Citation: LUO Yunfeng, LIU Baoshuang, LI Chunxiang. All Solid-State Calcium Ion Selective Electrode Based on Carbon Nanotube/Ag/MoS₂ Transducer[J]. Chinese Journal of Applied Chemistry, ;2019, 36(6): 704-710. doi: 10.11944/j.issn.1000-0518.2019.06.180313 shu

All Solid-State Calcium Ion Selective Electrode Based on Carbon Nanotube/Ag/MoS₂ Transducer

a.
Drilling Technology Research Institute, Shengli Petroleum Engineering Co., Ltd., SINOPEC, Dongying, Shandong 257000, China
b.
School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: LI Chunxiang, lichx@hit.edu.cn
Received Date: 20 September 2018
Revised Date: 30 October 2018
Accepted Date: 5 December 2018

Fund Project: the National Natural Science Foundation of Major Special Projects 2016ZX05022-006the Innovation Talent project(Distinguished Young Scholars) of Harbin Science and Technology Bureau 2017RAYXJ015Supported by the National Natural Science Foundation of Major Special Projects(No.2016ZX05022-006), the Innovation Talent project(Distinguished Young Scholars) of Harbin Science and Technology Bureau(No.2017RAYXJ015)

Figures(7)

An all-solid-state Ca²⁺ ion selective electrode(Ca²⁺-ISE) was prepared with carbon nanotube(CNT)/Ag/MoS₂ as the ion-to-electron transducer and tripodal compound as the calcium ionophore. The stability, slope, response range, selectivity coefficient, etc. of the electrode were investigated. It is revealed that the electrode exhibits a 28.1 mV/decade Nernst slope in the range of 1×10^-6~1×10^-1 mol/L Ca²⁺ concentration. The transducer is helpful in enlarging the linear response range of the Ca²⁺ concentration, shortening the potential balance time and reducing the difference of the Nernst slope. All of these results are important for long-term online detection of calcium ions for the solid electrode.
- all-solid-state electrode,
- calcium ion selectiveelectrode,
- ion-to-electron transducer
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

All Solid-State Calcium Ion Selective Electrode Based on Carbon Nanotube/Ag/MoS2 Transducer

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通讯作者: 陈斌, bchen63@163.com

All Solid-State Calcium Ion Selective Electrode Based on Carbon Nanotube/Ag/MoS₂ Transducer