Citation: HU Xumin, LI Guishui, CHENG Lijun, HAO Liang. Preparation and Photocatalytic Properties of Bismuth Subcarbonate Modified with Surfactants[J]. Chinese Journal of Applied Chemistry, ;2018, 35(6): 692-699. doi: 10.11944/j.issn.1000-0518.2018.06.170235 shu

Preparation and Photocatalytic Properties of Bismuth Subcarbonate Modified with Surfactants

Tianjin Key Laboratory of Integrated Design and On-line Monitoring for Light Industry & Food Machinery and Equipment, College of Mechanical Engineering, Tianjin University of Science & Technology, Tianjin 300222, China

Corresponding author: CHENG Lijun, chenglijun@tust.edu.cn
Received Date: 3 July 2017
Revised Date: 7 August 2017
Accepted Date: 30 August 2017

Fund Project: the Youth Innovation Foundation of Tianjin University of Science & Technology 2015LG11Supported by the Youth Innovation Foundation of Tianjin University of Science & Technology(No.2015LG11)

Figures(4)

Bi₂O₂CO₃ was synthesized by surfactant-assisted hydrothermal method. The dosage of cationic surfactant cetyltrimethylammonium bromide(CTAB), nonionic surfactant polyethylene glycol 8000(PEG8000), anionic surfactant sodium dodecyl sulfate(SDS), and coupling of SDS with CTAB as well as their influences on crystal plane, morphology, photoabsorption ability and photocatalytic activity of Bi₂O₂CO₃ photocatalyst were investigated. The photocatalytic activity was evaluated by the degradation of rhodamine B solution(10 mg/L) under ultraviolet light irradiation. The results show that when the addition of Bi₂O₂CO₃ is 6 mmol(2.9106 g), modified Bi₂O₂CO₃ with SDS will inhibits the photocatalytic activity. The photocatalytic activity of Bi₂O₂CO₃ is effectively improved by addition of 0.6 g CTAB in the hydrothermal process. A totally 0.3 g of SDS and CTAB can improve the photocatalytic activity of Bi₂O₂CO₃. Addition of 0.3 g PEG8000 also promotes the photocatalytic activity of Bi₂O₂CO₃.
- photocatalysis,
- bismuth carbonate,
- surfactant,
- rhodamine B
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