Citation: DING Hongxia, WU Ying, LIU Zhengping. Preparation of Cationic Polymerizable Imdazolium Ionic Liquid-Acrylamide Copolymers and Their Inhibition Behaviors for Carbon Steel Corrosion in Hydrochloric Acid[J]. Chinese Journal of Applied Chemistry, ;2017, 34(8): 877-884. doi: 10.11944/j.issn.1000-0518.2017.08.160398 shu

Preparation of Cationic Polymerizable Imdazolium Ionic Liquid-Acrylamide Copolymers and Their Inhibition Behaviors for Carbon Steel Corrosion in Hydrochloric Acid

BNU Key Lab of Environmentally Friendly and Functional Polymer Materials; Beijing Key Laboratory of Energy Convers & Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: LIU Zhengping, lzp@bnu.edu.cn
Received Date: 30 September 2016
Revised Date: 4 May 2017
Accepted Date: 7 June 2017

Fund Project: Supported by the Program for Changjiang Scholars and Innovative Research Team in University and the Open Foundation of Beijing Key Laboratory of Materials for Energy Conversion and Storage

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Cationic polymerizable imdazolium ionic liquid-acrylamide copolymers as the corrosion inhibitors were successfully prepared by copolymerization of hydrophilic polymerizable ionic liquid, 1-methyl-3-[2-[(1-oxo-2-propenyl)oxy]ethyl]imdazoliumtetrafluoroborate(ACIMBF₄), with acrylamide via inverse microemulsion polymerization. Various impact factors on the inhibition of carbon steel corrosion by hydrochloric acid including the cationic degree, the relative molecular mass of the copolymer, the concentration of copolymer solution and the absorption time were investigated simultaneously, and the corrosion mitigation mechanism was also discussed preliminary. The corrosion inhibition efficiency of cationic ionic liquid-acrylamide copolymers can reach higher than 90% by forming a protective adsorption film on the carbon steel. The corrosion inhibition ability of cationic copolymer depends on not only its cationic degree but also its relative molecular mass. Moreover, the corrosion inhibition efficiency increases with the increase of the concentration of cationic poly(ionic liquid) copolymer, and then decreases when the concentration of copolymer solution is too high. Furthermore, with the extension of the adsorption time, the corrosion rate of carbon steel is reduced gradually, and remains constant after approximately 40 h, namely the absorbing capacity of inhibitor on the carbon steel reaches the maximum.
- cationic polymerizable imdazolium ionic liquid,
- ionic liquid-acrylamide copolymer,
- cationic degree,
- corrosion inhibitor,
- corrosion mitigation mechanism
1. [1]
  Singh A K, Quraishi M A. The Effect of Some Bis-Thiadiazole Derivatives on the Corrosion of Mild Steel in Hydrochloric Acid[J]. Corros Sci, 2010,52(35):1373-1385.
2. [2]
  Granese S L. Study of the Inhibitory Action of Nitrogen-Containing Compounds[J]. J Sci Eng Corros, 1988,44(26):322-327.
3. [3]
  Singh V P, Singh P, Singh A K. Synthesis, Structural and Corrosion Inhibition Studies on Cobalt(Ⅱ), Nickel(Ⅱ), Copper(Ⅱ), and Zinc(Ⅱ) Complexes with 2-Acetylthiophene Benzoyl Hydrazone[J]. Inorg Chim Acta, 2011,379(58):56-63.
4. [4]
  Al-Amiery A A, Kadhum A A H, Alobaidy A H M. Novel Corrosion Inhibitor for Mild Steel in HCl[J]. Materials, 2014,7(4):662-672.
5. [5]
  Matad P B, Mokshanatha P B, Hebbar N. Ketosulfone Drug as a Green Corrosion Inhibitor for Mild Steel in Acidic Medium[J]. Ind Eng Chem Res, 2014,53(15):8436-8444.
6. [6]
  Shivakumar S S, Mohana K N. Centella Asiatica Extracts as Green Corrosion Inhibitor for Mild Steel in 0.5 M Sulphuric Acid Medium[J]. Adv Appl Sci Res, 2012,3(1):3097-3106.
7. [7]
  Rajendran S, Sri V G, Arockiaselvi J. Corrosion Inhibition by Plant Extracts:An Overview[J]. Bull Electrochem, 2005,21(10):367-377.
8. [8]
  Singh V P, Singh P, Singh A K. Synthesis, Structural and Corrosion Inhibition Studies on Cobalt(Ⅱ), Nickel(Ⅱ), Copper(Ⅱ), and Zinc(Ⅱ) Complexes with 2-Acetylthiophene Benzoyl Hydrazone[J]. Inorg Chim Acta, 2011,379(78):56-63.
9. [9]
  Zhao H. Innovative Applications of Ionic Liquids as "Green" Engineering Liquids[J]. Chem Eng Commun, 2006,193(28):1660-1677.
10. [10]
  Welton T. Room-Temperature Ionic Liquids:Solvents for Synthesis and Catalysis[J]. Chem Rev, 1999,99(10):2071-2083.
11. [11]
  Zheng X W, Zhang S T, Li W P. Experimental and Theoretical Studies of Two Imidazolium-Based Ionic Liquids as Inhibitors for Mild Steel in Sulfuric Acid Solution[J]. Corros Sci, 2015,95(11):168-179.
12. [12]
  Pourghasemi Hanza A, Naderib R, Kowsari E. Corrosion Behavior of Mild Steel in H₂SO₄ Solution with 1, 4-Di[J]. Corros Sci, 2016,107(6):96-106.
13. [13]
  Sasikumar Y, Adekunle A S, Olasunkanmi L O. Experimental, Quantum Chemical and Monte Carlo Simulation Studies on the Corrosion Inhibition of Some Alkyl Imidazolium Ionic Liquids Containing Tetrafluoroborate Anion on Mild Steel in Acidic Medium[J]. J Mol Liq, 2015,211(89):105-118.
14. [14]
  Olivares-Xometl O, López-Aguilar C, Herrastí-González P. Adsorption and Corrosion Inhibition Performance by Three New Ionic Liquids on API 5L X52 Steel Surface in Acid Media[J]. Ind Eng Chem Res, 2014,53(23):9534-9543. doi: 10.1021/ie4035847
15. [15]
  Bereket G, Yurt A, Turk H. Inhibition of Corrosion of Low Carbon Steel in Acidic Solution by Selected Polyelectrolytes and Polymers[J]. Anti-Corros Methods Mater, 2003,50(16):422-535.
16. [16]
  Umoren S A, Ogbobe O, Okafor P C. Polyethylene Glycol and Polyvinyl Alcohol as Corrosion Inhibitors for Aluminium in Acidic Medium[J]. J Appl Polym Sci, 2007,105(35):3363-3370.
17. [17]
  Rajendran S, Sridevi S P, Anthony N. Corrosion Behaviour of Carbon Steel in Polyvinyl Alcohol[J]. Anti-Corros Methods Mater, 2005,52(13):102-107.
18. [18]
  Amin M A, El-Rehim S S A, El-Sherbini E E F. Polyacrylic Acid as a Corrosion Inhibitor for Aluminium in Weakly Alkaline Solutions.Part Ⅰ:Weight Loss, Polarization, Impedance EFM and EDX Studies[J]. Corros Sci, 2009,51(7):658-667.
19. [19]
  Kroschwitz J I, Mark H F, Bikales N M, et al. Encyclopaedia of Polymer Science and Technology[M]. 2nd ed. Wiley-Interscience Publication:Chichester, UK, 1964:1.
20. [20]
  Gao B, Zhang X, Sheng Y. Studies on Preparing and Corrosion Inhibition Behaviour of Quaternized Polyethyleneimine for Low Carbon Steel in Sulfuric Acid[J]. Mater Chem Phys, 2008,108(62):375-381.
21. [21]
  Dobbelin M, Jovanovski V, Llarena I. Synthesis of Paramagnetic Polymers using Ionic Liquid Chemistry[J]. Polym Chem, 2011,2(6):275-1278.
22. [22]
  Rahman M T, Barikbin Z, Badruddoza A Z M. Monodisperse Polymeric Ionic Liquid Microgel Beads with Multiple Chemically Switchable Functionalities[J]. Langmuir, 2013,59(30):9535-9543.
23. [23]
  Mecerreyes D. Polymeric Ionic Liquids:Broadening the Properties and Applications of Polyelectrolytes[J]. Prog Polym Sci, 2011,36(12):1629-1648. doi: 10.1016/j.progpolymsci.2011.05.007
24. [24]
  Gao B, Lv Y, Jiu H. Synthesis and Properties of Cationic Polyacrylamide Containing Pyridine Quaternary Salt[J]. Polym Int, 2003,52(9):1468-1473. doi: 10.1002/(ISSN)1097-0126
25. [25]
  Sayed S, Abd R, Hamdy H. Corrosion Inhibition of Aluminum by 1, 1-(Lauryl amido) Propyl Ammonium Chloride in HCl Solution[J]. Mater Chem Phys, 2001,70(23):64-72.
26. [26]
  Atta A M, El-Mahdy G A, Allohedan H A. Poly(ionic liquid) Based on Modified Ionic Polyacrylamide for Inhibition Steel Corrosion in Acid Solution[J]. Int J Electrochem Sci, 2015,10(12):10389-10401.
27. [27]
  Atta A M, El-Mahdy G A, Allohedan H A. Synthesis and Application of Poly Ionic Liquid-Based on 2-Acrylamido-2-Methyl Propane Sulfonic Acid as Corrosion Protective Film of Steel[J]. Int J Electrochem Sci, 2015,10(8):6106-6119.
28. [28]
  Arellanes-Lozada P, Olivares-Xometl O, Guzmánú-Lucero D. The Inhibition of Aluminum Corrosion in Sulfuric Acid by Poly(1-vinyl-3-alkyl-imidazolium Hexafluorophosphate)[J]. Materials, 2014,7(8):5711-5734. doi: 10.3390/ma7085711
29. [29]
  HU Yaohong, ZHANG Shuling. Corrosion Inhibitor of Nnitrogenous Heterocyclic Compounds[J]. J Chem Corros Prot, 1991,4:10-14.
30. [30]
  YANG Wenzhi, HUANG Kuiyuan. Corrosion Inhibitor[M]. Beijing:Chemical Industry Press, 1989:90(in Chinese).
31. [31]
  Qiu L G, Xie A J, Shen Y H. Understanding the Adsorption of Cationic Gemini Surfactants on Steel Surface in Hydrochloric Acid[J]. Mater Chem Phys, 2004,87(2/3):237-242.
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