Citation: LI Xiancai, TIAN Minglei, CHENG Yuwen, WANG Xiu. Preparation and Characterization of Yb Ion-Imprinted Polymers Based on MCM-41 Molecular Sieve Surface[J]. Chinese Journal of Applied Chemistry, ;2019, 36(2): 203-211. doi: 10.11944/j.issn.1000-0518.2019.02.180110 shu

Preparation and Characterization of Yb Ion-Imprinted Polymers Based on MCM-41 Molecular Sieve Surface

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: LI Xiancai, xcli@ncu.edu.cn
Received Date: 13 April 2018
Revised Date: 24 August 2018
Accepted Date: 7 September 2018

Fund Project: the National Natural Science Foundation of China 51664042Supported by the National Natural Science Foundation of China(No.51664042)

Figures(7)

By ion-imprinting technology, 3-chloropropyltriethoxysilane as anchor, functional monomer linear polyethyleneimine(PEI) was grafted on the surface of MCM-41 molecular sieve. With Yb ions as template ions, and epichlorohydrin as cross-linking agent, a Yb(Ⅲ) ion-imprinted polymer(IIP), Yb(Ⅲ)-IIP-PEI/MCM-41, was prepared on MCM-41 surface. A non-ion-imprinted polymer(NIP-PEI/MCM-41) was prepared via similar process. Yb³⁺ imprinted polymer was characterized by infrared spectroscopy and scanning electron microscopy. The optimal adsorption conditions and selective adsorption performance of Yb(Ⅲ)-IIP-PEI/MCM-41 for Yb³⁺ were determined by static adsorption method. The maximum adsorption capacities of Yb(Ⅲ)-IIP-PEI/MCM-41 and NIP-PEI/MCM-41 are 229.93 mg/g and 99.27 mg/g, respectively. The adsorption of Yb³⁺ by the imprinted material is conformed to the Langmuir model; The equilibrium can basically be reached in 40 min, and the adsorption process can be described using the pseudo-second-order kinetic model. Yb(Ⅲ)-IIP-PEI/MCM-41 has strong selectivity toward Yb³⁺ and also has good recyclability. This adsorbent with high adsorption capacity and high selectivity for rare earth Yb ions combining the advantages of MCM-41 and ion-imprinted polymer thus-prepared lays the foundation for further application in the separation and recovery of low-concentration earth elements from wastewater.
- ytterbium ion,
- ion imprinted polymer,
- MCM-41 molecular sieve,
- polyethylenimine
1. [1]
  LI Xizhong, SUN Yanping. Assembly and Characterization of Inorganic-Organic Hybrid Mesoporous Materials[J]. J Taiyuan Univ Technol, 2007,38(4):316-319. doi: 10.3969/j.issn.1007-9432.2007.04.010
2. [2]
  LAI Xiaoqi, YANG Yuanqi, XUE Jun. Preparation and Properties of Iridium(Ⅲ) Ion Imprinted Polymers[J]. Acta Chim Sin, 2009,67(8):863-868. doi: 10.3321/j.issn:0567-7351.2009.08.025
3. [3]
  Kala R, Biju V M, Rao T P. Synthesis, Characterization, and Analytical Applications of Erbium(Ⅲ) Ion Imprinted Polymer Particles Prepared via γ-Irradiation with Different Functional and Crosslinking Monomers[J]. Anal Chim Acta, 2005,549:51-58. doi: 10.1016/j.aca.2005.06.024
4. [4]
  Kala R, Gladis J M, Rao T P. Preconcentrative Separation of Erbium from Y, Dy, Ho, Tb and Tm by Using Ion Imprinted Polymer Particles via Solid Phase Extraction[J]. Anal Chim Acta, 2004,518:143-150. doi: 10.1016/j.aca.2004.05.029
5. [5]
  WU Xinhua, SHI Hui, YANG Xiaoyu. Progress in Separation and Enrichment of Trace Metal Ions by Surface Imprinting Technique[J]. Guangzhou Chem Ind, 2015,3:10-12.
6. [6]
  Guo J J, Cai J B, Su Q D. Ion Imprinted Polymer Particles of Neodymium:Synthesis, Characterization and Selective Recognition[J]. J Rare Earth, 2009(27):22-27.
7. [7]
  Yang X L, Zhang J W. Recovery of Rare Earth from Ion-adsorption Rare Earth Ores with a Compound Lixiviant[J]. Sep Purif Technol, 2015(142):203-208.
8. [8]
  LI Xiancai, TIAN Minglei, CHENG Yuwen. Preparation and Properties of Lanthanum Ion MCM-41 Imprinted Polymer[J]. J Nanchang Univ(Eng Tech Edit), 2018,40(4):307-310.
9. [9]
  LIU Zhigang, WANG Jiangang, YU Shihua. Preparation of MCM-41 and Its Application in the Sustained Release of Piracetam[J]. Chem Ind Technol, 2013,6:42-44.
10. [10]
  WANG Huanlong. Synthesis and Properties of MCM-41 Molecular Sieve[D]. Inner Mongolia University Science Technology, 2012(in Chinese).
11. [11]
  Wang W, Li Y, Gao B. Effective Removal of Fe(Ⅱ) Impurity from Rare Earth Solution Using Surface Imprinted Polymer[J]. Chem Eng Res Des, 2013,91:2759-2764. doi: 10.1016/j.cherd.2013.05.006
12. [12]
  An F, Gao B, Feng X. Adsorption and Recognizing Ability of Molecular Imprinted Polymer MIP-PEI/SiO₂Towards Phenol[J]. J Hazard Mater, 2008,157(2):286-292.
13. [13]
  Sarri S, Misaelides P, Zamboulis D. Rhenium(Ⅶ) and Technetium(Ⅶ) Separation from Aqueous Solutions Using a Polyethylenimine-Epichlorohydrin Resin[J]. J Radioanal Nucl Chem, 2015,307(1):681-689.
14. [14]
  Liao S, Zhang W, Wei L. Adsorption Characteristics, Recognition Properties, and Preliminary Application of Nordihydroguaiaretic Acid Molecularly Imprinted Polymers Prepared by Sol-gel Surface Imprinting Technology[J]. Appl Surf Sci, 2016,364:579-588. doi: 10.1016/j.apsusc.2015.12.184
15. [15]
  Fasihi J, Shamsipur M, Khanchi A. Imprinted Polymer Grafted from Silica Particles for On-line Trace Enrichment and ICP OES Determination of Uranyl Ion[J]. Microchem J, 2015,126:316-321.
16. [16]
  An F, Gao B, Huang X. Selectively Removal of Al(Ⅲ) from Pr(Ⅲ) and Nd(Ⅲ) Rare Earth Solution Using Surface Imprinted Polymer[J]. React Funct Polym, 2013,73(1):60-65. doi: 10.1016/j.reactfunctpolym.2012.08.022
17. [17]
  Wu H, Qiu J. Adsorption Performance for Bromine Ion Using Bromide Ion-Lanthanum Nitrate Modified Chitosan Imprinted Polymer[J]. Anal Methods-UK, 2014,6(6):1890-1896. doi: 10.1039/C3AY40687C
18. [18]
  Li C X, Pan J M, Gao J. An Ion-imprinted Polymer Supported by Attapulgite with a Chitosan Incorporated Sol-gel Process for Selective Separation of Ce(Ⅲ)[J]. Chinese Chem Lett, 2009,20(8):985-989. doi: 10.1016/j.cclet.2009.03.020
19. [19]
  CHEN Rui. Preparation of SBA-15 Surface Ion-Imprinted Polymer and Its Selective Separation of Medium and Low-level Radioactive Metals[D]. Jiangsu University of Science and Technology, 2014(in Chinese).
20. [20]
  Gao B, Zhang Y, Xu Y. Study on Recognition and Separation of Rare Earth Ions at Picometre Scale by Using Efficient Ion-Surface Imprinted Polymer Materials[J]. Hydrometallurgy, 2014,150:83-91. doi: 10.1016/j.hydromet.2014.09.017
21. [21]
  Kameda T, Umetsu M, Kumagai S. New Principals on the Adsorption of Alkyl Compound by Mg-Al Oxide:Adsorption Kinetics and Equilibrium Studies[J]. Colloid Surf A, 2017,513:348-354. doi: 10.1016/j.colsurfa.2016.10.063
22. [22]
  Kameda T, Shinmyou T, Yoshioka T. Kinetics and Equilibrium Studies on the Uptake of Nd³⁺ by Zn-Al Layered Double Hydroxide Intercalated with Triethylenetetramine-Hexaacetic Acid[J]. Mater Chem Phys, 2017,191:96-98. doi: 10.1016/j.matchemphys.2017.01.050
23. [23]
  Adebisi G A, Alaba P A. Equilibrium, Kinetic, and Thermodynamic Studies of Lead Ion and Zinc Ion Adsorption from Aqueous Solution onto Activated Carbon Prepared from Palm Oil Mill Effluent[J]. J Clean Prod, 2017,148:958-968. doi: 10.1016/j.jclepro.2017.02.047
24. [24]
  Asuquo E, Martin A, Nzerem P. Adsorption of Cd(Ⅱ) and Pb(Ⅱ) Ions from Aqueous Solutions Using Mesoporous Activated Carbon Adsorbent:Equilibrium, Kinetics and Characterisation Studies[J]. J Environ Chem Eng, 2017,5(1):679-698. doi: 10.1016/j.jece.2016.12.043
25. [25]
  Maneechakr P, Karnjanakom S. Adsorption Behaviour of Fe(Ⅱ) and Cr(Ⅵ) on Activated Carbon:Surface Chemistry, Isotherm, Kinetic and Thermodynamic Studies[J]. J Chem Thermodyn, 2017,106:104-112. doi: 10.1016/j.jct.2016.11.021
26. [26]
  Badawi M A, Negm N A, Abou Kana M T H. Adsorption of Aluminum and Lead from Wastewater by Chitosan-Tannic Acid Modified Biopolymers:Isotherms, Kinetics, Thermodynamics and Process Mechanism[J]. Int J Biol Macromol, 2017,99:465-476. doi: 10.1016/j.ijbiomac.2017.03.003
1. [1]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
2. [2]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
3. [3]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
4. [4]
  Chunyuan Kang , Xiaoyu Li , Fan Yang , Bai Yang . Ionic-bond crosslinked carbonized polymer dots for tunable and enhanced room temperature phosphorescence. Acta Physico-Chimica Sinica, 2026, 42(1): 100156-0. doi: 10.1016/j.actphy.2025.100156
5. [5]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
6. [6]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
7. [7]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
8. [8]
  Weijie Yang , Mansheng Chen , Chen Xu , Fujian Xu . Hydroxyl-Rich Polycations: Innovative Materials Empowering Life and Health. University Chemistry, 2025, 40(9): 332-343. doi: 10.12461/PKU.DXHX202410072
9. [9]
  Wen Tang , Luyu Sui , Qian Chen , Jun Shao , Xinwen Peng , Jianwen Jiang , Shuiliang Chen . Project-based Teaching of “the Condensed State of Polymers”: Unveiling the Lithium-Ion Battery Separator. University Chemistry, 2025, 40(11): 115-126. doi: 10.12461/PKU.DXHX202412108
10. [10]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . Emerging Irreversible and Reversible Ion Migrations in Perovskites. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-0. doi: 10.3866/PKU.WHXB202311011
11. [11]
  Rongzhan LOU , Qiaoling KANG , Zhenchao BAI , Dongyun LI , Yang XU , Rui WANG , Qingyi LU . Research progress of sodium ion high entropy layered oxide cathode. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2411-2428. doi: 10.11862/CJIC.20250142
12. [12]
  Zhiming Feng , Lili Wu , Chengming Wang . Doubly Oxidized Carbene. University Chemistry, 2025, 40(9): 326-331. doi: 10.12461/PKU.DXHX202411008
13. [13]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
14. [14]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
15. [15]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
16. [16]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
17. [17]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
18. [18]
  Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
19. [19]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
20. [20]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1317)
HTML views(307)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142