Citation: YU Huifa, CHEN Chonglai, WANG Yuejuan, LUO Mengfei. Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts[J]. Chinese Journal of Applied Chemistry, ;2019, 36(6): 698-703. doi: 10.11944/j.issn.1000-0518.2019.06.180328 shu

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts

a.
Key Laboratory of Advanced Catalytic Materials, Ministry of Education, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
b.
Jinhua Vocational and Technical College, Jinhua, Zhejiang 321004, China

Corresponding author: LUO Mengfei, mengfeiluo@zjnu.cn
Received Date: 12 October 2018
Revised Date: 12 December 2018
Accepted Date: 23 January 2019

Figures(5)

A series of NiO/Mn₃O₄ monolithic catalysts with different NiO contents was prepared by ball-milling of Ni(NO₃)₂·6H₂O, Mn₃O₄ and pseudo boehmite precusors via subsequent impregnation with cordierite, followed by calcination. These catalysts were tested for ozone decomposition. It was found that the 30NiO/Mn₃O₄(mass fraction of NiO in total mass is 30%) catalyst has the highest activity at a space velocity of 20000 h^-1, and leads to 98% conversion of ozone, while the catalyst remains stable. When the space velocity is increased to 40000 h^-1, the 50NiO/Mn₃O₄(mass fraction of NiO in total mass is 50%) catalyst gives the highest activity, with a ozone conversion at about 90%. But the catalyst suffers deactivation. Characterizations by X-ray diffraction(XRD), TPR, XPS and BET reveal that the presence of Mn₃O₄ in the NiO increases the specific surface area of the catalyst, and electronic interaction between Mn₃O₄ and NiO. Meanwhile, the co-presence of Mn₃O₄ and NiO in the catalyst results in facile reduction of these oxides. This synergy is believed to be responsible for the enhanced catalytic performance.
- Mn₃O₄,
- NiO,
- catalyst,
- Ozone decomposition,
- active site
1. [1]
  FU Jiayuan, FENG Yijun, ZHONG Bing. Description of Catalytic Decomposition Ozone Methods and Properties of Catalysts[J]. Sichuan Environ, 2001,20(1):35-39. doi: 10.3969/j.issn.1001-3644.2001.01.010
2. [2]
  ZHOU Min, HE Bingyu, CAI Xiaowei. Preparation and Properties of Au/TiO₂ Ozone Decomposition Catalysts[J]. Chem Manage, 2015(3):70-71. doi: 10.3969/j.issn.1008-4800.2015.03.063
3. [3]
  WANG Xiumin. Be Wary of Chronic Occupational Hazards Caused by Ozone[J]. Occup Hea, 1988,4:39-40.
4. [4]
  JIANG Qingyuan. Ozone Harm and Protection[J]. Environ Technol, 1986,3:32-34.
5. [5]
  REN Guizheng. Protection of High Altitude Ozone Layer and Harm of Low Altitude Ozone[J]. Chinese J Environ Manage, 2002,3:43-44.
6. [6]
  LIU Chang'an, SUN Dezhi, LI Wei. Study on Treatment of Ozone Tail Gas by Catalytic Decomposition[J]. Environ Protect Sci, 2003,29(5):1-3. doi: 10.3969/j.issn.1004-6216.2003.05.001
7. [7]
  ZHANG Jingjie, ZHANG Pengyi, ZHANG Bo. Activated Carbon Supported by Gold Catalyzed Decomposition of Low Concentration Ozone in Air[J]. J Catal, 2008,29(4):335-340. doi: 10.3321/j.issn:0253-9837.2008.04.006
8. [8]
  SUN Qingping, WU Jianping. Preliminary Exploration of Ozone Removal by Metal Oxide Catalyst[J]. Environ Pollut Prevent, 2002,24(1):32-33. doi: 10.3969/j.issn.1001-3865.2002.01.012
9. [9]
  GU Yulin, LIU Shuwen, XU Xianlun. Preparation and Properties of Ozone Decomposition Catalysts[J]. Ind Catal, 2002,10(6):39-42. doi: 10.3969/j.issn.1008-1143.2002.06.010
10. [10]
  LIU Chang'an, YANG Dehua, SUN Dezhi. Preparation and Characterization of Catalysts for Ozone Tail Gas Treatment[J]. J Nat Sci Harbin Normal Univ, 2001,17(6):64-67.
11. [11]
  Dhandapani B, Oyama S T. Gas Phase Ozone Decomposition Catalysts[J]. Appl Catal B:Environ, 1997,11(2):129-166. doi: 10.1016/S0926-3373(96)00044-6
12. [12]
  LI Wei, SUN Dezhi, LIU Chang'an. Study on the Decomposition of Ozone by Activated Carbon Supported Composite Catalyst[J]. J Harbin Inst Technol, 2004,36(5):624-626. doi: 10.3321/j.issn:0367-6234.2004.05.017
13. [13]
  CHEN Yepu, JIANG Aili, TANG Guixia. Study on Catalytic Decompositon of Ozone[J]. Ind Catal, 2006,14(5):52-55. doi: 10.3969/j.issn.1008-1143.2006.05.012
14. [14]
  LIU Chang'an, SUN Dezhi, LI Wei. Study on Treatment of Ozone Tail Gas by Catalytic Decomposition[J]. Environ Protect Sci, 2003,29(119):1-3.
15. [15]
  Tang W, Deng Y, Li W. Importance of Porous Structure and Synergistic Effect on the Catalytic Oxidation Activities over Hierarchical Mn-Ni Composite Oxides[J]. Catal Sci Technol, 2015,6(6):1710-1718.
16. [16]
  LI Qiurong, WU Jinbao, HAO Jiming. Promotion of NiO/Al₂O₃ Adsorption of NO_X by Low Temperature Plasma Treatment[J]. Chinese J Catal, 2011,32(4):572-581.
17. [17]
  Tang W, Li J, Wu X. Limited Nanospace for Growth of Ni-Mn Composite Oxide Nanocrystals with Enhanced Catalytic for Deep Oxidation of Benzene[J]. Catal Today, 2015,258(12):148-155.
18. [18]
  Tang W, Deng Y, Li W. Importance of Porous Structure and Synergistic Effect on the Catalytic Oxidation Activities over Hierarchical Mn-Ni Composite Oxides[J]. Catal Sci Technol, 2015,6(6):1710-1718.
19. [19]
  ZHANG Zhaoyan, WANG Ying, LI Xian. Synergistic Effect of Gold Palladium Bimetal Catalyst in Sodium Benzoate Oxidation by Benzyl Alcohol[J]. Chinese J Catal, 2014,35(11):1846-1857.
20. [20]
  Wang C, Ma J, Liu F. The Effects of Mn²⁺ Precursors on the Structure and Ozone Decomposition Activity of Cryptomelane-Type Manganese Oxide(OMS-2) Catalyst[J]. J Phys Chem C, 2015,119(40):23119-23126. doi: 10.1021/acs.jpcc.5b08095
21. [21]
  Batakliev T T, Georgiev V F, Karakashkova P A. Gas Phase Ozone Decomposition over Co-Precipitated Ni-Based Catalysts[J]. Bull Chem Commun, 2017,49(special issue L):24-29.
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts