1762.
2. [2]
  Mahadevi, A. S.; Sastry, G. N. Chem. Rev. 2016, 116, 2775.
3. [3]
4. [4]
  Boulas, P. L.; Gómez-Kaifer, M.; Echegoyen, L. Angew. Chem. Int. Ed. 1998, 37, 216.
5. [5]
6. [6]
7. [7]
  Cui, L.; Gadde, S.; Li, W.; Kaifer, A. E. Langmuir 2009, 25, 13763.
8. [8]
  Ashton, P. R.; Balzani, V.; Becher, J.; Credi A.; Fyfe, M. C. T.; Mattersteig, G.; Menzer, S.; Nielsen, M. B.; Raymo, F. M.; Stoddart, J. F.; et al. J. Am. Chem. Soc. 1999, 121, 3951.
9. [9]
  Hein, R.; Beer P. D.; Davis, J. J. Chem. Rev. 2020, 120, 1888.
10. [10]
  Mirzoian, A.; Kaifer, A. E. Chem. Eur. J. 1997, 3, 1052.
11. [11]
  Spruell, J. M. Pure Appl. Chem. 2010, 82, 2281.
12. [12]
  Chen, L.; Zhang, Y.-C.; Wang, W.-K.; Tian J.; Zhang, L.; Wang H.; Zhang, D.-W.; Li, Z.-T. Chin. Chem. Lett. 2015, 26, 811.
13. [13]
  Lee, C.; Moon, M. S.; Park, J. W. J. Inclus. Phenom. 1996, 26, 219.
14. [14]
  Badjić, J. D.; Nelson. A.; Cantrill, S. J.; Turnbull, W. B.; Stoddart, J. F. Acc. Chem. Res. 2005, 38, 723.
15. [15]
  Jeon, W. S.; Kim, H.-J.; Lee, C.; Kim, K. Chem. Commun. 2002, 1828.
16. [16]
  Zhou, C.; Tian, J.; Wang, J.-L.; Zhang, D.-W.; Zhao, X.; Liu, Y.; Li, Z.-T. Polym. Chem. 2014, 5, 341.
17. [17]
  Chiang, P.-T.; Chen, N.-C.; Lai, C.-C.; Chiu, S.-H. Chem. Eur. J. 2008, 14, 6546.
18. [18]
  Tian, J.; Ding, Y.-D.; Zhou, T.-Y.; Zhang, K.-D.; Zhao, X.; Wang, H.; Zhang, D.-W.; Liu, Y.; Li, Z.-T. Chem. Eur. J. 2014, 20, 575.
19. [19]
  Tootoonchi, M. H.; Yi, S.; Kaifer, A. E. J. Am. Chem. Soc. 2013, 135, 10804.
20. [20]
  Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruña, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422.
21. [21]
  Steuerman, D. W.; Tseng, H.-R.; Peters, A. J.; Flood, A. H.; Jeppesen, J, O.; Nielsen, K. A.; Stoddart, J. F.; Heath, J. R. Angew. Chem. Int. Ed. 2004, 43, 6486.
22. [22]
  Zhang, K.-D.; Zhao, X.; Wang, G.-T.; Liu, Y.; Zhang, Y.; Lu, H.-J.; Jiang, X.-K.; Li, Z.-T. Angew. Chem. Int. Ed. 2011, 50, 9866.
23. [23]
  Ellis, T. K.; Galerne, M.; Armao IV, J. J.; Osypenko, A.; Martel, D.; Maaloum, M.; Fuks, G.; Moulin, E.; Gavat, O.; Giuseppone, N. Angew. Chem. Int. Ed. 2018, 57, 15749.
24. [24]
  Jiao, Y.; Qiu, Y.; Zhang, L.; Liu, W.-G.; Mao, H.; Chen, H.; Feng, Y.; Cai, K.; Shen, D.; Song, B.; et al. Nature 2022, 603, 265.
25. [25]
  Trabolsi, A.; Khashab, N.; Fahrenbach, A. C.; Friedman, D. C.; Colvin, M. T.; Cotí, K. K.; Benítez, D.; Tkatchouk, E.; Olsen, J.-C.; Belowich, M. E.; et al. Nat. Chem. 2010, 2, 42.
26. [26]
27. [27]
  Wang, Y.; Lin, H.-X.; Chen, L.; Ding, S.-Y.; Lei, Z.-C.; Liu, D.-Y.; Cao, X.-Y.; Liang, H.-J.; Jiang, Y.-B.; Tian, Z.-Q. Chem. Soc. Rev. 2014, 43, 399.
1. [1]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
2. [2]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
3. [3]
  Ling Zhang , Jing Kang . Turn Waste into Valuable: Preparation of High-Strength Water-Based Adhesives from Polymethylmethacrylate Wastes: a Comprehensive Chemical Experiments. University Chemistry, 2024, 39(2): 221-226. doi: 10.3866/PKU.DXHX202306075
4. [4]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
5. [5]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
6. [6]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
7. [7]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
8. [8]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
9. [9]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
10. [10]
  Jiarui Wu , Gengxin Wu , Yan Wang , Yingwei Yang . Crystal Engineering Based on Leaning Towerarenes. University Chemistry, 2024, 39(3): 58-62. doi: 10.3866/PKU.DXHX202304014
11. [11]
  Yifei Cheng , Jiahui Yang , Wei Shao , Wanqun Zhang , Wanqun Hu , Weiwei Li , Kaiping Yang . Learning Goes Beyond the Written Word: Practical Insights from the “Leaf Electroplating” Popular Science Experiment. University Chemistry, 2024, 39(9): 319-327. doi: 10.3866/PKU.DXHX202310033
12. [12]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
13. [13]
  Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
14. [14]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . 电容去离子提锂技术中电极材料的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-. doi: 10.1016/j.actphy.2025.100089
15. [15]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
20. [20]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(374)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142