Citation: YU Huifa, CHEN Chonglai, WANG Yuejuan, LUO Mengfei. Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts[J]. Chinese Journal of Applied Chemistry, ;2019, 36(6): 698-703. doi: 10.11944/j.issn.1000-0518.2019.06.180328 shu

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts

a.
Key Laboratory of Advanced Catalytic Materials, Ministry of Education, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
b.
Jinhua Vocational and Technical College, Jinhua, Zhejiang 321004, China

Corresponding author: LUO Mengfei, mengfeiluo@zjnu.cn
Received Date: 12 October 2018
Revised Date: 12 December 2018
Accepted Date: 23 January 2019

Figures(5)

A series of NiO/Mn₃O₄ monolithic catalysts with different NiO contents was prepared by ball-milling of Ni(NO₃)₂·6H₂O, Mn₃O₄ and pseudo boehmite precusors via subsequent impregnation with cordierite, followed by calcination. These catalysts were tested for ozone decomposition. It was found that the 30NiO/Mn₃O₄(mass fraction of NiO in total mass is 30%) catalyst has the highest activity at a space velocity of 20000 h^-1, and leads to 98% conversion of ozone, while the catalyst remains stable. When the space velocity is increased to 40000 h^-1, the 50NiO/Mn₃O₄(mass fraction of NiO in total mass is 50%) catalyst gives the highest activity, with a ozone conversion at about 90%. But the catalyst suffers deactivation. Characterizations by X-ray diffraction(XRD), TPR, XPS and BET reveal that the presence of Mn₃O₄ in the NiO increases the specific surface area of the catalyst, and electronic interaction between Mn₃O₄ and NiO. Meanwhile, the co-presence of Mn₃O₄ and NiO in the catalyst results in facile reduction of these oxides. This synergy is believed to be responsible for the enhanced catalytic performance.
- Mn₃O₄,
- NiO,
- catalyst,
- Ozone decomposition,
- active site
1. [1]
  FU Jiayuan, FENG Yijun, ZHONG Bing. Description of Catalytic Decomposition Ozone Methods and Properties of Catalysts[J]. Sichuan Environ, 2001,20(1):35-39. doi: 10.3969/j.issn.1001-3644.2001.01.010
2. [2]
  ZHOU Min, HE Bingyu, CAI Xiaowei. Preparation and Properties of Au/TiO₂ Ozone Decomposition Catalysts[J]. Chem Manage, 2015(3):70-71. doi: 10.3969/j.issn.1008-4800.2015.03.063
3. [3]
  WANG Xiumin. Be Wary of Chronic Occupational Hazards Caused by Ozone[J]. Occup Hea, 1988,4:39-40.
4. [4]
  JIANG Qingyuan. Ozone Harm and Protection[J]. Environ Technol, 1986,3:32-34.
5. [5]
  REN Guizheng. Protection of High Altitude Ozone Layer and Harm of Low Altitude Ozone[J]. Chinese J Environ Manage, 2002,3:43-44.
6. [6]
  LIU Chang'an, SUN Dezhi, LI Wei. Study on Treatment of Ozone Tail Gas by Catalytic Decomposition[J]. Environ Protect Sci, 2003,29(5):1-3. doi: 10.3969/j.issn.1004-6216.2003.05.001
7. [7]
  ZHANG Jingjie, ZHANG Pengyi, ZHANG Bo. Activated Carbon Supported by Gold Catalyzed Decomposition of Low Concentration Ozone in Air[J]. J Catal, 2008,29(4):335-340. doi: 10.3321/j.issn:0253-9837.2008.04.006
8. [8]
  SUN Qingping, WU Jianping. Preliminary Exploration of Ozone Removal by Metal Oxide Catalyst[J]. Environ Pollut Prevent, 2002,24(1):32-33. doi: 10.3969/j.issn.1001-3865.2002.01.012
9. [9]
  GU Yulin, LIU Shuwen, XU Xianlun. Preparation and Properties of Ozone Decomposition Catalysts[J]. Ind Catal, 2002,10(6):39-42. doi: 10.3969/j.issn.1008-1143.2002.06.010
10. [10]
  LIU Chang'an, YANG Dehua, SUN Dezhi. Preparation and Characterization of Catalysts for Ozone Tail Gas Treatment[J]. J Nat Sci Harbin Normal Univ, 2001,17(6):64-67.
11. [11]
  Dhandapani B, Oyama S T. Gas Phase Ozone Decomposition Catalysts[J]. Appl Catal B:Environ, 1997,11(2):129-166. doi: 10.1016/S0926-3373(96)00044-6
12. [12]
  LI Wei, SUN Dezhi, LIU Chang'an. Study on the Decomposition of Ozone by Activated Carbon Supported Composite Catalyst[J]. J Harbin Inst Technol, 2004,36(5):624-626. doi: 10.3321/j.issn:0367-6234.2004.05.017
13. [13]
  CHEN Yepu, JIANG Aili, TANG Guixia. Study on Catalytic Decompositon of Ozone[J]. Ind Catal, 2006,14(5):52-55. doi: 10.3969/j.issn.1008-1143.2006.05.012
14. [14]
  LIU Chang'an, SUN Dezhi, LI Wei. Study on Treatment of Ozone Tail Gas by Catalytic Decomposition[J]. Environ Protect Sci, 2003,29(119):1-3.
15. [15]
  Tang W, Deng Y, Li W. Importance of Porous Structure and Synergistic Effect on the Catalytic Oxidation Activities over Hierarchical Mn-Ni Composite Oxides[J]. Catal Sci Technol, 2015,6(6):1710-1718.
16. [16]
  LI Qiurong, WU Jinbao, HAO Jiming. Promotion of NiO/Al₂O₃ Adsorption of NO_X by Low Temperature Plasma Treatment[J]. Chinese J Catal, 2011,32(4):572-581.
17. [17]
  Tang W, Li J, Wu X. Limited Nanospace for Growth of Ni-Mn Composite Oxide Nanocrystals with Enhanced Catalytic for Deep Oxidation of Benzene[J]. Catal Today, 2015,258(12):148-155.
18. [18]
  Tang W, Deng Y, Li W. Importance of Porous Structure and Synergistic Effect on the Catalytic Oxidation Activities over Hierarchical Mn-Ni Composite Oxides[J]. Catal Sci Technol, 2015,6(6):1710-1718.
19. [19]
  ZHANG Zhaoyan, WANG Ying, LI Xian. Synergistic Effect of Gold Palladium Bimetal Catalyst in Sodium Benzoate Oxidation by Benzyl Alcohol[J]. Chinese J Catal, 2014,35(11):1846-1857.
20. [20]
  Wang C, Ma J, Liu F. The Effects of Mn²⁺ Precursors on the Structure and Ozone Decomposition Activity of Cryptomelane-Type Manganese Oxide(OMS-2) Catalyst[J]. J Phys Chem C, 2015,119(40):23119-23126. doi: 10.1021/acs.jpcc.5b08095
21. [21]
  Batakliev T T, Georgiev V F, Karakashkova P A. Gas Phase Ozone Decomposition over Co-Precipitated Ni-Based Catalysts[J]. Bull Chem Commun, 2017,49(special issue L):24-29.
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
3. [3]
  Mei-Xia Yang , Zhen-Hong He , Long-Rui Wang , You-Xing Yang . Route for Turning Waste CH₄ and CO₂ into Valuable Products: Reforming for Syngas. University Chemistry, 2026, 41(2): 197-207. doi: 10.12461/PKU.DXHX202503012
4. [4]
  Wenruo NI , Hongpeng LI , Yun ZHANG , Yiran TIAN , Jiehui RUI , Yingcheng TONG , Xiaolin PI , Zhenyan TANG . Research progress of ruthenium alloy catalysts in hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 23-44. doi: 10.11862/CJIC.20250188
5. [5]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
6. [6]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
7. [7]
  Chenyang WANG , Yiyan BAI , Wei ZHANG , Zhaorong LIU , Yuchun WANG . Performance of photo-assisted copper oxide catalyzed hydrolysis of ammonia borane to produce hydrogen. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 97-110. doi: 10.11862/CJIC.20250116
8. [8]
  Shuting KONG , Fengshi ZHANG , Zhiyi LU , Yanling LIU , Minglang YE , Zhengfang HU , Longsheng WANG , Bing HU , Haiying WANG . Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303
9. [9]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
10. [10]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
11. [11]
  Jiahong WANG , Zekun XU , Tianjiao LU , Jinming HUANG . Performance of N, Mn doped semi-coke activated carbon catalyzed ozone oxidation for the degradation of tetracycline hydrochloride in water. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2549-2560. doi: 10.11862/CJIC.20250120
12. [12]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
13. [13]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
14. [14]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
15. [15]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
16. [16]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
17. [17]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
18. [18]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
19. [19]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
20. [20]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1208)
HTML views(239)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ozone Decomposition over NiO/Mn3O4 Monolithic Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Ozone Decomposition over NiO/Mn₃O₄ Monolithic Catalysts