Citation: WANG Renliang, ZHU Yanmei, JI Haiwei. Synthesis of Ordered Supermicroporous Silica Using Short-Chain Quaternary Ammonium/Fatty Acid Salts as Template[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 51-57. doi: 10.11944/j.issn.1000-0518.2019.01.180069 shu

Synthesis of Ordered Supermicroporous Silica Using Short-Chain Quaternary Ammonium/Fatty Acid Salts as Template

School of Chemistry and Pharmaceutical Engineering, Taishan Medical University, Taian, Shangdong 271016, China

Corresponding author: ZHU Yanmei, renliangw@163.com
Received Date: 13 March 2018
Revised Date: 4 April 2018
Accepted Date: 7 June 2018

Fund Project: Foundation for High-Level Project Development 2015GCC19Science and Technology Research Program for Colleges and Universities J17KB072the Foundation of Key Laboratory of Colloid and Interface Chemistry(Shandong University), Ministry of Education 201407Supported by the Foundation of Key Laboratory of Colloid and Interface Chemistry(Shandong University), Ministry of Education(No.201407), Foundation for High-Level Project Development(No.2015GCC19), Science and Technology Research Program for Colleges and Universities(No.J17KB072)

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Supermicroporous materials possess pore size of 1~2 nm. They are expected to exhibit size-and shape-based separation/catalytic applications, which plays important role in modern industry. It is challenging to find an economic/simple surfactant system for the synthesis of supermicroporous materials. In this work, supermicroporous silica was synthesized using short-chain quaternary ammonium salt(decyltrimethyl ammonium bromide, denoted C₁₀ TAB) surfactant system mixed with fatty acid salts as the templating agents. The samples were characterized by small-angle X-ray diffraction(XRD), N₂ adsorption-desorption, Fourier transform infrared spectroscopy(FTIR), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The results indicate that the length of alkyl chain in co-surfactant, the dosage amount, crystallization temperature have great effects on the regularity of the pore structure. We can obtain highly ordered supermicroporous silica when using sodium octanoate(denoted SO) as co-surfactant in the molar ratio of n(C₁₀TAB):n(Na₂SiO₃):n(SO):n(H₂O)=1:1.5:0.3:800, at the crystallization temperature of 80℃. The calcinated materials possess surface area 1300 m²/g and pore volume 0.49 cm³/g with a pore size distribution centered at about 1.90 nm.
- supermicroporous silcia,
- short-chain quaternary ammonium salt,
- fatty acid salts,
- micellar,
- mixed surfactants system
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