Citation: ZENG Lihui, LI Yuefeng, YAN Haoxiang, ZENG Yongkang, ZHANG Zhixiang, LIU Zhongwen, LIU Zhaotie. Catalytic Hydrogenation Performance of p-tert-Butyl-α-Methyl Cinnamaldehydeover Precious Metal Catalysts[J]. Chinese Journal of Applied Chemistry, ;2020, 37(3): 322-331. doi: 10.11944/j.issn.1000-0518.2020.03.190192 shu

Catalytic Hydrogenation Performance of p-tert-Butyl-α-Methyl Cinnamaldehydeover Precious Metal Catalysts

a.
Key Laboratory of Applied Surface and Colloid Chemistry(Ministry of Education), School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
b.
Kaili Catalyst & New Materials Co., Ltd. Xi'an 710201, China
c.
College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

Corresponding author: LIU Zhaotie, ztliu@snnu.edu.cn
Received Date: 9 July 2019
Revised Date: 10 January 2020
Accepted Date: 11 February 2020

Fund Project: the Key Industry Innovation Chain of Shaanxi Science and Technology Department(group) 2019ZDLGY06-04Supported by the Key Industry Innovation Chain of Shaanxi Science and Technology Department(group)(No.2019ZDLGY06-04)

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In this paper, Fourier transform infrared spectroscopy (FT-IR), N₂ adsorption-desorption, X-ray diffraction (XRD) andtransmission electron microscopy (TEM) were used to characterize the activated carbon treated via microwave with KOH. The results show that the oxygen-containing groups on the surface of activated carbon increase greatly, and the number of micropores decrease significantly. The selective catalytic hydrogenation performances of p-tert-butyl-α-methyl cinnamaldehyde over Pt, Pd, Ru and Rh supported on activated carbon were investigated. The Pt/C catalyst shows excellent selective hydrogenation for C═O, while the Pd/C catalyst has good selectivity for hydrogenation of C═C. The product distribution of selective hydrogenation of p-tert-butyl-α-methylcinnamaldehyde catalyzed by Pd-Pt bimetallic catalyst was also studied. The results show that the selective hydrogenation of C═O is gradually increased with an increase of Pt content, while the selectivity of hydrogenation of C═C decreases gradually over the Pd-Pt bimetallic catalyst. An optimal catalytic performance is obtained over Pd-Pt bimetallic catalyst when m(Pd):m(Pt)=4:1.
- microwave-assisted,
- activated carbon,
- noble metal supported catalyst,
- selective hydrogenation,
- p-tert-butyl-α-methylcinnamaldehyde
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