Citation: YANG Mei, SHI Zhenling, XU Nan, MAO Dan, WANG Dan. Research Progress of Hollow Micro/Nano-Structured Photoanode Materials for Dye-Sensitized Solar Cells[J]. Chinese Journal of Applied Chemistry, ;2018, 35(8): 902-915. doi: 10.11944/j.issn.1000-0518.2018.08.180177 shu

Research Progress of Hollow Micro/Nano-Structured Photoanode Materials for Dye-Sensitized Solar Cells

YANG Mei ^a,, ,
SHI Zhenling ^b ,
XU Nan ^a ,
MAO Dan ^a ,
WANG Dan ^a

a.
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
b.
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: YANG Mei, myang@ipe.ac.cn
Received Date: 16 May 2018
Revised Date: 26 June 2018
Accepted Date: 26 June 2018

Fund Project: the National Natural Science Foundation of China 51472244Supported by the National Natural Science Foundation of China(No.51472244, No.51672274)the National Natural Science Foundation of China 51672274

Figures(9)

The dye-sensitized solar cell(DSSC) has attracted a great attention in the solar energy conversion fields owing to its advantages including low cost, simple fabrication process, and relatively high efficiency. The component and microstructure of semiconductor photoanode as an important part of DSSC have direct roles on the photoelectrochemical performance of solar cell. Hollow micro/nano-structure can provide large surface area and high loading capacity of dyes, improve the light harvesting and promote the charge transport in photovoltaic devices. Therefore, the photoanode materials with hollow micro/nano-structures became a hot topic in recent years. This review addresses the progress of hollow micro/nano-structured photoanode materials, including hollow microsphere, hollow box, core-shell structure, hierarchical hollow microspheres, multi-shelled structure besides the pure or hybrid components. The relationships between each structure and power conversion efficiency(PCE) are analyzed especially. The facing challenge and prospect of hollow micro/nano-structured photoanode in the future are also discussed.
- hollow micro/nano-structure,
- multi-shelled structure,
- dye-sensitized solar cells(DSSC),
- photoanode,
- power conversion efficiency(PCE)
1. [1]
  Service R F. Is It Time to Shoot for the Sun[J]. Science, 2005,309(5734):548-551. doi: 10.1126/science.309.5734.548
2. [2]
  Potocnik J. Renewable Energy Sources and the Realities of Setting an Energy Agenda[J]. Science, 2007,315(5813):810-811. doi: 10.1126/science.1139086
3. [3]
  Schiermeier Q, Tollefson J, Scully T. Energy Alternatives:Electricity without Carbon[J]. Nature, 2008,454(7206):816-823. doi: 10.1038/454816a
4. [4]
  Hagfeldt A, Boschloo G, Sun L. Dye-Sensitized Solar Cells[J]. Chem Rev, 2010,110(11):6595-6663. doi: 10.1021/cr900356p
5. [5]
  O'Regan B, Grätzel M. A Low-Cost, High-Efficient Solar Cell Based on Dye-Sensitized Colloidal TiO₂ Films[J]. Nature, 1991,353(6346):737-740. doi: 10.1038/353737a0
6. [6]
  Grätzel M. Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells[J]. Inorg Chem, 2005,44(20):6841-6851. doi: 10.1021/ic0508371
7. [7]
  Zhang S, Yang X, Numata Y. Highly Efficient Dye-Sensitized Solar Cells:Progress and Future Challenges[J]. Energy Environ Sci, 2013,6(5):1443-1464. doi: 10.1039/c3ee24453a
8. [8]
  Chen M, Ye C, Zhou S. Recent Advances in Applications and Performance of Inorganic Hollow Spheres in Devices[J]. Adv Mater, 2013,44(49):5343-5351.
9. [9]
  Qi J, Lai X, Wang J. Multi-Shelled Hollow Micro-/Nanostructures[J]. Chem Soc Rev, 2015,44(19):6749-6773. doi: 10.1039/C5CS00344J
10. [10]
  Zhou L, Zhuang Z, Zhao H. Intricate Hollow Structures:Controlled Synthesis and Applications in Energy Storage and Conversion[J]. Adv Mater, 2017,29(20)1602914. doi: 10.1002/adma.v29.20
11. [11]
  Mishra A, Fischer M K, Bäuerle P. Metal-Free Organic Dyes for Dye-Sensitized Solar Cells:From Structure:Property Relationships to Design Rules[J]. Angew Chem Int Ed, 2009,48(14):2474-2499. doi: 10.1002/anie.v48:14
12. [12]
  Chung I, Lee B, He J. All-Solid-State Dye-Sensitized Solar Cells with High Efficiency[J]. Nature, 2012,485(7399):486-489. doi: 10.1038/nature11067
13. [13]
  Lee C T, Peng J D, Li C T. Ni₃Se₄ Hollow Architectures as Catalytic Materials for the Counter Electrodes of Dye-Sensitized Solar Cells[J]. Nano Energy, 2014,10:201-211. doi: 10.1016/j.nanoen.2014.09.017
14. [14]
  Grätzel M. Dye-Sensitized Solar Cells[J]. J Photochem Photobiol C, 2003,4:145-153. doi: 10.1016/S1389-5567(03)00026-1
15. [15]
  Kakiage K, Aoyama Y, Yano T. Highly-Efficient Dye-Sensitized Solar Cells with Collaborative Sensitization by Silyl-anchor and Carboxy-anchor Dyes[J]. Chem Commun, 2015,51(88)15894. doi: 10.1039/C5CC06759F
16. [16]
  Ning Z, Fu Y, Tian H. Improvement of Dye-Sensitized Solar Cells:What We Know and What We Need to Know[J]. Energy Environ Sci, 2010,3(9):1170-1181. doi: 10.1039/c003841e
17. [17]
  Mathew S, Yella A, Gao P. Dye-Sensitized Solar Cells with 13% Efficiency Achieved Through the Molecular Engineering of Porphyrin Sensitizers[J]. Nat Chem, 2014(3):242-247.
18. [18]
  Yella A, Lee H W, Tsao H N. Porphyrin-Sensitized Solar Cells with Cobalt(Ⅱ/Ⅲ)-based Redox Electrolyte Exceed 12 Percent Efficiency[J]. Science, 2011,334(6056):629-634. doi: 10.1126/science.1209688
19. [19]
  Li Z Q, Chen W C, Guo F L. Mesoporous TiO₂ Yolk-Shell Microspheres for Dye-Sensitized Solar Cells with a High Efficiency Exceeding 11%[J]. Sci Rep, 2015,514178. doi: 10.1038/srep14178
20. [20]
  Wu W Q, Xu Y F, Rao H S. Multistack Integration of Three-Dimensional Hyperbranched Anatase Titania Architectures for High-Efficiency Dye-Sensitized Solar Cells[J]. J Am Chem Soc, 2014,136(17):6437-6445. doi: 10.1021/ja5015635
21. [21]
  Koo H J, Kim Y J, Lee Y H. Nano-embossed Hollow Spherical TiO₂ as Bifunctional Material for High-Efficiency Dye-Sensitized Solar Cells[J]. Adv Mater, 2008,20(1):195-199. doi: 10.1002/(ISSN)1521-4095
22. [22]
  Wang Z S, Kawauchi H, Kashima T. Significant Influence of TiO₂ Photoelectrode Morphology on the Energy Conversion Efficiency of N719 Dye-Sensitized Solar Cell[J]. Coord Chem Rev, 2004,248(13):1381-1389.
23. [23]
  Bach U, Lupo D, Comte P. Solid-state Dye-Sensitized Mesoporous TiO₂ Solar Cells with High Photon-to-Electron Conversion Efficiencies[J]. Nature, 1998,395(6702):583-585. doi: 10.1038/26936
24. [24]
  Nazeeruddin M K, Pechy P, Renouard T. Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO₂-based Solar Cells[J]. J Am Chem Soc, 2001,123(8):1613-1624. doi: 10.1021/ja003299u
25. [25]
  Jose R, Thavasi V, Ramakrishna S. Metal Oxides for Dye-Sensitized Solar Cells[J]. J Am Ceram Soc, 2009,92(2):289-301. doi: 10.1111/jace.2009.92.issue-2
26. [26]
  Quintana M, Edvinsson T, Hagfeldt A. Comparison of Dye-Sensitized ZnO and TiO₂ Solar Cells:Studies of Charge Transport and Carrier Lifetime[J]. J Phys Chem C, 2007,111(2):1035-1041. doi: 10.1021/jp065948f
27. [27]
  Zhang Q, Dandeneau C S, Zhou X. ZnO Nanostructures for Dye-Sensitized Solar Cells[J]. Adv Mater, 2009,21(41):4087-4108. doi: 10.1002/adma.v21:41
28. [28]
  Gubbala S, Chakrapani V, Kumar V. Band-edge Engineered Hybrid Structures for Dye-Sensitized Solar Cells based on SnO₂ Nanowires[J]. Adv Funct Mater, 2008,18(16):2411-2418. doi: 10.1002/adfm.v18:16
29. [29]
  Chen J, Li C, Xu F. Hollow SnO₂ Microspheres for High-Efficiency Bilayered Dye Sensitized Solar Cell[J]. RSC Adv, 2012,2(19):7384-7387. doi: 10.1039/c2ra20909h
30. [30]
  Sayama K, Sugihara H, Arakawa H. Photoelectrochemical Properties of a Porous Nb₂O₅ Electrode Sensitized by a Ruthenium Dye[J]. Chem Mater, 1998,10(12):3825-3832. doi: 10.1021/cm980111l
31. [31]
  Law M, Greene L E, Johnson J C. Nanowire Dye-Sensitized Solar Cells[J]. Nat Mater, 2005,4:455-459. doi: 10.1038/nmat1387
32. [32]
  Deepak T G, Anjusree G S, Thomas S. A Review on Materials for Light Scattering in Dye-sensitized Solar Cells[J]. RSC Adv, 2014,417615. doi: 10.1039/C4RA01308E
33. [33]
  Wang Y F, Li K N, Xu Y F. Hydrothermal Fabrication of Hierarchically Macroporous Zn₂SnO₄ for Highly Efficient Dye-Sensitized Solar Cells[J]. Nanoscale, 2013,5:5940-5948. doi: 10.1039/c3nr01133j
34. [34]
  Xu Y, Schoonen M A A. The Absolute Energy Positions of Conduction and Valence Bands of Selected Semiconducting Minerals[J]. Am Mineral, 2000,85(3/4):543-556.
35. [35]
  Concina I, Vomiero A. Metal Oxide Semiconductors for Dye-and Quantum-Dot-Sensitized Solar Cells[J]. Small, 2015,11(15):1744-1774. doi: 10.1002/smll.201402334
36. [36]
  Chen H Y, Kuang D B, Su C Y. Hierarchically Micro/nanostructured Photoanode Materials for Dye-Sensitized Solar Cells[J]. J Mater Chem, 2012,22(31):15475-15489. doi: 10.1039/c2jm32402d
37. [37]
  Hore S, Nitz P, Vetter C. Scattering Spherical Voids in Nanocrystalline TiO₂-enhancement of Efficiency in Dye-Sensitized Solar Cells[J]. Chem Commun, 2005,15(15):2011-2013.
38. [38]
  Yang S C, Yang D J, Kim J. Hollow TiO₂ Hemispheres Obtained by Colloidal Templating for Application in Dye-Sensitized Solar Cells[J]. Adv Mater, 2008,20(5):1059-1064. doi: 10.1002/(ISSN)1521-4095
39. [39]
  Khan J, Gu J, Meng Y. Anatase TiO₂ Single Crystal Hollow Nanoparticles:Their Facile Synthesis and High-performance in Dye-Sensitized Solar Cells[J]. CrystEngComm, 2017,19:325-334. doi: 10.1039/C6CE02062C
40. [40]
  Pan H, Qian J, Cui Y. Hollow Anatase TiO₂ Porous Microspheres with V-Shaped Channels and Exposed (101) Facets:Anisotropic Etching and Photovoltaic Properties[J]. J Mater Chem, 2012,22(13):6002-6009. doi: 10.1039/c2jm15925b
41. [41]
  Wu X, Lu G Q, Wang L. Dual-Functional Upconverter-Doped TiO₂ Hollow Shells for Light Scattering and Near-Infrared Sunlight Harvesting in Dye-Sensitized Solar Cells[J]. Adv Energy Mater, 2013,3(6):704-707. doi: 10.1002/aenm.201200933
42. [42]
  Han G, Wang M, Li D. Novel Upconversion Er, Yb-CeO₂ Hollow Spheres as Scattering Layer Materials for Efficient Dye-sensitized Solar Cells[J]. Sol Energy Mater Sol Cells, 2017,160:54-59. doi: 10.1016/j.solmat.2016.10.021
43. [43]
  Li Y Y, Wang J G, Liu X R. Au/TiO₂ Hollow Spheres with Synergistic Effect of Plasmonic Enhancement and Light Scattering for Improved Dye-Sensitized Solar Cells[J]. ACS Appl Mater Interfaces, 2017,9(37):31691-31698. doi: 10.1021/acsami.7b04624
44. [44]
  Yun J, Hwang S H, Jang J. Fabrication of Au@Ag Core/Shell Nanoparticles Decorated TiO₂ Hollow Structure for Efficient Light-Harvesting in Dye-Sensitized Solar Cells[J]. ACS Appl Mater Interfaces, 2015,7(3):2055-2063. doi: 10.1021/am508065n
45. [45]
  Lü X, Huang F, Mou X. A General Preparation Strategy for Hybrid TiO₂ Hierarchical Spheres and Their Enhanced Solar Energy Utilization Efficiency[J]. Adv Mater, 2010,22(33):3719-3722. doi: 10.1002/adma.201001008
46. [46]
  He C X, Lei B X, Wang Y F. Sonochemical Preparation of Hierarchical ZnO Hollow Spheres for Efficient Dye-Sensitized Solar Cells[J]. Chem Eur J, 2010,16(29):8757-8761. doi: 10.1002/chem.201000264
47. [47]
  Wang G, Zhu X, Yu J. Bilayer Hollow/Spindle-like Anatase TiO₂ Photoanode for High Efficiency Dye-Sensitized Solar Cells[J]. J Power Sources, 2015,278:344-351. doi: 10.1016/j.jpowsour.2014.12.091
48. [48]
  Zhao L, Li J, Shi Y. Double Light-scattering Layer Film based on TiO₂ Hollow Spheres and TiO₂ Nanosheets:Improved Efficiency in Dye-Sensitized Solar Cells[J]. J Alloys Compd, 2013,575(20):168-173.
49. [49]
  Chavaa R K, Lee W M, Oh S Y. Improvement in Light Harvesting and Device Performance of Dye Sensitized Solar Cells Using Electrophoretic Deposited Hollow TiO₂ NPs Scattering Layer[J]. Sol Energy Mater Sol Cells, 2017,161:255-262. doi: 10.1016/j.solmat.2016.11.037
50. [50]
  Yu J, Li Qn, Shu Z. Dye-sensitized Solar Cells based on Double-layered TiO₂ Composite Films and Enhanced Photovoltaic Performance[J]. Electrochim Acta, 2011,56(18):6293-6298. doi: 10.1016/j.electacta.2011.05.045
51. [51]
  Zhang Y, Zhang J, Wang P. Anatase TiO₂ Hollow Spheres Embedded TiO₂ Nanocrystalline Photoanode for Dye-Sensitized Solar Cells[J]. Mater Chem Phys, 2010,123(2/3):595-600.
52. [52]
  Pang H, Yang H, Guo C X. Nanoparticle Self-assembled Hollow TiO₂ Spheres with well Matching Visible Light Scattering for High Performance Dye-Sensitized Solar Cells[J]. Chem Commun, 2012,48(70):8832-8834. doi: 10.1039/c2cc34355j
53. [53]
  Dadgostar S, Tajabadi F, Taghavinia N. Mesoporous Submicrometer TiO₂ Hollow Spheres as Scatterers in Dye-Sensitized Solar Cells[J]. ACS Appl Mater Interfaces, 2012,4(6):2964-2968. doi: 10.1021/am300329p
54. [54]
  Yu J, Fan J, Zhao L. Dye-Sensitized Solar Cells Based on Hollow Anatase TiO₂ Spheres Prepared by Self-transformation Method[J]. Electrochim Acta, 2010,55(3):597-602. doi: 10.1016/j.electacta.2009.09.021
55. [55]
  Niu L, Zhang Q, Liu J. TiO₂ Nanoparticles Embedded in Hollow Cube with Highly Exposed {001} Facets:Facile Synthesis and Photovoltaic Applications[J]. J Alloys Compd, 2016,656:863-870. doi: 10.1016/j.jallcom.2015.10.039
56. [56]
  Feng J, Hong Y, Zhang J. Novel Core-Shell TiO₂ Microsphere Scattering Layer for Dye-Sensitized Solar Cells[J]. J Mater Chem A, 2014,2(5):1502-1508. doi: 10.1039/C3TA13523C
57. [57]
  Bai J, Sun X, Han G. Double-shell CeO₂@TiO₂ Hollow Spheres Composites with Enhanced Light Harvesting and Electron Transfer in Dye-Sensitized Solar Cells[J]. J Alloys Compd, 2017,22:864-871.
58. [58]
  Kay A, Grätzel M. Dye-Sensitized Core-Shell Nanocrystals:Improved Efficiency of Mesoporous Tin Oxide Electrodes Coated with a Thin Layer of an Insulating Oxide[J]. Chem Mater, 2002,14(7):2930-2935. doi: 10.1021/cm0115968
59. [59]
  Xie F, Li Y, Dou J. Facile Synthesis of SnO₂ Coated Urchin-like TiO₂ Hollow Microspheres as Efficient Scattering Layer for Dye-Sensitized Solar Cells[J]. J Power Sources, 2016,336:143-149. doi: 10.1016/j.jpowsour.2016.10.061
60. [60]
  Du J, Qi J, Wang D. Facile Synthesis of Au@TiO₂ Core-Shell Hollow Spheres for Dye-Sensitized Solar Cells with Remarkably Improved Efficiency[J]. Energy Environ Sci, 2012,5(5):6914-6918. doi: 10.1039/c2ee21264a
61. [61]
  Thapa A, Zai J, Elbohy H. TiO₂ Coated Urchin-like SnO₂ Microspheres for Efficient Dye-Sensitized Solar Cells[J]. Nano Research, 2014,7(8):1154-1163. doi: 10.1007/s12274-014-0478-z
62. [62]
  Wu W Q, Xu Y F, Rao H S. Constructing 3D Branched Nanowire Coated Macroporous Metal Oxide Electrodes with Homogeneous or Heterogeneous Compositions for Efficient Solar Cells[J]. Angew Chem Int Ed, 2014,53(19):4816-4821. doi: 10.1002/anie.201402371
63. [63]
  Pan J H, Xing Wang Z, Huang Q. Large-scale Synthesis of Urchin-like Mesoporous TiO₂ Hollow Spheres by Targeted Etching and Their Photoelectrochemical Properties[J]. Adv Funct Mater, 2014,24(1):95-104. doi: 10.1002/adfm.v24.1
64. [64]
  Wang H, Li B, Gao J. SnO₂ Hollow Nanospheres Enclosed by Single Crystalline Nanoparticles for Highly Efficient Dye-Sensitized Solar Cells[J]. CrystEngComm, 2012,14(16):5177-5181. doi: 10.1039/c2ce06531b
65. [65]
  Ahn S H, Kim D J, Chi W S. Hierarchical Double-Shell Nanostructures of TiO₂ Nanosheets on SnO₂ Hollow Spheres for High-Efficiency, Solid-State, Dye-Sensitized Solar Cells[J]. Adv Funct Mater, 2014,24(32):5037-5044. doi: 10.1002/adfm.v24.32
66. [66]
  Wang X, Feng J, Bai Y. Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures[J]. Chem Rev, 2016,116(18):10983-11060. doi: 10.1021/acs.chemrev.5b00731
67. [67]
  Wang J, Tang H, Wang H. Multi-shelled Hollow Micro-/Nanostructures:Promising Platforms for Lithium-Ion Batteries[J]. Mater Chem Front, 2017,1(3):414-430. doi: 10.1039/C6QM00273K
68. [68]
  Xu H, Wang W. Template Synthesis of Multishelled Cu₂O Hollow Spheres with a Single-Crystalline Shell Wall[J]. Angew Chem Int Ed, 2007,46(9):1489-1492. doi: 10.1002/(ISSN)1521-3773
69. [69]
  Zhang H, Zhu Q, Zhang Y. One-Pot Synthesis and Hierarchical Assembly of Hollow Cu₂O Microspheres with Nanocrystals-Composed Porous Multishell and Their Gas-Sensing Properties[J]. Adv Funct Mater, 2007,17(15):2766-2771. doi: 10.1002/(ISSN)1616-3028
70. [70]
  Wang X, Wu X L, Guo Y G. Synthesis and Lithium Storage Properties of Co₃O₄ Nanosheet-Assembled Multishelled Hollow Spheres[J]. Adv Funct Mater, 2010,20(10):1680-1686. doi: 10.1002/adfm.v20:10
71. [71]
  Liu J, Hartono S B, Jin Y G. A Facile Vesicle Template Route to Multi-shelled Mesoporous Silica Hollow Nanospheres[J]. J Mater Chem, 2010,20(22):4595-4601. doi: 10.1039/b925201k
72. [72]
  Xi G, Yan Y, Ma Q. Synthesis of Multiple-Shell WO₃ Hollow Spheres by a Binary Carbonaceous Template Route and Their Applications in Visible-Light Photocatalysis[J]. Chem Eur J, 2012,18(44):13949-13953. doi: 10.1002/chem.v18.44
73. [73]
  Lai X Y, Li J, Korgel B A. General Synthesis and Gas-Sensing Properties of Multiple-Shell Metal Oxide Hollow Microspheres[J]. Angew Chem Int Ed, 2011,50(12):2738-2741. doi: 10.1002/anie.201004900
74. [74]
  Li H, Ma H, Yang M. Highly Controlled Synthesis of Multi-shelled NiO Hollow Microspheres for Enhanced Lithium Storage Properties[J]. Mater Res Bull, 2017,87:224-229. doi: 10.1016/j.materresbull.2016.12.005
75. [75]
  Ren H, Sun J, Yu R. Controllable Synthesis of Mesostructures from TiO₂ Hollow to Porous Nanospheres with Superior Rate Performance for Lithium Ion Batteries[J]. Chem Sci, 2016,7(1):793-798. doi: 10.1039/C5SC03203B
76. [76]
  Wang J, Tang H, Zhang L. Multi-shelled Metal Oxides Prepared via an Anion-Adsorption Mechanism for Lithium-Ion Batteries[J]. Nat Energy, 2016,116050. doi: 10.1038/nenergy.2016.50
77. [77]
  Xu S, Hessel C, Ren H. α-Fe₂O₃ Multi-shelled Hollow Microspheres for Lithium Ion Battery Anodes with Superior Capacity and Charge Retention[J]. Energy Environ Sci, 2013,7(2):632-637.
78. [78]
  Wang J, Yang N, Tang H. Accurate Control of Multi-shelled Co₃O₄ Hollow Microspheres for High-Performance Anode Materials in Lithium Ion Batteries[J]. Angew Chem Int Ed, 2013,52(25):6417-6420. doi: 10.1002/anie.201301622
79. [79]
  Ren H, Yu R, Wang J. Multi-shelled TiO₂ Hollow Microspheres as Anodes with Superior Reversible Capacity for Lithium Ion Batteries[J]. Nano Lett, 2014,14(11):6679-6684. doi: 10.1021/nl503378a
80. [80]
  Wang J, Tang H, Ren H. pH-Regulated Synthesis of Multi-Shelled Manganese Oxide Hollow Microspheres as Supercapacitor Electrodes Using Carbonaceous Microspheres as Templates[J]. Adv Sci, 2014,1(1):1719-1720.
81. [81]
  Zhao X, Yu R, Tang H. Formation of Septuple-Shelled (Co_2/3Mn_1/3)(Co_5/6Mn_1/6)₂O₄ Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery[J]. Adv Mater, 2017,29(34)1700550. doi: 10.1002/adma.v29.34
82. [82]
  Lai X, Halperta J E, Wang D. Recent advances in Micro-/Nano-structured Hollow Spheres for Energy Applications:From Simple to Complex Systems[J]. Energy Environ Sci, 2012,5(2):5604-5618. doi: 10.1039/C1EE02426D
83. [83]
  Qian J, Liu P, Xiao Y. TiO₂-Coated Multilayered SnO₂ Hollow Microspheres for Dye-Sensitized Solar Cells[J]. Adv Mater, 2009,21(36):3663-3667. doi: 10.1002/adma.v21:36
84. [84]
  Wu X, Lu G Q, Wang L. Shell-in-Shell TiO₂ Hollow Spheres Synthesized by One-Pot Hydrothermal Method for Dye-Sensitized Solar Cell Application[J]. Energy Environ Sci, 2011,4(9):3565-3572. doi: 10.1039/c0ee00727g
85. [85]
  Hwang S H, Yun J, Jang J. Multi-Shell Porous TiO₂ Hollow Nanoparticles for Enhanced Light Harvesting in Dye-Sensitized Solar Cells[J]. Adv Funct Mater, 2014,24(48):7619-7626. doi: 10.1002/adfm.v24.48
86. [86]
  Dong Z, Lai X, Halpert J E. Accurate Control of Multishelled ZnO Hollow Microspheres for Dye-Sensitized Solar Cells with High Efficiency[J]. Adv Mater, 2012,24(8):1046-1049. doi: 10.1002/adma.201104626
87. [87]
  Xia W, Mei C, Zeng X. Mesoporous Multi-shelled ZnO Microspheres for the Scattering Layer of Dye Sensitized Solar Cell with a High Efficiency[J]. Appl Phys Lett, 2016,108113902. doi: 10.1063/1.4944532
88. [88]
  Dong Z, Ren H, Hessel C M. Quintuple-Shelled SnO₂ Hollow Microspheres with Superior Light Scattering for High-Performance Dye Sensitized Solar Cells[J]. Adv Mater, 2014,26(6):905-909. doi: 10.1002/adma.v26.6
89. [89]
  Yang N L. The PrThe Preparation of Nano Composites and Their Applications in Solar Energy Conversion[M]. Springer Berlin Heidelberg, 2017.
90. [90]
  N L. When Hierarchical Structure Meets the Solar Cell[J]. Sci Bull, 2017,62(4):234-235. doi: 10.1016/j.scib.2017.01.023
91. [91]
  Du J, Lai X, Yang N. Hierarchically Ordered Macro-Mesoporous TiO₂-Graphene Composite Films:Improved Mass Transfer, Reduced Charge Recombination, and Their Enhanced Photocatalytic Activities[J]. ACS Nano, 2011,5(1):590-596. doi: 10.1021/nn102767d
92. [92]
  Yang Y, Jin Q, Mao Dan. Dually Ordered Porous TiO₂-rGO Composites with Controllable Light Absorption Properties for Efficient Solar Energy Conversion[J]. Adv Mater, 2017,29(4)1604795. doi: 10.1002/adma.v29.4
1. [1]
  Zhenhuan Wang , Weifei Wei , Ruijie Ma , Dou Luo , Zhanxiang Chen , Jun Zhang , Liyang Yu , Gang Li , Zhenghui Luo . 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能电池. Acta Physico-Chimica Sinica, 2026, 42(2): 100182-0. doi: 10.1016/j.actphy.2025.100182
2. [2]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . Thickness-Insensitive, Cyano-Modified Perylene Diimide Derivative as a Cathode Interlayer Material for High-Efficiency Organic Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 100027-0. doi: 10.3866/PKU.WHXB202406007
3. [3]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
4. [4]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098
5. [5]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
6. [6]
  Shantao Zhang , TianAo Hou , Yandong Wang , Zhimin Fang , Yu Wu , Haolin Wang , Tao Chen , Shuang Chen , Wenhua Zhang , Shengzhong (Frank) Liu , Shangfeng Yang . π-Conjugation-extended dinaphthocarbazole phosphonic acid as a hole-selective layer for inverted perovskite solar cells. Acta Physico-Chimica Sinica, 2026, 42(3): 100194-0. doi: 10.1016/j.actphy.2025.100194
7. [7]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
8. [8]
  Qian ZHANG , Yuxuan ZHANG , Yongguang YANG , Ruijie BAI , Yuandong LI , Ling LI . FeMoS₄/carbon fiber cloth composites: Preparation and application in dye-sensitized solar cells. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1916-1926. doi: 10.11862/CJIC.20240442
9. [9]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
10. [10]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
13. [13]
  Xiaotian Hu , Binhuan Qiu , Jinglin Le , Runrui Dai , Xiaolan Lü , Yu Hu . Digital Design, Computational Modeling, Fabrication and Characterization of Organic Solar Cells Based on Green Energy Principles. University Chemistry, 2026, 41(1): 298-309. doi: 10.12461/PKU.DXHX202506034
14. [14]
  Chuan′an DING , Weibo YAN , Shaoying WANG , Hao XIN . Preparation of wide-band gap copper indium gallium sulfide solar cells by solution method. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1755-1764. doi: 10.11862/CJIC.20250198
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
17. [17]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
18. [18]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
19. [19]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
20. [20]
  Yawen Guo , Dawei Li , Yang Gao , Cuihong Li . Recent Progress on Stability of Organic Solar Cells Based on Non-Fullerene Acceptors. Acta Physico-Chimica Sinica, 2024, 40(6): 2306050-0. doi: 10.3866/PKU.WHXB202306050

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1454)
HTML views(214)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142