Citation: DUAN Jinchi, QI Yunxia, SHI Chengying, ZHAO Qi, LIU Baijun, SUN Zhaoyan, XU Yiquan, HU Wei, ZHANG Niaona. Electron Beam Radiation Modification of Polyethylene Thermal Conductive Composites[J]. Chinese Journal of Applied Chemistry, ;2020, 37(8): 896-903. doi: 10.11944/j.issn.1000-0518.2020.08.200050 shu

Electron Beam Radiation Modification of Polyethylene Thermal Conductive Composites

DUAN Jinchi ^a ,
QI Yunxia ^b ,
SHI Chengying ^c ,
ZHAO Qi ^a ,
LIU Baijun ^c ,
SUN Zhaoyan ^d ,
XU Yiquan ^b ,
HU Wei ^a,, ,
ZHANG Niaona ^a,,

a.
Changchun University of Technology, Changchun 130012, China
b.
Changchun Kinwa High Technology Co. Ltd, Changchun 130000, China
c.
Jilin University, Changchun 130012, China
d.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: HU Wei, huw884@nenu.edu.cn ZHANG Niaona, zhangniaona@163.com
Received Date: 24 February 2020
Revised Date: 20 March 2020
Accepted Date: 21 April 2020

Fund Project: Supported by National Natural Science Foundation of China(No.21404013, No.5187306); Science and Technology Development Plan of Jilin Province, China(No.20200401036GX), "13th Five Year Plan" Science and Technology Project of Jilin Provincial Department of Education, China(No.JJKH20191297KJ), Changchun New Area "Changbai Huigu" Talent Project(No.9-2020004)"13th Five Year Plan" Science and Technology Project of Jilin Provincial Department of Education, China JJKH20191297KJChangchun New Area "Changbai Huigu" Talent Project 9-2020004Science and Technology Development Plan of Jilin Province, China 20200401036GXNational Natural Science Foundation of China 21404013National Natural Science Foundation of China 5187306

Figures(6)

In this study, the composites (PE-Al-Si) with high thermal conductivity and mechanical properties were obtained by compounding low density polyethylene (LDPE), alumina (Al₂O₃) and SiO₂ nanoparticles through melt blending, and then further modification through electron beam radiation. When the mass fraction of SiO₂ nanoparticles is 1% and the electron beam radiation (EB) dose is 120 kGy, the thermal conductivity of PE-Al-Si increases from 0.624 W/(m·K) to 0.759 W/(m·K), which is 22% increase compared with the composites without SiO₂ (PE-Al). The tensile strength of PE-Al-Si is increased by 17% compared with that of PE-Al. The results prove that SiO₂ improves the mechanical properties, the radiation efficiency and the thermal conductivity of the composites.
- polyethylene,
- electron beam radiation,
- SiO₂ nanoparticles,
- thermal conductivity
1. [1]
  Anithambigai P, Shanmugan S, Mutharasu D. Study on Thermal Performance of High Power LED Employing Aluminum Filled Epoxy Composite as Thermal Interface Material[J]. Microelectron J, 2014,45(12):1726-1733. doi: 10.1016/j.mejo.2014.05.011
2. [2]
  Henry A, Chen G. Anomalous Heat Conduction in Polyethylene Chains:Theory and Molecular Dynamics Simulations[J]. Phys Rev B, 2009,79(14)144305. doi: 10.1103/PhysRevB.79.144305
3. [3]
  Fan J, Xu S. Aluminum Oxide Particles/Silicon Carbide Whiskers' Synergistic Effect on Thermal Conductivity of High-Density Polyethylene Composites[J]. Iran Polym J, 2018,27(5):339-347. doi: 10.1007/s13726-018-0614-9
4. [4]
  Ouyang Y, Hou G, Bai L. Constructing Continuous Networks by Branched Alumina for Enhanced Thermal Conductivity of Polymer Composites[J]. Compos Sci Technol, 2018,165:307-313. doi: 10.1016/j.compscitech.2018.07.019
5. [5]
  Evgin T, Koca H D, Horny N. Effect of Aspect Ratio on Thermal Conductivity of High Density Polyethylene/Multi-Walled Carbon Nanotubes Nanocomposites[J]. Compos Part A:Appl Sci Manuf, 2016,82:208-213. doi: 10.1016/j.compositesa.2015.12.013
6. [6]
  Pedrazzoli D, Pegoretti A, Thomann R. Toughening Linear Low-Density Polyethylene with Halloysite Nanotubes[J]. Polym Composit, 2015,36(5):869-883. doi: 10.1002/pc.23006
7. [7]
  Zhang Y, Yu J, Zhou C. Preparation, Morphology, and Adhesive and Mechanical Properties of Ultrahigh-Molecular-Weight Polyethylene/SiO₂ Nanocomposite Fibers[J]. Polym Compos, 2010,31(4):684-690.
8. [8]
  Sahyoun J, Crepet A, Gouanve F. Diffusion Mechanism of Byproducts Resulting from the Peroxide Crosslinking of Polyethylene[J]. J Appl Polym Sci, 2017,134(9).
9. [9]
  Liu D, Pourrahimi A M, Pallon L K H. Interactions Between a Phenolic Antioxidant, Moisture, Peroxide and Crosslinking By-Products with Metal Oxide Nanoparticles in Branched Polyethylene[J]. Polym Degrad Stab, 2016,125:21-32. doi: 10.1016/j.polymdegradstab.2015.12.014
10. [10]
  Kabanov V, Feldman V, Ershov B. Radiation Chemistry of Polymers[J]. High Energy Chem, 2009,43(1):1-18. doi: 10.1134/S0018143909010019
11. [11]
  Kolanthai E, Bose S, Bhagyashree K S. Graphene Scavenges Free Radicals to Synergistically Enhance Structural Properties in a Gamma-Irradiated Polyethylene Composite Through Enhanced Interfacial Interactions[J]. Phys Chem Chem Phys, 2015,17(35):22900-22910. doi: 10.1039/C5CP02609A
12. [12]
  Chen P Y, Chen C C, Harmon J P. The Effect of Gamma Radiation on Hardness Evolution in High Density Polyethylene at Elevated Temperatures[J]. Mater Chem Phys, 2014,146(3):369-373.
13. [13]
  Chen Y, Yue W, Bian Z. Preparation and Properties of KH550-Al₂O₃/PI-EP Nanocomposite Material[J]. Iran Polym J, 2013,22(5):377-383. doi: 10.1007/s13726-013-0137-3
14. [14]
  Anithambigai P, Chakravarthii M K D, Mutharasu D. Potential Thermally Conductive Alumina Filled Epoxy Composite for Thermal Management of High Power LEDs[J]. J Mater Sci:Mater Electron, 2017,28(1):856-867. doi: 10.1007/s10854-016-5600-4
15. [15]
  Narkis M, Raiter I, Shkolnik S. Structure and Tensile Behavior of Irradiation-and Peroxide-Crosslinked Polyethylenes[J]. J Macromol Sci Phys, 1987,26(1):37-58. doi: 10.1080/00222348708248057
16. [16]
  Stephen H. Electrical Properties of Composites in the Vicinity of the Percolation Threshold[J]. J Appl Polym Sci, 1999,72(12):1573-1582. doi: 10.1002/(SICI)1097-4628(19990620)72:12<1573::AID-APP10>3.0.CO;2-6
17. [17]
  Lai S K. Interface Trap Generation in Silicon Dioxide When Electrons are Captured by Trapped Holes[J]. J Appl Phys, ,54(5):2540-2546. doi: 10.1063/1.332323
18. [18]
  DiMaria D J. Correlation of Trap Creation with Electron Heating in Silicon Dioxide[J]. Appl Phys Lett, 1987,51(9):655-657. doi: 10.1063/1.98324
19. [19]
  Zhang J, Li C, Yu C. Large Improvement of Thermal Transport and Mechanical Performance of Polyvinyl Alcohol Composites Based on Interface Enhanced by SiO₂ Nanoparticle-Modified-Hexagonal Boron Nitride[J]. Compos Sci Technol, 2019,169:167-175. doi: 10.1016/j.compscitech.2018.11.001
20. [20]
  Kochetov R, Andritsch T, Lafont U. Thermal Conductivity of Nano-Filled Epoxy Systems[J]. Conference on Electrical Insulation and Dielectric Phenomena, 2009:658-661.
21. [21]
  Stelescu M D, Manaila E, Craciun G. New Green Polymeric Composites Based on Hemp and Natural Rubber Processed by Electron Beam Irradiation[J]. Sci World J, 2014,2014:1-13.
22. [22]
  Sener A A, Demirhan E. The Investigation of Using Magnesium Hydroxide as a Flame Retardant in the Cable Insulation Material by Cross-Linked Polyethylene[J]. Mater Des, 2008,29(7):1376-1379. doi: 10.1016/j.matdes.2007.05.008
23. [23]
  Mishra A K, Luyt A S. Effect of Sol-Gel Derived Nano-Silica and Organic Peroxide on the Thermal and Mechanical Properties of Low-Density Polyethylene/Wood Flour Composites[J]. Polym Degrad Stab, 2008,93(1):1-8. doi: 10.1016/j.polymdegradstab.2007.11.006
24. [24]
  Bikiaris D N, Vassiliou A, Pavlidou E. Compatibilisation Effect of PP-g-MA Copolymer on iPP/SiO₂ Nanocomposites Prepared by Melt Mixing[J]. Eur Polym J, 2005,41(9):1965-1978. doi: 10.1016/j.eurpolymj.2005.03.008
25. [25]
  Dadbin S, Frounchi M, Saeid M H. Molecular Structure and Physical Properties of E-Beam Crosslinked Low-Density Polyethylene for Wire and Cable Insulation Applications[J]. J Appl Polym Sci, 2002,86(8):1959-1969. doi: 10.1002/app.11111
26. [26]
  Ziaie F, Borhani M, Mirjalili G. Effect of Crystallinity on Electrical Properties of Electron Beam Irradiated LDPE and HDPE[J]. Radiat Phys Chem, 2007,76(11/12):1684-1687.
27. [27]
  Sharif J, Aziz S H S A, Hashim K. Radiation Effects on LDPE/EVA Blends[J]. Radiat Phys Chem, 2000,58(2):191-195.
28. [28]
  Hassan M A. Effect of Incorporation of Butyl Acrylate-Iron Chelate Resin on the Flammability Properties of Mg (OH)₂-LDPE Compositions[J]. Polym-Plast Technol Eng, 2005,43(5):1487-1501. doi: 10.1081/PPT-200030241
29. [29]
  Xiong L, Xiong D, Jin J. Study on Tribological Properties of Irradiated Crosslinking UHMWPE Nano-Composite[J]. J Bionic Eng, 2009,6(1):7-13. doi: 10.1016/S1672-6529(08)60102-X
30. [30]
  Zhang Y, Yu J, Chen L. Surface Modification of Ultrahigh-Molecular-Weight Polyethylene Fibers with Coupling Agent During Extraction Process[J]. J Macromol Sci, 2009,48(2):391-404.
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