Citation: SUN Yinghua, YANG Meiling, MEI Zemin. Synthesis, Structure Characterization and Photoluminescence Property of a New Molybdenum-Vanadium Polyoxometalate[J]. Chinese Journal of Applied Chemistry, ;2018, 35(5): 589-593. doi: 10.11944/j.issn.1000-0518.2018.05.170263 shu

Synthesis, Structure Characterization and Photoluminescence Property of a New Molybdenum-Vanadium Polyoxometalate

Department College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China

Corresponding author: MEI Zemin, zeminmei@163.com
Received Date: 6 September 2017
Revised Date: 18 October 2017
Accepted Date: 18 October 2017

Fund Project: Supported by the Education Department of Jilin Province Science and Technology Research Projects During the 12th Five Year Plan(No.2013-389)the Education Department of Jilin Province Science and Technology Research Projects During the 12th Five Year Plan 2013-389

Figures(6)

A new tetra-capped Keggin molybdenum-vanadium polyoxometalate[H₃Mo₈^ⅥV₈^ⅣO₄₀(AsO₄)](en)₂(4, 4-bipy)₇·9H₂O(en:ethylenediamine, bipy:bipyridine)(1) was prepared under hydrothermal conditions, and characterized by elemental analysis, FT-IR, X-ray photoelectron spectroscopy(XPS) and single crystal X-ray diffraction analysis. The title compound crystallized in a triclinic system, P1 space group, a=1.47395(5) nm, b=1.48172(6) nm, c=1.62881(7) nm, α=66.16(3)°, β=87.15(2)°, γ=63.42(1)°, V=2.8723(2) nm³, Z=1, R₁=0.0728, wR₂=0.2014. Compound 1 is composed of a tetra-capped Keggin polyoxoanion, 4, 4'-bipyridine, ethylenediamines and lattice water molecules. The rich hydrogen bonds among polyoxoanion and water molecules make the compound molecules forming three dimensional supramolecular array. The compound 1 exhibits strong fluorescent emission and may be an excellent candidate for potential photoactive materials.
- polyoxometalate,
- supramolecular,
- hydrothermal synthesis,
- fluorescent properties
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