Citation: WANG Renliang, ZHU Yanmei, JI Haiwei. Synthesis of Ordered Supermicroporous Silica Using Short-Chain Quaternary Ammonium/Fatty Acid Salts as Template[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 51-57. doi: 10.11944/j.issn.1000-0518.2019.01.180069 shu

Synthesis of Ordered Supermicroporous Silica Using Short-Chain Quaternary Ammonium/Fatty Acid Salts as Template

School of Chemistry and Pharmaceutical Engineering, Taishan Medical University, Taian, Shangdong 271016, China

Corresponding author: ZHU Yanmei, renliangw@163.com
Received Date: 13 March 2018
Revised Date: 4 April 2018
Accepted Date: 7 June 2018

Fund Project: Foundation for High-Level Project Development 2015GCC19Science and Technology Research Program for Colleges and Universities J17KB072the Foundation of Key Laboratory of Colloid and Interface Chemistry(Shandong University), Ministry of Education 201407Supported by the Foundation of Key Laboratory of Colloid and Interface Chemistry(Shandong University), Ministry of Education(No.201407), Foundation for High-Level Project Development(No.2015GCC19), Science and Technology Research Program for Colleges and Universities(No.J17KB072)

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Supermicroporous materials possess pore size of 1~2 nm. They are expected to exhibit size-and shape-based separation/catalytic applications, which plays important role in modern industry. It is challenging to find an economic/simple surfactant system for the synthesis of supermicroporous materials. In this work, supermicroporous silica was synthesized using short-chain quaternary ammonium salt(decyltrimethyl ammonium bromide, denoted C₁₀ TAB) surfactant system mixed with fatty acid salts as the templating agents. The samples were characterized by small-angle X-ray diffraction(XRD), N₂ adsorption-desorption, Fourier transform infrared spectroscopy(FTIR), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The results indicate that the length of alkyl chain in co-surfactant, the dosage amount, crystallization temperature have great effects on the regularity of the pore structure. We can obtain highly ordered supermicroporous silica when using sodium octanoate(denoted SO) as co-surfactant in the molar ratio of n(C₁₀TAB):n(Na₂SiO₃):n(SO):n(H₂O)=1:1.5:0.3:800, at the crystallization temperature of 80℃. The calcinated materials possess surface area 1300 m²/g and pore volume 0.49 cm³/g with a pore size distribution centered at about 1.90 nm.
- supermicroporous silcia,
- short-chain quaternary ammonium salt,
- fatty acid salts,
- micellar,
- mixed surfactants system
1. [1]
  Jiang J X, Yu J H, Corma A. Extra-Large-Pore Zeolites:Bridging the Gap Between Micro and Mesoporous Structures[J]. Angew Chem Int Ed, 2010,49(18):3120-3145. doi: 10.1002/anie.v49:18
2. [2]
  Chal R, Gerardin C, Bulut M. Overview and Industrial Assessment of Synthesis Strategies Towards Zeolites with Mesopores[J]. ChemCatChem, 2011,3(1):67-81. doi: 10.1002/cctc.201000158
3. [3]
  Beck J S, Vartuli J C, Roth W J. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates[J]. J Am Chem Soc, 1992,114(27):10834-10843. doi: 10.1021/ja00053a020
4. [4]
  Abdelhamid S. Catalysis by Crystalline Mesoporous Molecular Sieves[J]. Chem Mater, 1996,8(8):1840-1852. doi: 10.1021/cm950585+
5. [5]
  Ying J Y, Mehnert C P, Wong M S. Synthesis and Applications of Supramolecular-Templated Mesoporous Materials[J]. Angew Chem Int Ed, 1999,30(12):56-77.
6. [6]
  Hu W B, Xie H L, Yue H B. Super-Microporous Silica-Supported Platinum Catalyst for Highly Regioselective Hydrosilylation[J]. Catal Commun, 2017,97:51-55. doi: 10.1016/j.catcom.2017.04.015
7. [7]
  Fu W H, Liang X M, Zhang H D. Shape Selectivity Extending to Ordered Supermicroporous Aluminosilicates[J]. Chem Commun, 2015,51(8):1449-1452. doi: 10.1039/C4CC08784D
8. [8]
  Watanabe H, Fujikata K, Oaki Y. Dynamic Adsorption of Toluene on Pore-Size Tuned Supermicroporous Silica[J]. Micropor Mesopor Mater, 2015,214:41-44. doi: 10.1016/j.micromeso.2015.04.034
9. [9]
  Suzuki T, Watanabe H, Ueno T. Significant Increase in Band Gap and Emission Efficiency of In₂O₃ Quantum Dots by Size-Tuning Around 1 nm in Supermicroporous Silicas[J]. Langmuir, 2017,33(12):3014-3017. doi: 10.1021/acs.langmuir.6b04181
10. [10]
  Di Y, Meng X J, Wang L F. Ultralow Temperature Synthesis of Ordered Hexagonal Smaller Supermicroporous Silica Using Semifluorinated Surfactants as Template[J]. Langmuir, 2006,22(7):3068-3072. doi: 10.1021/la0521342
11. [11]
  Bagshaw S A, Hayman A R. Novel Super-Microporous Silicate Templating by ω-Hydroxyalkylammonium Halide Bolaform Surfactants[J]. Chem Commun, 2000,7(7):533-534.
12. [12]
  Bagshaw S A, Hayman A R. Super-Microporous Silicate Molecular Sieves[J]. Adv Mater, 2001,13(12/13):1011-1013.
13. [13]
  Ryoo R, Park I S, Jun S. Synthesis of Ordered and Disordered Silicas with Uniform Pores on the Border Between Micropore and Mesopore Regions Using Short Double-Chain Surfactants[J]. J Am Chem Soc, 2001,123(8):1650-1657. doi: 10.1021/ja0038326
14. [14]
  Wang R L, Han S H, Hou W G. Highly Ordered Supermicroporous Silica[J]. J Phys Chem C, 2007,111(29):10955-10958. doi: 10.1021/jp0716029
15. [15]
  Zhou Y, Antonietti M. Preparation of Highly Ordered Monolithic Super-microporous Lamellar Silica with a Room-Temperature Ionic Liquid as Template via the Nanocasting Technique[J]. Adv Mater, 2003,15(17):1452-1455. doi: 10.1002/(ISSN)1521-4095
16. [16]
  Zhou Y, Antonietti M. A Series of Highly Ordered, Super-Microporous, Lamellar Silicas Prepared by Nanocasting with Ionic Liquids[J]. Chem Mater, 2004,16(3):544-550. doi: 10.1021/cm034442w
17. [17]
  Wang P, Chen S X, Zhao Z D. Synthesis of Ordered Porous SiO₂ with Pores on the Border Between the Micropore and Mesopore Regions Using Rosin-Based Quaternary Ammonium Salt[J]. RSC Adv, 2015,5(15):11223-11228. doi: 10.1039/C4RA12113A
18. [18]
  LIU Chunyan, GONG Caiyun, ZHOU Dongxue. Modified Jeffamine Molecular Tools for Ordered Mesoporous and Super-micorporous Silica Microsphere Particles[J]. Chinese J Inorg Chem, 2015,31(5):954-960.
19. [19]
  Hao J C, Hoffmann H. Self-assembled Structures in Excess and Salt-Free Catanionic Surfactant Solutions[J]. Curr Opin Colloid Interface Sci, 2004,9(3/4):279-293.
20. [20]
  HAN Feng, FU Honglan, HE Xiao. Superior Stable Vesicle Formation in Mixed Cationic and Anionic Surfactant Systems[J]. Acta Chim Sin, 2003,61(9):1399-1404. doi: 10.3321/j.issn:0567-7351.2003.09.011
21. [21]
  DONG Wenjing, ZHAO Jianxi. Self-Assembly of Cationic/Anionic Surfactants with Highly Dissymmetric Lengths of Alkyl Tails[J]. Acta Phys Chim Sin, 2015,31(8):1535-1540.
22. [22]
  MU Mingwei, PENG Ce, WANG Song. Synthesis and Characterization of Mesoporous Silica Vesicles Using Cationic-Anionic Binary Surfactant as Template[J]. Chem J Chinese Univ, 2013,34(6):1309-1312.
23. [23]
  WANG Wenxuan, DENG Shaoxin, SHI Chengxiang. Synthesis of Mesoporous Silica Using Anionic Surfactant/Cationic Polyamine as a Template[J]. Acta Phys Chim Sin, 2015,31(4):707-714.
24. [24]
  Ohkubo T, Ogura T, Sakai H. Synthesis of Highly-Ordered Mesoporous Silica Particles Using Mixed Cationic and Anionic Surfactants as Templates[J]. J Colloid Interface Sci, 2007,312(1):42-46. doi: 10.1016/j.jcis.2007.02.043
25. [25]
  Anacker E W. Organic Counterions and Micellar Parameters. n-Alkyl Carboxylates[J]. J Phys Chem, 1981,85(17):2463-2466. doi: 10.1021/j150617a011
26. [26]
  Lin Y S, Lin H P, Mou C P. A Simple Synthesis of Well-Ordered Super-Microporous Aluminosilicate[J]. Micropor Mesopor Mater, 2004,76(1/3):203-208.
27. [27]
  Galarneau A, Desplantier D, Dutartre R. Micelle-templated Silicates as a Test Bed for Methods of Mesopore Size Evaluation[J]. Micropor Mesopor Mater, 1999,27(2/3):297-308.
28. [28]
  Ravikovitch P I, Domhnaill S C, Neimark A V. Capillary Hysteresis in Nanopores:Theoretical and Experimental Studies of Nitrogen Adsorption on MCM-41[J]. Langmuir, 1995,11(12):4765-4772. doi: 10.1021/la00012a030
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