Citation: TANG Cheng, ZOU Zhijuan, SONG Kunpeng. Preparation of Ni-P Co-doped Hyper-Crosslinked Polymer and Used for Reduction of 4-Nitrophenol[J]. Chinese Journal of Applied Chemistry, ;2019, 36(7): 782-789. doi: 10.11944/j.issn.1000-0518.2019.07.180346 shu

Preparation of Ni-P Co-doped Hyper-Crosslinked Polymer and Used for Reduction of 4-Nitrophenol

Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China

Corresponding author: SONG Kunpeng, song19880405@126.com
Received Date: 31 October 2018
Revised Date: 4 April 2019
Accepted Date: 16 April 2019

Fund Project: Supported by the Science and Technology Planning Project of Guangdong Province(No.2017B030314092), the Fundamental Research Funds of CWNU(No.17C038), the Meritocracy Research Funds of CWNU(No.17Y031)the Meritocracy Research Funds of CWNU 17Y031the Science and Technology Planning Project of Guangdong Province 2017B030314092the Fundamental Research Funds of CWNU 17C038

Figures(8)

Ni-P co-doped hyper-cross-linked polymer(HCP-(BTP-Ni)) was constructed in situ via cross-linking with bis(triphenylphosphine)nickel chloride(BTP-Ni). The specific surface area of HCP-(BTP-Ni) was controlled in the synthesis. The characterization results of nitrogen absorption and desorption(BET), scanning electron microscope(SEM), X-ray photoelectron spectroscopy(XPS), and others showed that the specific surface areas of HCP-(BTP-Ni) could reach 733.8 m²/g, and the conversion rate of 4-nitrophenol at room temperature could reach 99% within 8 min. The turnover frequency(TOF) could reach more than 820 h^-1. At the same time, Ni-P co-doped skeleton structure greatly promoted the stability of the catalyst. The catalyst HCP-(BTP-Ni) could be reused for 8 times with a high yield.>
- Ni-P co-doped,
- hyper-crosslinked polymer,
- reduction of 4-nitrophenol,
- in situ synthesis
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