Citation: Qiuting Zhang, Fan Wu, Jin Liu, Zian Lin. Chromatographic Stationary Phase and Chiral Separation Using Frame Materials[J]. University Chemistry, ;2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174 shu

Chromatographic Stationary Phase and Chiral Separation Using Frame Materials

Fujian Key Laboratory of Food Safety Analysis and Testing, Key Laboratory of Food Safety and Biological Analysis, Ministry of Education, School of Chemistry, Fuzhou University, Fuzhou 350108, China

Received Date: 27 May 2024
Revised Date: 22 July 2024

Chirality plays an important role in fields such as biology, pharmacology and chemical reactions. In practical applications, only one specific configuration of chiral materials typically exhibits the desired effects, making chiral separation essential. The framework materials, with their diverse structures and ease of modification, are highly effective as chromatographic stationary phases for the efficient separation of chiral substances. This paper reviews the latest research on framework material stationary phases for chiral separations and discusses the challenges and application prospects of framework material stationary phases.
1. [1]
  Rikken, G. L.; Raupach, E. Nature 2000, 405, 932.
2. [2]
  Sun, Z. F.; Hou, J. J.; Li, L. S.; Tang, Z. Y. Coord. Chem. Rev. 2020, 425, 213481.
3. [3]
  Crosby, J. Tetrahedron 1991, 22.
4. [4]
5. [5]
  Sui, J.; Wang, N.; Wang, J.; Huang, X.; Wang, T.; Zhou, L.; Hao, H. Chem. Sci. 2023, 14, 11955.
6. [6]
  Zhong, H.; Deng, J. Polym. Rev. 2022, 62, 826.
7. [7]
  Li, X. F.; Zhu, Q. L. EnergyChem 2020, 2.
8. [8]
  Mínguez, E. G.; Coronado, E. Chem. Soc. Rev. 2018, 47, 533.
9. [9]
  Krause, S.; Bon, V.; Senkovska, I.; Stoeck, U.; Wallacher, D.; Többens, D. M.; Zander, S.; Pillai, R. S.; Maurin, G.; Coudert, F.-X.; et al. Nature 2016, 532, 348.
10. [10]
  Zhou, W. X.; Tang, Y. J.; Zhang, X. Y.; Zhang, S. T.; Xue, H. G.; Pang, H. Coord. Chem. Rev. 2023, 477, 214949.
11. [11]
  Ezuhara, T.; Endo, K.; Aoyama, Y. J. Am. Chem. Soc. 1999, 121, 3279.
12. [12]
  Corella-Ochoa, M. N.; Tapia, J. B.; Rubin, H. N.; Lillo, V.; González-Cobos, J.; Núñez-Rico, J. L.; Balestra, S. R. G.; Almora-Barrios, N.; Lledós, M.; Güell-Bara, A.; et al. J. Am. Chem. Soc. 2019, 141, 14306.
13. [13]
  Jiang, H.; Yang, K. W.; Zhao, X. X.; Zhang, W. Q.; Liu, Y.; Jiang, J. W.; Cui, Y. J. Am. Chem. Soc. 2021, 143, 390.
14. [14]
  Yu, Y. Y.; Xu, N. Y.; Zhang, J. H.; Wang, B. J.; Xie, S. M.; Yuan, L. M. ACS Appl. Mater. Interfaces 2020, 12, 16903.
15. [15]
  Ma, X.; Guo, Y.; Zhang, L.; Wang, K. X.; Yu, A. J.; Zhang, S. S.; Ouyang, G. F. Talanta 2022, 239, 123143.
16. [16]
  Kou, W. T.; Yang, C. X.; Yan, X. P. J. Mater. Chem. A 2018, 6, 17861.
17. [17]
  Fei, Z. X.; Zhang, M.; Zhang, J. H.; Yuan, L. M. Anal. Chim. Acta 2014, 830, 49.
18. [18]
  Li, Z. T.; Mao, Z. K.; Zhou, W.; Chen, Z. L. Talanta 2020, 218, 121160.
19. [19]
  Suttipat, D.; Butcha, S.; Assavapanumat, S.; Maihom, T.; Gupta, B.; Perro, A.; Sojic, N.; Kuhn, A.; Wattanakit, C. ACS Appl. Mater. Interfaces 2020, 12, 36548.
20. [20]
  Sun, X. D.; Niu, B.; Zhang, Q.; Chen, Q. J. Pharm. Anal. 2022, 12, 509.
21. [21]
  Xu, H.; Chen, X.; Gao, J.; Lin, J. B.; Addicoat, M.; Irle, S.; Jiang, D. L. Chem. Commun. 2014, 50, 1292.
22. [22]
  Han, X.; Huang, J. J.; Yuan, C.; Liu, Y.; Cui, Y. J. Am. Chem. Soc. 2018, 140, 892.
23. [23]
  Zhang, S. N.; Zheng, Y. L.; An, H. D.; Aguila, B.; Yang, C. X.; Dong, Y. Y.; Xie, W.; Cheng, P.; Zhang, Z. J.; Chen, Y.; et al. Angew. Chem., Int. Ed. 2018, 57, 16754.
24. [24]
  Xu, N. Y.; Guo, P.; Chen, J. K.; Zhang, J. H.; Wang, B. J.; Xie, S. M.; Yuan, L. M. Talanta 2021, 235, 122754.
25. [25]
  Wan, M. J.; Zheng, Y. C.; Dai, X. M.; Yang, H. L.; Zhou, J. Q.; Ou, J.; Yang, Y. X.; Liao, M. F.; Xia, Z. N.; Wang, L. J. Chem. Mater. 2023, 35, 609.
26. [26]
  Chen, Y. L.; Huang, S. M.; Xia, L.; Hu, Y. L.; Li, G. K. Anal. Chem. 2024, 96, 1380.
27. [27]
  Tang, B.; Wang, W.; Hou, H. P.; Liu, Y. Q.; Liu, Z. K.; Geng, L. N.; Sun, L. Q.; Luo, A. Q. Chin. Chem. Lett. 2022, 33, 898.
28. [28]
  Yuan, C.; Jia, W. Y.; Yu, Z. Y.; Li, Y. N.; Zi, M.; Yuan, L. M.; Cui, Y. J. Am. Chem. Soc. 2022, 144, 891.
29. [29]
  Yuan, C.; Wang, Z.; Xiong, W. Q.; Huang, Z. F.; Lai, Y. L.; Fu, S. G.; Dong, J. Q.; Duan, A. H.; Hou, X. D.; Yuan, L. M.; et al. J. Am. Chem. Soc. 2023, 145, 18956.
30. [30]
  Song, Q. Y.; Yang, J.; Zheng, K. N.; Zhang, T.; Yuan, C.; Yuan, L. M.; Hou, X. D. J. Am. Chem. Soc. 2024, 146, 7594.
31. [31]
  Wang, Y. Y.; Zhuo, S. Q.; Hou, J. W.; Li, W.; Ji, Y. B. ACS Appl. Mater. Interfaces 2019, 11, 48363.
32. [32]
  Wang, W.; Zhang, Y. K.; Tang, B.; Hou, H. P.; Tang, S. S.; Luo, A. Q. J. Chromatogr. A 2022, 1675.
1. [1]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
2. [2]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
3. [3]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
4. [4]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
5. [5]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
6. [6]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
7. [7]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
8. [8]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
9. [9]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
10. [10]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
11. [11]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
12. [12]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
13. [13]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
14. [14]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
15. [15]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
16. [16]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
19. [19]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
20. [20]
  Lina Feng , Guoyu Jiang , Xiaoxia Jian , Jianguo Wang . Application of Organic Radical Materials in Biomedicine. University Chemistry, 2025, 40(4): 253-260. doi: 10.12461/PKU.DXHX202405171

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(59)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142