Citation: ZHANG Xuefeng, XU Yantong, LIU Siyang, YE Jiawen, ZHANG Jiepeng. Cu(Ⅰ) Phosphorescence Doping of Zeolitic Zinc-Imidazolate Framework MAF-6[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1052-1058. doi: 10.11944/j.issn.1000-0518.2017.09.170170 shu

Cu(Ⅰ) Phosphorescence Doping of Zeolitic Zinc-Imidazolate Framework MAF-6

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: ZHANG Jiepeng, zhangjp7@mail.sysu.edu.cn
Received Date: 23 May 2017
Revised Date: 16 June 2017
Accepted Date: 16 June 2017

Fund Project: the National Natural Science Foundation of China 91622109Supported by the National Natural Science Foundation of China(No.91622109), Natural Science Foundation of Guangdong(No.S2012030006240)Natural Science Foundation of Guangdong S2012030006240

Figures(9)

For luminescence sensing, Cu(Ⅰ)-based coordination complexes have unique advantages such as low cost and long luminescence lifetime. However, Cu(Ⅰ) coordination complexes are generally unstable in air, easily oxidized by oxygen, or quite difficult to form porous frameworks. Among various zeolitic zinc-imidazolate porous coordination polymers, RHO-[Zn(eim)₂] (MAF-6, Heim=2-ethylimidazole) has received considerable interest due to its large pore size and superior hydrophobicity. In this paper, by virtue of the similar coordination behaviors of Cu(Ⅰ) and Zn(Ⅱ) ions, an isomorphic phosphorescent porous coordination polymer, Cu:MAF-6, was obtained through partial substituting Zn(Ⅱ) ions of MAF-6 with Cu(Ⅰ) ions. The phosphorescence of Cu:MAF-6 exhibits very high oxygen sensitivity(K_sv=28.09 kPa^-1; limit of detection=0.36 Pa) in the low oxygen concentration environment( < 600 Pa).
- copper(Ⅰ),
- oxygen sensing,
- zeolite,
- imidazole,
- porous coordination polymer,
- metal-organic framework
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沈阳化工大学材料科学与工程学院沈阳 110142

Cu(Ⅰ) Phosphorescence Doping of Zeolitic Zinc-Imidazolate Framework MAF-6

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com