Citation: QU Haonan, BAO Chong, MA Wenjing, MA Yiming, ZHAO Peng, WANG Xinhai, ZHOU Yanmei. Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride[J]. Chinese Journal of Applied Chemistry, ;2019, 36(1): 58-64. doi: 10.11944/j.issn.1000-0518.2019.01.180049 shu

Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

  • Corresponding author: WANG Xinhai, xinhaiwang@126.com ZHOU Yanmei, zhouyanmei@henu.edu.cn
  • Received Date: 19 February 2018
    Revised Date: 16 April 2018
    Accepted Date: 7 June 2018

    Fund Project: Supported by the National Natural Science Foundation of China(No.21576071, No.21776061)the National Natural Science Foundation of China 21776061the National Natural Science Foundation of China 21576071

Figures(5)

  • Cellulose is a renewable resource. Compounds obtained by the hydrolysis of cellulose are of great significance to ease the energy pressure. Herein, the hydrolysis of cellulose catalyzed by solid carbon sulfonic acid supported 1-butyl-3-methylimidazolium chloride is reported. The solid carbon sulfonic acid obtained from bamboo biomass by pre-carbonization at 700℃ and sulfonation at 150℃ was used as the matrix. Ionic liquid functionalized solid carbon sulfonic acid catalyst was obtained by loading 1-butyl-3-methylimidazolium chloride. The results show that the total reducing sugar yield under optimal conditions is increased by 15.2% relative to the total reducing sugar yield by exploiting solid carbon sulfonic acid. The catalyst still exhibits good performance after recycling.
  • 加载中
    1. [1]

      Liu Y, West A R. Semiconductor-Insulator Transition in Undoped Rutile, TiO2, Ceramics[J]. J Am Ceram Soc, 2013,96(1):218-222. doi: 10.1111/jace.12025

    2. [2]

      Ogaki Y, Yu S, Hara T. Hemicellulose Decomposition and Saccharides Production from Various Plant Biomass by Sulfonated Allophane Catalyst[J]. Catal Today, 2011,164(1):415-418. doi: 10.1016/j.cattod.2010.11.002

    3. [3]

      Xu A, Wang J, Wang H. Effects of Anionic Structure and Lithium Salts Addition on the Dissolution of Cellulose in 1-Butyl-3-methylimidazolium-based Ionic Liquid Solvent Systems[J]. Green Chem, 2010,12(2):268-275. doi: 10.1039/B916882F

    4. [4]

      Alonso D M, Gallo J M R, Mellmer M A. Direct Conversion of Cellulose to Levulinic Acid and Gamma-Valerolactone Using Solid Acid Catalysts[J]. Catal Sci Technol, 2013,3(4):927-931. doi: 10.1039/C2CY20689G

    5. [5]

      Goswami M, Meena S, Navatha S. Hydrolysis of Biomass Using a Reusable Solid Carbon Acid Catalyst and Fermentation of the Catalytic Hydrolysate to Ethanol[J]. Bioresour Technol, 2015,188:99-102. doi: 10.1016/j.biortech.2015.03.012

    6. [6]

      OUYANG Siyu, XU Qiong, FU Zaihui. New Progress in Acid Catalysis of Biomass Conversion to 5-Hydroxymethylfurfural[J]. Chem Ind Eng Prog, 2014,33(5):1077-1085.  

    7. [7]

      Li C Z, Qian W, Zhao Z K. Acid in Ionic Liquid:An Efficient System for Hydrolysis of Lignocellulose[J]. Green Chem, 2008,10(2):177-182. doi: 10.1039/B711512A

    8. [8]

      LUO Yingling, XU Zhiquan, YI Weilin. Ionic Liquid Pretreatment of Biomass Improves Saccharification Yield[J]. Chinese J Appl Chem, 2014,31(1):54-60.  

    9. [9]

      LIU Zhen, DAI Hui, WANG Jianji. Ionic Liquid Pretreatment of Enzymatic Hydrolysis of Cellulose[J]. Chinese J Appl Chem, 2009,26(9):1111-1113.  

    10. [10]

      Zhuo K, Du Q, Bai G. Hydrolysis of Cellulose Catalyzed by Novel Acidic Ionic Liquids[J]. Carbohydr Polym, 2015,115:49-53. doi: 10.1016/j.carbpol.2014.08.078

    11. [11]

      Liu X, Xu Q, Liu J. Hydrolysis of Cellulose into Reducing Sugars in Ionic Liquids[J]. Fuel, 2016,164:46-50. doi: 10.1016/j.fuel.2015.09.086

    12. [12]

      YUE Caibo, WEI Yuyang, LV Minjie. Synthesis of Acetates in Novel Acidic Ionic Liquids[Hmim]HSO4[J]. Chinese J Appl Chem, 2006,23(11):1282-1285. doi: 10.3969/j.issn.1000-0518.2006.11.021 

    13. [13]

      WANG Fuyu, LIU Yanli, WANG Chong. Dehydration of Fructose in Acidic Ionic Liquid to Produce 5-Hydroxymethylfurfural[J]. Chinese J Appl Chem, 2014,31(4):424-430.  

    14. [14]

      Hara M, Yoshida T, Takagaki A. A Carbon Material as a Strong Protonic Acid[J]. Angew Chem Int Ed, 2004,43(22):2955-2958. doi: 10.1002/(ISSN)1521-3773

    15. [15]

      Ba Y Y, Xiao L P, Sun R C. Microwave-Assisted Conversion of Biomass Derived Hemicelluloses into Xylo-Oligosaccharides by Novel Sulfonated Bamboo-Based Catalysts[J]. Biomass Bioenergy, 2015,75:245-253. doi: 10.1016/j.biombioe.2015.02.023

    16. [16]

      Yan L, Liu N, Wang Y. Production of 5-Hydroxymethylfurfural from Corn Stalk Catalyzed by Corn Stalk-Derived Carbonaceous Solid Acid Catalyst[J]. Bioresour Technol, 2014,173:462-466. doi: 10.1016/j.biortech.2014.09.148

    17. [17]

      Sun Z, Tao M, Zhao Q. A Highly Active Willow-Derived Sulfonated Carbon Material with Macroporous Structure for Production of Glucose[J]. Cellulose, 2015,22(1):675-682. doi: 10.1007/s10570-014-0540-8

    18. [18]

      Hu L, Li Z, Wu Z. Catalytic Hydrolysis of Microcrystalline and Rice Straw-Derived Cellulose over a Chlorine-Doped Magnetic Carbonaceous Solid Acid[J]. Ind Crops Prod, 2016,84:408-417. doi: 10.1016/j.indcrop.2016.02.039

    19. [19]

      MA Hao, LIAO Chunyan, FAN Meilin. Solubility of Cellulose Anion-Functionalized Ionic Liquids on Cellulose[J]. Chinese J Appl Chem, 2018,35(4):449-456.  

    20. [20]

      Zhang C, Fu Z H, Liu Y C. Ionic Liquid-Functionalized Biochar Sulfonic Acid as a Biomimetic Catalyst for Hydrolysis of Cellulose and Bamboo under Microwave Irradiation[J]. Green Chem, 2012,14(7):1928-1934. doi: 10.1039/c2gc35071h

    21. [21]

      Fu Z, Wan H, Hu X. Preparation and Catalytic Performance of a Carbon-Based Solid Acid Catalyst with High Specific Surface Area[J]. React Kinet Mech Catal, 2012,107(1):203-213. doi: 10.1007/s11144-012-0466-9

    22. [22]

      Li C Z, Zhao Z K. Efficient Acid-Catalyzed Hydrolysis of Cellulose in Ionic Liquid[J]. Adv Synth Catal, 2007,349(11/12):1847-1850.  

    23. [23]

      CAI Xinxing, WANG Zhusheng, LI Ying. Preparation of Biomass Carbon Sulfonic Acid and Its Catalytic Hydrolysis of Cellulose[J]. CIESC J, 2015,66(8):3106-3112.  

  • 加载中
    1. [1]

      Yameen AhmedXiangxiang FengYuanji GaoYang DingCaoyu LongMustafa HaiderHengyue LiZhuan LiShicheng HuangMakhsud I. SaidaminovJunliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI3 Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057

    2. [2]

      Qiang ZhangYuanbiao HuangRong Cao . Imidazolium-Based Materials for CO2 Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040

    3. [3]

      Xiaoning TANGJunnan LIUXingfu YANGJie LEIQiuyang LUOShu XIAAn XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191

    4. [4]

      Yan'e LIUShengli JIAYifan JIANGQinghua ZHAOYi LIXinshu CHANG . MoO3/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054

    5. [5]

      Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020

    6. [6]

      Lisha LEIWei YONGYiting CHENGYibo WANGWenchao HUANGJunhuan ZHAOZhongjie ZHAIYangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202

    7. [7]

      Chao WUQingxiu SHITao XUZhengxi PENGZhongping XIONGYinglin ZHANGYujun SIChaozhong GUO . Enhancement of oxygen reduction reaction performance of iron-nitrogen doped carbon based catalysts by sodium carboxymethyl cellulose pre-deoxygenation. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 737-746. doi: 10.11862/CJIC.20250305

    8. [8]

      Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121

    9. [9]

      Zhi DouHuiyu DuanYixi LinYinghui XiaMingbo ZhengZhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039

    10. [10]

      Zhenhua Wang Haoyang Feng Xiaoyang Shao Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007

    11. [11]

      Qing XueShengyi LiYanan ZhaoPeng ShengLi XuZhengxi LiBo ZhangHui LiBo WangLibin YangYuliang CaoZhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na0.44MnO2 towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041

    12. [12]

      Jianjun LIMingjie RENLili ZHANGLingling ZENGHuiling WANGXiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe2O4@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187

    13. [13]

      Jiahong WANGZekun XUTianjiao LUJinming HUANG . Performance of N, Mn doped semi-coke activated carbon catalyzed ozone oxidation for the degradation of tetracycline hydrochloride in water. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2549-2560. doi: 10.11862/CJIC.20250120

    14. [14]

      Yingran Liang Fei WangJiabao Sun Hongtao Zheng Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024

    15. [15]

      Jun HuangPengfei NieYongchao LuJiayang LiYiwen WangJianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-0. doi: 10.1016/j.actphy.2025.100066

    16. [16]

      Ying LiYushen ZhaoKai ChenXu LiuTingfeng YiLi-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007

    17. [17]

      Shijie LiKe RongXiaoqin WangChuqi ShenFang YangQinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta3N5 S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005

    18. [18]

      Mei Yan Rida Feng Yerdos·Tohtarkhan Biao Long Li Zhou Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103

    19. [19]

      Benhua Wang Chaoyi Yao Yiming Li Qing Liu Minhuan Lan Guipeng Yu Yiming Luo Xiangzhi Song . 一种基于香豆素氟离子荧光探针的合成、表征及性能测试——“科研反哺教学”在有机化学综合实验教学中的探索与实践. University Chemistry, 2025, 40(6): 201-209. doi: 10.12461/PKU.DXHX202408070

    20. [20]

      Kexin DongChuqi ShenRuyu YanYanping LiuChunqiang ZhuangShijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013

Metrics
  • PDF Downloads(7)
  • Abstract views(1457)
  • HTML views(175)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return