Citation: QIAO Zongwen, CHEN Tao. Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells[J]. Chinese Journal of Applied Chemistry, ;2019, 36(8): 917-923. doi: 10.11944/j.issn.1000-0518.2019.08.190013 shu

Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes for Fuel Cells

QIAO Zongwen ^a,, ,
CHEN Tao ^b

a.
Department of Chemical Engineering, Shaanxi Institute of Technology, Xi'an 710300, China
b.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: QIAO Zongwen, qiaozongwen@126.com
Received Date: 14 January 2019
Revised Date: 22 February 2019
Accepted Date: 17 April 2019

Fund Project: Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Project of Shaanxi Institute of Technology Gfy18-04Natural Science Special Project of Shaanxi Education Department 18JK0069Supported by Natural Science Special Project of Shaanxi Education Department(No.18JK0069), Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Project of Shaanxi Institute of Technology(No.Gfy18-04)

Figures(6)

Chloromethylated polysulfones(CPS) was used as the precursors, and side chain type sulfonted polysulfone(PS-BDS) was obtained using disodium 1, 2-dihydroxybenzene-3, 5-disufonate as nucleophilic reagents. The corresponding proton exchange membranes(PEMs) were produced using solution casting method. The relationship between the temperature and properties of PEMs was studied. Since they have characteristic micro-phase separation structures by locating hydrophilic sulfonic acid group far away from hydrophobic main chain of PS, PEMs have excellent dimensional stability at high water sorption ratio. With the increase of temperature, the proton conductivity, the swelling ratio and the water sorption ratio increase. PS-BDS PEMs have comprehensive size stability and methanol permeability. The swelling ratio of PS-BDS-4 PEM is only 22.1% at 25℃ and 55.0% at 85℃. The methanol permeability is 9.94×10^-7 cm²/s at 25℃, lower than those of commercial Nafion115(16.8×10^-7 cm²/s) and Nafion117(23.8×10^-7 cm²/s) PEMs.
- polysulfone,
- exchange membranesphase separation,
- dimensional stability,
1. [1]
  Kima K, Junga B K, Koa T. Polysulfones Containing Sulfonated Polytriazole Side Chains for Proton Exchange Membranes[J]. J Membr Sci, 2018,554(15):232-243.
2. [2]
  Liu D, Xu M Z, Fang M L. Branched Comb-shaped Poly(arylene ether sulfone)s Containing Flexible Alkyl Imidazolium Side Chains as Anion Exchange Membranes[J]. J Mater Chem, 2018,6:10879-10890. doi: 10.1039/C8TA02115E
3. [3]
  Yan X M, Zhang C M, Dong Z W. Amphiprotic Side-Chain Functionalization Constructing Highly Proton/Vanadium-Selective Transport Channels for High-Performance Membranes in Vanadium Redox Flow Batteries[J]. Appl Mater Interfaces, 2018,10(38):32247-32255. doi: 10.1021/acsami.8b11993
4. [4]
  Li X, Zhao Y, Li W W. Molecular Dynamics Simulation of Radiation Grafted FEP Films as Proton Exchange Membranes:Effects of the Side Chain Length[J]. Int J Hydrogen Energy, 2017,42(50):29977-29987. doi: 10.1016/j.ijhydene.2017.09.043
5. [5]
  Han M M, Zhang G, Li M Y. Sulfonated Poly(etheretherketone) Polybenzimidazole Oligomer/Epoxy Resin Composite Membranes in Situ Polymerization for Direct Methanol Fuel Cell Usages[J]. J Power Sources, 2011,196:9916-9923. doi: 10.1016/j.jpowsour.2011.08.049
6. [6]
  QIAO Zongwen, YAN Xiaoqian. Properties of Naphthalenesulfonic Acid Type Polysulfone Proton Exchange Membrane[J]. Chem Res Appl, 2018,30(12):1993-1998. doi: 10.3969/j.issn.1004-1656.2018.12.011
7. [7]
  Kumar P, Dutta K, Das S. Membrane Prepared by Incorporation of Crosslinked Sulfonated Polystyrene in the Blend of PVdF-co-HFP/Nafion[J]. Appl Energy, 2014,123:66-74. doi: 10.1016/j.apenergy.2014.02.060
8. [8]
  RONG Qian, GU Shuang, HE Gaohong. Preparation and Performance of Sulfonated Polyether Ether/Ketone/Poly4-Vinylepyridine Acid-Base Composite Proton Exchange Membrane[J]. Polym Mater Sci Eng, 2009,8:126-129.
9. [9]
  GONG Feixiang, QI Yonghong, XUE Qunxiang. Synthesis and Properties of Fluorinated Poly(arylene ether sulfone)s with Sulfonated Pentiptycene Pendants as Proton Exchange Membranes[J]. Chem J Chinese Univ, 2014,35:433-439. doi: 10.7503/cjcu20130605
10. [10]
  Jin C H, Zhu X L, Zhang S. Highly Conductive Flexible Alkylsulfonated Side Chains Poly(phthalazinone ether ketone)s for Proton Exchange Membranes[J]. Polymer, 2018,148(18):269-277.
11. [11]
  Zhang X L, Shi Q, Chen P. Block Poly(arylene ether sulfone) Copolymers Tethering Aromatic Side-Chain Quaternary Ammonium as Anion Exchange Membranes[J]. Polym Chem, 2018,9:699-711. doi: 10.1039/C7PY01558E
12. [12]
  QIAO Zongwen, CHEN Tao. Effect of Side Chain Structure on Properties of Side Chain Type Sulfonated Polysulfone Proton Exchange Membranes[J]. Chem Bull, 2019,82(5):457-462.
13. [13]
  Liu D, Tao D, Ni J P. Synthesis and Properties of Highly Branched Sulfonated Poly(arylene ether)s with Flexible Alkylsulfonated Side Chains as Proton Exchange Membranes[J]. J Mater Chem C, 2016,4:1326-1335.
14. [14]
  Pang J H, Shen K Z, Feng S N. Polymer Electrolyte Membranes Based on Poly(arylene ether)s with Flexible Disulfophenyl Pendant[J]. J Power Sources, 2014,263:59-65. doi: 10.1016/j.jpowsour.2014.03.100
15. [15]
  TAO Dan, XIANG Xiongzhi, WANG Lei. Synthsis and Characterization of Poly(arylene ether)s Proton Exchange Membranes with Sulfonic Groups Attached on Pendent Naphthyl Rings[J]. Acta Polym Sin, 2014,3:326-332.
16. [16]
  Ekström H, Lafitte B, Ihonen J. Evaluation of a Sulfophenylated Polysulfone Membrane in a Fuel Cell at 60 to 110℃[J]. Solid State Ionics, 2007,178:959-966. doi: 10.1016/j.ssi.2007.04.002
17. [17]
  Zhang Y, Wan Y, Zhao C J. Novel Side-Chain-Type Sulfonated Poly(arylene ether ketone) with Pendant Sulfoalkyl Groups for Direct Methanol Fuel Cells[J]. Polymer, 2009,50:4471-4478. doi: 10.1016/j.polymer.2009.07.036
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