Citation: LI Wenjin, YAO Weilong, XU Jiaxin, JIANG Qiying, DENG Hongquan. Preparation and Photocatalytic Properties of Ho³⁺ Doping BiFeO₃[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 91-96. doi: 10.11944/j.issn.1000-0518.2019.01.180080 shu

Preparation and Photocatalytic Properties of Ho³⁺ Doping BiFeO₃

School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China

Corresponding author: JIANG Qiying, jqy_163@163.com
Received Date: 21 March 2018
Revised Date: 14 May 2018
Accepted Date: 15 June 2018

Fund Project: the Sichuan′s Training Program of Innovation and Entrepreneurship for Undergraduate 201810619019Supported by the Sichuan′s Training Program of Innovation and Entrepreneurship for Undergraduate(No.201810619019)

Figures(6)

In order to improve photocalytic property and enhance magnetism of BiFeO₃(BFO), nano-sized Bi_0.95Ho_0.05FeO₃(BHFO) particles were prepared through thermal decomposition of coordination precursor at 500℃. The material obtained was characterized by X-ray diffractometer(XRD), Fourier transfom infrared(FT-IR) spectrometer, dynamic reflectance spectrometer(DRS), vibrating sample magnetometer(VSM), and Zeta potential analyser. It exhibits rhombohedral R3c phase with a band gap of 1.90 eV, and its magnetism is 5 times stronger than BFO. With methyl orange(MO) as the degradation model, the influence factors on photocatalytic activity of BHFO was found to be affected by the oxidization and acid-base property of anions. At last, BHFO exhibits good photocatalytic stability and can be recovered by magnetical separation.
- BiFeO₃,
- Ho³⁺,
- methyl orange,
- photo-catalysis,
- magnetic property
1. [1]
  Caroline P, Vinitha G, Joseph D. A Review on the Visible Active BiFeO₃ Nanostructures as Suitable Photocatalyst in the Degradation of Different Textile Dyes[J]. Environ Nanotechnol Monit Manag, 2017,7:110-120.
2. [2]
  Lam S M, Sin J C, Mohamed A R. A Newly Emering Visible Light-Responsive BiFeO₃ Perovskite for Photocatalytic Applications:A Mini Review[J]. Mater Res Bull, 2017,90:15-30. doi: 10.1016/j.materresbull.2016.12.052
3. [3]
  Wu J, Fan Z, Xiao D. Multiferroic Bismuth Ferrite-Based Materials for Multifunctional Applications:Ceramic Bulks, Thin Films and Nanostructures[J]. Prog Mater Sci, 2016,84:335-402. doi: 10.1016/j.pmatsci.2016.09.001
4. [4]
  Xu Q, Zheng X, Wang L. The Structural and Multiferroic Properties of Bi_1-xLa_xFe_0.95Co_0.05O₃(x=0, 0.10, 0.20, 0.30) Ceramics Through Tartaric Acid Modified Sol Gel Method[J]. Phys B, 2012,407:4793-4796. doi: 10.1016/j.physb.2012.09.021
5. [5]
  Song G L, Su J, Ma G J. Effects of Trivalent Gadolinium and Cobalt co-Substitution on the Crystal Structure, Electronic Transport, and Ferromagnetic Properties of Bismuth Ferrite[J]. Mater Sci Semicond Process, 2014,27:899-908. doi: 10.1016/j.mssp.2014.09.004
6. [6]
  Meng W, Hu R, Yang J. Influence of Lanthanum-Doping on Photocatalytic Properties of BiFeO₃ for Phenol Degradation[J]. Chinese J Catal, 2016,37:1283-1292. doi: 10.1016/S1872-2067(16)62449-X
7. [7]
  Pradhan S K, Rout P P, Mohant V R. Effect of Holmium Substitution for the Improvement of Multiferroic Properties of BiFeO₃[J]. J Phys Chem Solid, 2010,71:1557-1564. doi: 10.1016/j.jpcs.2010.08.001
8. [8]
  Annapu Reddy V, Pathak N P, Nath R. Particle Size Dependent Magnetic Properties and Phase Transitions in Multiferroic BiFeO₃ Nano-Particles[J]. J Alloy Compd, 2012,543:206-212. doi: 10.1016/j.jallcom.2012.07.098
9. [9]
  Chen X Z, Qiu Z C, Zhou J P. Large-Scale Growth and Shape Evolution of Bismuth Ferrite Particles with a Hydrothermal Method[J]. Mater Chem Phys, 2011,126:560-567. doi: 10.1016/j.matchemphys.2011.01.027
10. [10]
  Rao T D, Karthik T, Asthana S. Investigation of Structural, Magnetic and Optical Properties of Rare Earth Substituted Bismuth Ferrite[J]. J Rare Earths, 2013,31(4):370-375. doi: 10.1016/S1002-0721(12)60288-9
11. [11]
  WENG Shifu. FT-IR Spectrometer[M]. Beijing:Chemical Industry Press, 2005(in Chinese).
12. [12]
  Minh N V, Gia Quan N. Structural, Optical and Electromagnetic Properties of Bi_1-xHo_xFeO₃ Multiferroic Materials[J]. J Alloy Compd, 2011,509:2663-2666. doi: 10.1016/j.jallcom.2010.12.033
13. [13]
  Zou J, Jiang J, Zhang Y. A Comparative Study of the Optical, Magnetic and Electrocatalytic Properties of Nano BiFeO₃ with Different Morphologies[J]. Mater Lett, 2012,72:134-136. doi: 10.1016/j.matlet.2011.12.091
14. [14]
  REN Xuechang, CHENG Xuemin, ZHAO Haoxing. Effect of Inorganic Anions on Photocatalytic Degradation of Formaldehyde by TiO₂ Thin Films[J]. Chinese J Environ Eng, 2008,2(10):1339-1345.
15. [15]
  Hu Z, Chen D, Wang S. Facile Synthesis of Sm-Doped BiFeO₃ Nanoparticles for Enhanced Visible Light Photocatalytic Performance[J]. Mater Sci Eng B, 2017,220:1-12. doi: 10.1016/j.mseb.2017.03.005
16. [16]
  ZHANG Pengfei, DENG Hongquan, JIANG Qiying. Preparation of Bismuth Ferrite Composite Oxide and Its Photocatalytic Performance[J]. Chinese Environ Sci Technol, 2015,38(4):6-10.
17. [17]
  Uniyal H, Yadav K L. Enhanced Magnetoelectric Properties in Bi_0.95Ho_0.05FeO₃ Polycrystalline Ceramics[J]. J Alloys Compd, 2012,511:149-153. doi: 10.1016/j.jallcom.2011.09.012
1. [1]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
2. [2]
  Ze Luo , Yukun Zhu , Yadan Luo , Guangmin Ren , Yonghong Wang , Hua Tang . Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(3): 100166-0. doi: 10.1016/j.actphy.2025.100166
3. [3]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
4. [4]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
5. [5]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
6. [6]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
7. [7]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
8. [8]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
9. [9]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
10. [10]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
11. [11]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
12. [12]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
13. [13]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
14. [14]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
17. [17]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
18. [18]
  Yanping Qiu , Jiatong Zhang , Linping Li , Yangqin Gao , Ning Li , Lei Ge . MOF-derived g-C₃N₄/ZnIn₂S₄ S-scheme heterojunction: interface-engineering enhanced photocatalytic NO conversion. Acta Physico-Chimica Sinica, 2026, 42(4): 100175-0. doi: 10.1016/j.actphy.2025.100175
19. [19]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
20. [20]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(2034)
HTML views(317)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Properties of Ho3+ Doping BiFeO3

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Properties of Ho³⁺ Doping BiFeO₃