Citation: CHEN Lihui, WU Qiuhan, PAN Pei, SONG Zixuan, WANG Feng, DING Yu. Spinel Lithium Manganese Oxide Octahedral Nanoparticles with Excellent Electrochemical Performance as Cathode Materials for Lithium-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2018, 35(11): 1384-1390. doi: 10.11944/j.issn.1000-0518.2018.11.170407 shu

Spinel Lithium Manganese Oxide Octahedral Nanoparticles with Excellent Electrochemical Performance as Cathode Materials for Lithium-Ion Batteries

CHEN Lihui ^a ,
WU Qiuhan ^a ,
PAN Pei ^a ,
SONG Zixuan ^a ,
WANG Feng ^a,b ,
DING Yu ^a,b,,

a.
College of Chemistry and Materials Science, Hubei Engineering University, Xiaogan, Hubei 432000, China
b.
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: DING Yu, dy9802@126.com
Received Date: 14 November 2017
Revised Date: 8 January 2018
Accepted Date: 7 February 2018

Fund Project: Natural Scientific Foundation of Hubei Province T201517Supported by the National Natural Science Foundation of China(No.51402096), Natural Scientific Foundation of Hubei Province(No.T201517)the National Natural Science Foundation of China 51402096

Figures(8)

Spinel LiMn₂O₄ octahedral nanoparticles were prepared by template-directed and high temperature solid-phase methods as cathode materials for lithium-ion batteries. Their structure and electrochemical performances were investigated. The electrochemical performance results show that LiMn₂O₄ as lithium-ion batteries cathode displays excellent cycling stability, rate capability and high specific capacity. The initial charge-discharge specific capacities are 147 mA·h/g and 179 mA·h/g at a current density of 100 mA/g and the voltage of 2.5~4.5 V, respectively. The cathode materials retain reversible charge-discharge capacities of 180 mA·h/g and 181 mA·h/g after 50 cycles, respectively. Excellent electrochemical properties may be attributed to the octahedral LiMn₂O₄ structure. This method is instructive for fabrication and design of excellent electrode materials for lithium ion batteries.
- lithium manganese oxide,
- lithium-ion batteries,
- cathode materials,
- electrochemical performances
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