Citation: LIU Ting, LI Jingwei, LIU Yongxin, WANG Cheng. CuO Hollow Tubular Superstructure Fabricated from Cu₂O@HKUST-1 Nanowire for CO Oxidation[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 687-691. doi: 10.11944/j.issn.1000-0518.2018.06.170288 shu

CuO Hollow Tubular Superstructure Fabricated from Cu₂O@HKUST-1 Nanowire for CO Oxidation

LIU Ting ^a,d ,
LI Jingwei ^a,d ,
LIU Yongxin ^a,c ,
WANG Cheng ^a,b,,

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New-Energy Materials and Low-Carbon Technologies, Tianjin University of Technology, Tianjin, 300384, China
c.
School of Materials Science and Engineering, East China Jiaotong University, Nanchang, Jiangxi 330013, China
d.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Cheng, cwang@tjut.edu.cn
Received Date: 17 August 2017
Revised Date: 25 September 2017
Accepted Date: 20 October 2017

Fund Project: the National Natural Science Foundation of China 21501168the National Natural Science Foundation of China 21571170Supported by the National Natural Science Foundation of China(No.21571170, No.21501168)

Figures(4)

A new type of hollow tubular superstructure composed of CuO nanosheets was fabricated from Cu₂O@HKUST-1(HKUST-1=Cu₃(BTC)₂, BTC^3-=benzene-1, 3, 5-tricarboxylate) nanowire through the hydrolysis of HKUST-1 shell and oxidation etching of Cu₂O core. The as-obtained tubular CuO superstructures possess a large Brunauer-Emmett-Teller(BET) surface area(56.3 m²/g) and exhibit high catalytic performance in CO oxidation. The complete CO conversion temperature is 200℃. At 190℃, the value of CO conversion efficiency is 17.3 mmol_CO/(g_CuO·h).
- cupric oxide,
- superstructure,
- hierarchical structure,
- CO oxidation,
- core@shell structure
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CuO Hollow Tubular Superstructure Fabricated from Cu₂O@HKUST-1 Nanowire for CO Oxidation