Citation: QIAO Zongwen, ZHAO Benbo. Properties of Sulfonated Polysulfone Proton Exchange Membranes Based on One-Pot Method[J]. Chinese Journal of Applied Chemistry, ;2020, 37(6): 658-665. doi: 10.11944/j.issn.1000-0518.2020.06.190355 shu

Properties of Sulfonated Polysulfone Proton Exchange Membranes Based on One-Pot Method

QIAO Zongwen ^1,, ,
ZHAO Benbo ²

a.
Department of Chemical Engineering, Shaanxi Institute of Technology, Xi'an 710300, China
b.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: QIAO Zongwen, qiaozongwen@126.com
Received Date: 27 December 2019
Revised Date: 10 March 2020
Accepted Date: 7 April 2020

Fund Project: the Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Program of Shaanxi Institute of Technology Gfy18-04the Natural Science Special Project of Shaanxi Province 2019JQ-927Supported by the Natural Science Special Project of Shaanxi Province(No.2019JQ-927), and the Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Program of Shaanxi Institute of Technology(No.Gfy18-04)

Figures(6)

Ethyl isocyanate polysulfone (PS-SA) was prepared by introducing the —NCO active group onto the main chain of bisphenol A polysulfones matrix by the Friedel-Crafts alkylation reaction. Naphthalene sulfonic acid modified polysulfone (PS-NS) was obtained by using 2-naphthol-6, 8-disulfonic acid dipotassium as the nucleophilic reagent in one pot. The PS-NS proton exchange membranes(PEMs) were fabricated by solution casting. The relationship between temperature and the basic properties including water uptake, swelling ratio and proton conductivity were explored. PS-NS exhibits excellent dimensional stability at high water sorption because they can form phase separation structure by locating the hydrophilic group far away from the main chain of polysulfones. The water uptake of PS-NS-4 PEMs(the bonding amount of sulfonic groups is 1.42 mmol/g) is as high as 27.2% at 25 ℃ and 40.3% at 85 ℃, but the corresponding swelling ratio is only 25.2% and 57.2%. The properties are very close to that of Nafion115 membrane under the same condition.
- polysulfone,
- ethyl isocyanate,
- naphthalene sulfonic acid type,
- micro-phase separation,
- dimensional stability
1. [1]
  TAO Dan, XIANG Xiongzhi, WANG Lei. Synthsis and Characterization of Poly(Arylene ether)s Proton Exchange Membranes with Sulfonic Groups Attached on Pendent Naphthyl Rings[J]. Acta Polym Sin, 2014,3:326-332.
2. [2]
  Zhang X L, Shi Q, Chen P. Block Poly(arylene ether sulfone) Copolymers Tethering Aromatic Side-Chain Quaternary Ammonium as Anion Exchange Membranes[J]. Polym Chem, 2018,9:699-711.
3. [3]
  Liu B J, Robertson G P, Kim D S. Enhanced Thermo-Oxidative Stability of Sulfophenylated Poly(ether sulfone)s[J]. Polymer, 2010,51:403-413. doi: 10.1016/j.polymer.2009.12.014
4. [4]
  Feng S G, Shang Y M, Xie X F. Synthesis and Characterization of Crosslinked Sulfonated Poly(arylene ether sulfone) Membranes for DMFC Applications[J]. J Membr Sci, 2009,35:13-20.
5. [5]
  GONG Feixiang, QI Yonghong, XUE Qunxiang. Synthesis and Properties of Fluorinated Poly(arylene ether sulfone)s with Sulfonated Pentiptycene Pendants as Proton Exchange Membranes[J]. Chem J Chinese Univ, 2014,35:433-439. doi: 10.7503/cjcu20130605
6. [6]
  Mishra A K, Bose S, Kuila T. Silicate-Based Polymer-Nanocomposite Membranes for Polymer Electrolyte Membrane Fuel Cells[J]. Prog Polym Sci, 2012,37:842-869. doi: 10.1016/j.progpolymsci.2011.11.002
7. [7]
  RONG Qian, GU Shuang, HE Gaohong. Preparation and Performance of Sulfonated Polyether Ether/Ketone/Poly 4-Vinylepyridine Acid-Base Composite Proton Exchange Membrane[J]. Polym Mater Sci Eng, 2009,8:126-129.
8. [8]
  Lafitte B, Jannasch P. Proton-Conducting Aromatic Polymers Carrying Hypersulfonated Side Chains for Fuel Cell Applications[J]. Adv Funct Mater, 2007,17:2823-2834. doi: 10.1002/adfm.200700107
9. [9]
  MA Li, CHENG Hailong, XU Jingmei. Prepartion and Performance of Sulfonated Poly(aryl ether ketone sulfone)/Poly(aryl ether sulfone oxadiazole) Composite Proton-Exchange Membranes[J]. Chem J Chinese Univ, 2014,35:639-644.
10. [10]
  Zhang Y, Wan Y, Zhao C J. Novel Side-Chain-Type Sulfonated Poly(arylene ether ketone) with Pendant Sulfoalkyl Groups for Direct Methanol Fuel Cells[J]. Polymer, 2009,50:4471-4478. doi: 10.1016/j.polymer.2009.07.036
11. [11]
  Bose S, Kuila T, Nguyen T X. Polymer Membranes for High Temperature Proton Exchange Membrane Fuel Cell:Recent Advances and Challenges[J]. Prog Polym Sci, 2011,36:813-843. doi: 10.1016/j.progpolymsci.2011.01.003
12. [12]
  Kobayashi T, Rilukawa M, Sanui K. Proton Conducting Polymers Derived from Poly(ether-etherketone) and Poly(4-phenoxybenzoyl-1, 4-phenylene)[J]. Solid State Ionic, 1998,106:219-225. doi: 10.1016/S0167-2738(97)00512-2
13. [13]
  Liu D, Tao D, Ni J P. Synthesis and Properties of Highly Branched Sulfonated Poly(arylene ether)s with Flexible Alkylsulfonated Side Chains as Proton Exchange Membranes[J]. J Mater Chem C, 2016,4:1326-1335.
14. [14]
  QIAO Zongwen. Properties of Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells[J]. Mod Chem Ind, 2020,40(4):153-157.
15. [15]
  QIAO Zongwen, CHEN Tao. Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells[J]. Chinese J Appl Chem, 2019,36(8):917-923.
16. [16]
  Gao Y, Robertson G P, Guiver M D. Proton Exchange Membranes Based on Sulfonated Poly(Phthalazinone Ether Ketone)s/Aminated Polymer Blends B[J]. Solid State Ionics, 2005,176:409-415. doi: 10.1016/j.ssi.2004.08.009
17. [17]
  Zhang B P, Ni J P, Tang X Z. Synthesis and Properties of Reprocessable Sulfonated Polyimides Cross-Linked via Acid Stimulation for Use as Proton Exchange Membranes[J]. J Power Sources, 2017,337(1):110-117.
18. [18]
  Zhu Y Q, Manthiram A. Synthesis and Characterization of Polysulfone-Containing Sulfonated Side Chains for Direct Methanol Fuel Cells[J]. J Power Sources, 2011,196:7481-7487. doi: 10.1016/j.jpowsour.2011.05.019
19. [19]
  Gong X, Yan X M, Li T T. Design of Pendent Imidazolium Side Chain with Flexible Ether-Containing Spacer for Alkaline Anion Exchange Membrane[J]. J Membr Sci, 2017,523(1):216-224.
20. [20]
  Ahnab M K, Lee S B, Min C M. Enhanced Proton Conductivity at Low Humidity of Proton Exchange Membranes with Triazole Moieties in the Side Chains[J]. J Membr Sci, 2017,532:480-486.
21. [21]
  Wang G G, Weng Y M, Chu D. Developing a Polysulfone-Based Alkaline Anion Exchange Membrane for Improved Ionic Conductivity[J]. J Membr Sci, 2009,332:63-68. doi: 10.1016/j.memsci.2009.01.038
22. [22]
  Kima K, Junga B K, Koa T. Comb-Shaped Polysulfones Containing Sulfonated Polytriazole Side Chains for Proton Exchange Membranes[J]. J Membr Sci, 2018,554(15):232-243.
23. [23]
  Yin Y, Du Q, Qin Y Z. Sulfonated Polyimides with Flexible Aliphatic Side Chains for Polymer Electrolyte Fuel Cells[J]. J Membr Sci, 2011,367(1):211-219.
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